General Electric Company

Marcel Vieveen

Stephan Mathijs Bouwens

Rudy Francois Peemans

Gerrit Op Den Dries

Ad Nieuwlaat

Johan Adrianus Aarssen

The present invention provides a method for making aromatic carbonates. In this method, an aryl alcohol is reacted with a dialkyl carbonate in a reactor (e.g., a distillation column) to produce an arylalkyl carbonate and diaryl carbonate. The total yield of arylalkyl carbonate and diaryl carbonate together is at least 40%. Also, the selectivity of diaryl carbonate versus diaryl carbonate and arylalkyl carbonate together is preferably at least 25%.

Method for the continuous production of aromatic carbonates

The present invention provides a method for making aromatic carbonates. In this method, an aryl alcohol is reacted with a dialkyl carbonate in a reactor (e.g., a distillation column) to produce an arylalkyl carbonate and diaryl carbonate. In one embodiment, the method comprises: feeding to the top subsection of the reactive section of a distillation column, a first stream comprising an aryl alcohol and a catalyst, and feeding to the bottom subsection of the reactive section a second stream containing a dialkylcarbonate, wherein the temperature at the bottom of the column is between 220&deg; C. and 240&deg; C.

The present invention provides a method for making polycarbonates. One embodiment of the method comprises reacting diphenylcarbonate with a dihydric phenol. The diphenylcarbonate is made by reacting a reaction mixture comprising aryl alcohol together with a dialkyl carbonate in a reactor to produce aryl alkylcarbonate and diaryl carbonate.

Method for the continuous production of poly carbonates

An integrated process for the preparation and recovery of BPA in pure form utilizes a series of steps to crystallize the 1:1 adduct of phenol and bisphenol-A, with periodic descaling of the crystallizer surfaces with a modified reactor/crystallizer containing 1 to 40 percent water.

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Nieuw-Vossemeer, Netherlands

Marcel Vieveen