Celanese Emulsions Gmbh

Celanese International Corporation

Marc Theodorus Ratering

Stephan Krieger

Rajeev Farwaha

Ivan Cabrera

Thomas Fichtner

Ulrich Desor

Tara Joy Hansen

Christoph Deller

Argiri Tsami-Schulte

Disclosed are aqueous latex-based coating compositions which comprise a blend of an ethylene-vinyl acetate emulsion copolymer component and a selected type of acrylic emulsion copolymer component. The acrylic copolymer component comprises primarily acrylate ester co-monomers or acrylic ester co-monomers and vinyl aromatic, e.g., styrene, co-monomers. The blend of these two emulsion copolymer types also contains a specific type of hydrazine-based, water-soluble cross-linking agent which can eventually react with the acrylic emulsion copolymer component. The acrylic emulsion copolymer is one which contains minor amounts of both 1) carboxy functional co-monomers such as itaconic and/or (meth)acrylic acids, and 2) keto- or aldehyde-containing co-monomers such as diacetone acrylamide. Such latex-based coating compositions can be formulated in the form of water-based paint compositions. These paint products provide paint coatings that exhibit desirable dry and wet adhesion characteristics and desirable resistance to blocking.

Aqueous latex coating compositions

An aqueous polymer composition is described comprising a homogeneous acrylic polymer dispersion produced by emulsion polymerization of a monomer mixture comprising: (A) from 85 to 99.9 wt % of one or more main monomers selected from C-C-alkyl esters of acrylic acid or C-C-alkyl esters of methacrylic acid, styrene, and vinyl toluene in such a ratio as to produce a polymer having a Tg in the range of &#x2212;20 to +65&#xb0; C.; and (B) from 0.1 to 5 wt % of at least one stabilizing monomer selected from ethylenically unsaturated monocarboxylic acids or amides thereof, ethylenically unsaturated dicarboxylic acids or anhydrides or amides thereof, ethylenically unsaturated sulfonic acids, ethylenically unsaturated phosphoric acids, and ethylenically unsaturated phosphonic acids. The emulsion polymerization is conducted in the presence of 0.05 to 3 wt %, based on the total weight of monomers in the monomer mixture, of a chain transfer agent (C).

Aqueous polymer dispersions

Plasters and renders and paints, copolymer dispersions and their use Compositions containing selected polymer dispersions, colloidal silica, fillers and pigments are described. These can be formulated to give plasters and renders or paints which are distinguished by excellent abrasion resistance, little tendency to soiling, high water vapor permeability, good adhesion and good weathering stability. The compositions according to the invention can be processed to give plasters and renders or paints which have a nanostructured surface and which differ from conventionally produced surfaces.

Plasters and renders and paints, copolymer dispersions and their use

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Liederbach am Taunus, Germany

Marc Theodorus Ratering