Saudi Arabian Oil Company

King Fahd University of Petroleum and Minerals

Mansour Ali Al-Herz

Musaed Salem Al-Ghrami

Qi Xu

Aaron Chi Akah

Ali Al Jawad

Mohammed Abdul Bari Siddiqui

Mian Rahat Saeed

Rabindran Jermy Balasamy

Nathan D Hould

Ahmed Al-Asseel

Wala A Algozeeb

Zhonglin Zhang

Raed H Abudawoud

Lianhui Ding

Dominic Jude Anthony Kearney

Luis A Rojas Cordova

Enas Saleh Altarooti

Nathan Hould

Wala Algozeeb

A method of processing a hydrocarbon feed may comprise fractionating the hydrocarbon feed into a light stream, a middle stream, a heavy stream, and a residue stream; hydrotreating the residue stream to form a hydrotreated residue stream; and feeding the light stream, middle stream, heavy stream, and the hydrotreated residue stream to a single Fluid Catalytic Cracking (FCC) reaction zone, thereby producing a product stream comprising light olefins. The light stream and the hydrotreated residue streams may be exposed to more severe FCC cracking conditions than the middle stream and the middle stream may be exposed to more severe FCC cracking conditions than the heavy stream. The FCC reaction zone may be operated in a down-flow configuration and operated under high severity conditions.

Multi-zone catalytic cracking of crude oils

A method of processing a hydrocarbon feed may comprise fractionating the hydrocarbon feed into a light stream, a middle stream and a heavy stream; hydrotreating the heavy stream to form a hydrotreated heavy stream; feeding the light stream to a first Fluid Catalytic Cracking (FCC) reaction zone; feeding the middle stream to a second FCC reaction zone; and feeding the hydrotreated heavy stream to a third FCC reaction zone, thereby producing a heavy product stream comprising light olefins; and feeding one or more of the product streams to one or more fractionators, thereby producing one or more finished product streams and one or more recycle streams comprising one or more of light cycle oil (LCO), heavy cycle oil (HCO), and slurry oil; and hydrotreating one or more of the recycle streams to form the hydrotreated heavy stream.

A process for converting crude oil to light olefins, aromatics, or both, includes contacting a crude oil with an FCC catalyst composition in a catalytic cracking system at a temperature of greater than or equal to 580° C., a weight ratio of the FCC catalyst to the crude oil of from 2:1 to 10:1, and a residence time of from 0.1 seconds to 60 seconds. Contacting causes at least a portion of hydrocarbons in the crude oil to undergo cracking reactions to produce a cracked effluent comprising at least olefins. The FCC catalyst composition for producing olefins and aromatics from crude oil includes ultrastable Y-type zeolite impregnated with lanthanum, ZSM-5 zeolite impregnated with phosphorous, an alumina binder, colloidal silica, and a matrix material comprising Kaolin clay.

Process and catalyst formulation for cracking crude oil to produce light olefins and aromatics

Embodiments of the present disclosure are directed to a method of processing a hydrocarbon feed includes fractionating the hydrocarbon feed into a light stream and a heavy stream, hydrotreating the heavy stream to form a hydrotreated heavy stream, combining the light stream and the hydrotreated heavy stream to form a upgraded feed stream, and feeding the upgraded feed stream to a single Fluid Catalytic Cracking (FCC) reaction zone, thereby producing a product stream comprising light olefins. The light stream may comprise hydrocarbons boiling at less than 343° C. and the heavy stream may comprise hydrocarbons boiling at greater than 343° C. The FCC reaction zone may be operated in a down-flow configuration and the FCC may be operated under high severity conditions.

A method of processing a hydrocarbon feed may comprise fractionating the hydrocarbon feed into a light stream, a middle stream and a heavy stream; hydrotreating the heavy stream to form a hydrotreated heavy stream; feeding the light stream to a first Fluid Catalytic Cracking (FCC) reaction zone; feeding the middle stream to a second FCC reaction zone; and feeding the hydrotreated heavy stream to a third Fluid Catalytic Cracking (FCC) reaction zone. The light stream may comprise hydrocarbons boiling at less than 200° C. The middle stream may comprise hydrocarbons boiling at from 200° C. to 370° C. The heavy stream may comprise hydrocarbons boiling at greater than greater than 370° C. Each of the first and second FCC reaction zones may operate under more severe operating conditions than the third FCC reaction zone.

A method of processing a hydrocarbon feed may comprise fractionating the hydrocarbon feed into a light stream, a middle stream, and a heavy stream; hydrotreating the heavy stream to form a hydrotreated heavy stream; and feeding the light stream, middle stream, and the hydrotreated heavy stream to a single Fluid Catalytic Cracking (FCC) reaction zone, thereby producing a product stream comprising light olefins. The light stream may be exposed to more severe FCC cracking conditions than the middle stream and the middle stream may be exposed to more severe FCC cracking conditions than the hydrotreated heavy stream, within the same FCC reaction zone. The single FCC reaction zone may be operated in a down-flow configuration and under high severity conditions.

