Industrial Technology Research Institute

Lee Chang Yung Chemical Industry Corporation

Mao-Lin Hsueh

Yi-Zhen Chen

Kuo-Chen Shih

Cheng-Wei Yeh

Hao-Hsun Yang

Hsi-Hsin Shih

Chih-Wei Liu

Chih-Kuang Chang

Hsiao-Chun Yeh

Yung-Chan Lin

Hung-Yu Chen

Cheng-Han Hsieh

Tsai-Tien Su

Li-Key Chen

Cheng-Hsien Yang

Provided is a hydrophilic phosphorus ligand with the structure of formula 1. X is Y is m is an integer from 1 to 20, A independently is *&#x2014;O(CH), n is an integer from 1 to 5, *&#x2014; is a bond close to triphenylphosphine, and &#x2014; is a bond away from triphenylphosphine.

Hydrophilic phosphorus ligand and method for separation and recovery of catalyst

A method of forming foam material is provided, which includes mixing 100 parts by weight of a compound having cyclic carbonate groups and a foaming agent to form a foaming composition, wherein the foaming agent includes 3 to 13 parts by weight of carbamate salt and 15 to 65 parts by weight of amino compound. The foaming composition is heated to 100&#xb0; C. to 170&#xb0; C. for decomposing the carbamate salt into COand amino compound, and the amino compound is reacted with the compound having cyclic carbonate groups to form the foam material.

Method of forming foam material

Foaming composition and method of forming foam material

A polyurethane urea composition and a preparation method thereof are provided. The method includes mixing and reacting an urea and an amine compound to obtain a polyurea oligomer, and mixing and reacting the polyurea oligomer and a cyclic carbonate compound to obtain a polyurethane urea composition having a repeating unit represented by formula I:&#x2014;R&#x2014;U&#x2014;U&#x2014;U&#x2014;R&#x2014;, wherein &#x2003;&#x2003;[formula I]  

Polyurethane urea composition and preparation method thereof

A catalyst and a method for synthesizing cyclic carbonate using the catalyst are provided. The catalyst includes a metal complex shown in formula (I): wherein R, R, R, and Rare independently a C1-C25 alkyl group, a C1-C25 alkoxy group, a C3-C8 cycloalkyl group, a C6-C25 aryl group, a C6-C25 aryloxy group, a C7-C25 aralkyl group, a C7-C25 aralkoxy group, or halogen; Ris hydrogen, a C1-C25 alkyl group, a C3-C8 cycloalkyl group, a C6-C25 aryl group, a C6-C25 aryloxy group, a C7-C25 aralkyl group, or a C7-C25 aralkoxy group; M is Sn or Ti; X is Cl, Br, I, or OAc; and L represents ether or furan.

Catalyst and method for synthesizing cyclic carbonate by the same

A catalyst system includes a transition metal salt containing a halo group, an acetate group, or a combination thereof, and an organic phosphine ligand. The molar ratio of the organic phosphine ligand to the transition metal salt is greater than 0 and less than or equal to 50.

Cayalyst system

A hydrogenation catalyst system is provided. The catalyst system includes a metal complex of Formula (I), an organic lithium compound and an organic compound having a cyclic structure including at least one double bond.  In Formula (I), M is transition metals. R, R, R, Rand Rare the same or different, including hydrogen, C1-8 alkyl, and C1-8 alkoxy, or two of R, R, R, Rand Rare linked together to form a ring. X, Xand Xare a cyclic group, hydrogen, chlorine, bromine, alkyl or alkoxy, wherein when one of X, Xand Xis a cyclic group, and the others are the same or different, including hydrogen, chlorine, bromine, alkyl or alkoxy. The invention also provides a selective hydrogenation process utilizing the catalyst system.

Catalyst systems and selective hydrogenation processes

A catalyst system and a method for manufacturing cyclic carbonate by the same are provided. The catalyst system includes a transition metal salt containing a halo group, an acetate group, or a combination thereof, and an organic phosphine ligand. The molar ratio of the organic phosphine ligand to the transition metal salt is greater than 0 and less than or equal to 50.

Cayalyst system and manufacturing method of cyclic carbonate by the same

The present disclosure is related to a carbon-nanomaterial-supported catalyst, including: a carbon nanomaterial, and a polymer grafted onto the carbon nanomaterial, wherein the polymer has a repeat unit containing a phosphonium salt and its molecular weight is 1,000-200,000. The disclosure is also related to a method of preparing carbonate, which includes using the carbon nanomaterial-supported catalyst for the cycloaddition reaction of carbon dioxide into the epoxy group.

Carbon nanomaterial-supported catalyst and application thereof in cyclic carbonate synthesis

The disclosed is a comb-shaped graft copolymer, including a back bone of PMMA and side chains of a random copolymer, a block copolymer, or a homopolymer polymerized of a monomer having a carbon-carbon double bond. The monomer can be alkyl acrylate, styrene, and the likes. The side chains terminal is grafted to a nitro-oxy compound.

Comb-shaped graft copolymers and methods of manufacturing the same

The disclosure provides a catalyst carrier, including a nano carbon material; and a polymer grafted on the nano carbon material, wherein the polymer has a repetitive unit comprising a phosphorous atom. The disclosure further provides a catalyst deposited on the catalyst carrier of the disclosure. The catalyst of the disclosure has high reactivity, and is easy to be recovered in C&#x2014;C coupling reactions such as a Suzuki-Miyaura coupling reaction.

Catalyst carrier, catalyst thereon and C-C coupling method use the same

A gel electrolyte composition is provided. The composition of the gel electrolyte includes an unsubstituted or substituted pyridine, a metal salt, a halogen molecule, an unsubstituted or substituted nicotinic acid and a solvent. The composition may be free from or substantially free from one or more of a polymer and a low molecular gelling agent. Also provided is a dye-sensitized solar cell containing the composition as well as a method for preparing the composition.

Gel electrolyte composition, method of fabricating thereof and dye-sensitized solar cell using the same

An acrylic copolymer with high heat-resistance is provided. The acrylic copolymer includes repeat units of a monomer of Formula (1) and repeat units of a methacrylic monomer derivative: wherein x is 1-3 and y is 0-3. The acrylic copolymer possesses high heat-resistance and low water absorptivity. The invention also provides a method for preparing the acrylic copolymer.

Acrylic copolymers with high heat-resistance and preparation thereof

The disclosed is about a hydroformylation of a cyclic olefin with rhodium catalyst, and specifically about the recovering of the rhodium catalyst. Aldehyde and the cyclic olefin are added into a rhodium catalyst solution to process a hydroformylation, thereby forming the product cycloalkyl aldehyde. Afterwards, the result is divided into two layers. The upper layer is substantially rhodium catalyst solution, and the lower layer is substantially cycloalkyl aldehyde and the aldehyde. After separation, the upper layer is reserved to process next hydroformylation reaction with newly added cyclic olefin.

Hydroformylation process

The disclosed is about a hydroformylation reaction of a cyclic olefin in the presence of a rhodium catalyst, and specifically about recovering the rhodium catalyst. After the cyclic olefin is hydroformylated by the rhodium catalyst, the product solution is added an extraction liquid including a cycloalkyl alcohol and separated into two layers. The upper layer is substantially made up of the rhodium catalyst solution, and the lower layer is substantially made up of the cycloalkyl aldehyde and the extraction solution including cycloalkyl alcohol.

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Pingtung County, Taiwan

Mao-Lin Hsueh