According to one embodiment of the present disclosure, a method of processing a hydrocarbon feed may comprise fractionating the hydrocarbon feed into a light stream, a middle stream, and a residue stream, hydrotreating the residue stream to form a hydrotreated residue stream; and feeding the light stream, middle stream, and the hydrotreated residue stream to a single Fluid Catalytic Cracking (FCC) reaction zone, thereby producing a product stream comprising light olefins. The light stream and the hydrotreated residue streams may be exposed to more severe FCC cracking conditions than the middle stream, within the same FCC reaction zone. The single FCC reaction zone may be operated in a down-flow configuration and the single FCC reaction zone may be operated under high severity conditions.

A method of processing a hydrocarbon feed may comprise fractionating the hydrocarbon feed into a light stream and a heavy stream, where the light stream includes hydrocarbons boiling at less than 370° C., and the heavy stream includes hydrocarbons boiling at greater than greater than 370° C., hydrotreating the heavy stream to form a hydrotreated heavy stream, feeding the light stream to a first Fluid Catalytic Cracking (FCC) reaction zone, thereby producing a light product stream which includes light olefins, and feeding the hydrotreated heavy stream to a second Fluid Catalytic Cracking (FCC) reaction zone, thereby producing a heavy product stream which includes light olefins, where the first FCC reaction zone operates under more severe operating conditions than the second FCC reaction zone.

Embodiments of the present disclosure are directed to a method of processing a hydrocarbon feed includes fractionating the hydrocarbon feed into a light stream and a heavy stream, hydrotreating the heavy stream to form a hydrotreated heavy stream, combining the light stream and the hydrotreated heavy stream to form a upgraded feed stream, and feeding the upgraded feed stream to a single Fluid Catalytic Cracking (FCC) reaction zone, thereby producing a product stream comprising light olefins. The light stream may comprise hydrocarbons boiling at less than 540° C. and the heavy stream may comprise hydrocarbons boiling at greater than 540° C. The FCC reaction zone may be operated in a down-flow configuration and the FCC may be operated under high severity conditions.

According to one embodiment of the present disclosure, a method of processing a hydrocarbon feed includes fractionating the hydrocarbon feed into a light stream and a heavy stream; hydrotreating the heavy stream to form a hydrotreated heavy stream; feeding the light stream and the hydrotreated heavy stream to a single Fluid Catalytic Cracking (FCC) reaction zone, thereby producing a product stream which includes light olefins. The light stream may be exposed to more severe FCC cracking conditions than the heavy stream, within the same FCC reaction zone. The single FCC reaction zone may be operated in a down-flow configuration and the FCC may be operated under high severity conditions. The light stream may include hydrocarbons boiling at less than 371° C. and the heavy stream may include hydrocarbons boiling at greater than 371° C.

A process for converting crude oil to light olefins, aromatics, or both, includes contacting a crude oil with an FCC catalyst composition in a fluidized catalytic cracking system at a temperature of greater than or equal to 580&#xb0; C., a weight ratio of the FCC catalyst to the crude oil of from 2:1 to 10:1, and a residence time of from 0.1 seconds to 60 seconds. Contacting causes at least a portion of hydrocarbons in the crude oil to undergo cracking reactions to produce a cracked effluent comprising at least olefins. The FCC catalyst composition for producing olefins and aromatics from crude oil includes ultrastable Y-type zeolite impregnated with lanthanum, ZSM-5 zeolite impregnated with phosphorous, where the nano-ZSM-5 zeolite has an average particle size of from 0.01 &#x3bc;m to 0.2 &#x3bc;m, an alumina binder, colloidal silica, and a matrix material comprising Kaolin clay.

Process and nano-ZSM-5 based catalyst formulation for cracking crude oil to produce light olefins and aromatics

According to at least one aspect of the present disclosure, a method for processing a heavy oil includes introducing the heavy oil to a hydroprocessing unit, the hydroprocessing unit being operable to hydroprocess the heavy oil to form a hydroprocessed effluent by contacting the heavy oil feed with an HDM catalyst, an HDS catalyst, and an HDA catalyst. The hydroprocessed effluent is passed directly to a HS-FCC unit, the HS-FCC unit being operable to crack the hydroprocessed effluent to form a cracked effluent comprising at least one product. The cracked effluent is passed out of the HS-FCC unit. The heavy oil has an API gravity of from 25 degrees to 50 degrees and at least 20 wt. % of the hydroprocessed effluent passed to the HS-FCC unit has a boiling point less than 225 degrees &#xb0; C.

Systems and methods including hydroprocessing and high-severity fluidized catalytic cracking for processing petroleum-based materials

Methods including direct hydroprocessing and high-severity fluidized catalytic cracking for processing crude oil

Provided here are zirconium-substituted hierarchical zeolite compositions and methods of preparing such catalytic compositions. One such method involves subjecting the zirconium-substituted zeolite to a framework modification process using a single template to produce a framework-modified zeolite, followed by subjecting the framework-modified zeolite to an ion exchange process to produce a hierarchical zeolite composition. Also provided are methods of catalytic cracking of hydrocarbon feedstocks using these zirconium-substituted hierarchical zeolite compositions.

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Al-Ahsa, Saudi Arabia

Mansour Ali Al-Herz