Bayer Aktiengesellschaft

Manfred Schreckenberg

Dieter Freitag

Rolf Dhein

Klaus Konig

Christian Lindner

Carlhans Suling

Herbert Bartl

Hans Rudolph

Werner Nouvertne

Werner Waldenrath

Ralf Lange

Volker Serini

Johannes Blahak

Lothar Preis

Siegfried Adelmann

Hans-Heribert Burgdorfer

Gunther Lehnert

Harald Medem

Harald Blum

Dieter Margotte

Jurgen Meixner

Wolfgang Wellner

Frank Gerald Kleiner

Peter R Muller

Udo Wolf

Lothar Fleiter

Gottfried Schneider

Hermann Stetter

Nouvertne Werner

This invention relates to a process for monitoring polycondensation or polyaddition reactions by measuring the OH, NH or NCO value or acid value of participating reactants by means of infra-red ATR spectroscopy of the associated, temperature-dependent absorption bands and compensating for the temperature dependence by calibrating the self-absorption of the ATR measuring crystal.

Process for monitoring polycondensation or polyaddition reactions

A process is disclosed for preparing aqueous, oxidatively-drying alkyd resins. The resins are useful as binders in aqueous lacquers and coating compositions.

Process for the preparation of aqueous, oxidatively drying alkyd resins

The present invention relates to diphenol monoesters of carboxylic acids, a process for their preparation, their use for the preparation of polyester-carbonates, the polyester-carbonates obtainable according to the invention and flame-repellent moulding compositions containing these polyester-carbonates.

Diphenol monoesters of carboxylic acids and process for their preparation

Interpenetrating polymer networks prepared from 60 to 99.9% by weight, of a thermoplast and 0.1 to 40% by weight of a thermosetting resin which comprises:

Thermosetting cyanate resin and the use thereof for the production of

The present invention is directed to a process for the preparation of a segmented, aliphatic-aromatic polyether-copolycarbonate containing structural units conforming to ##STR1## wherein --D-- is a diphenolate radical and units conforming to ##STR2## wherein --O--Polyether--O-- is an aliphatic polyether-diolate radical, by the phase boundary process in which aliphatic polyether diol and a mixture of dihydroxy compounds are reacted with a carbonic acid halide which is employed in molar excess in relation to the dihydroxy compounds and in which the aqueous phase is kept at a pH value of at least 13 and where the polycondensation reaction is carried out in a reactor by addition of an amine catalyst. The invention is further directed to the polyether polycarbonate which is obtained by the process and to the preparation of membranes from said polyether copolycarbonate.

Polyether-copolycarbonates for dialysis membranes

This invention relates to a thermosetting resin of either (a) at least one polycyanate and (b) at least one polyester polyol or of (c) a prepolymer of (a) and (b) and to the use thereof for the production of composite materials and of interpenetrating polymer networks (IPNs).

The present invention relates to a process for the preparation of polyether-polycarbonates, a process for stabilizing the polyether-polycarbonates thus prepared, a process for the production of membranes from the polyether-polycarbonates prepared according to the invention, stabilized membranes obtainable by the process according to the invention and the use of the polyether-polycarbonate membranes obtainable by the process according to the invention for dialysis, ultrafiltration and reverse osmosis.

Polyether-polycarbonates for dialysis membranes

The present invention relates to high molecular weight thermoplastic hexahydro-furo-(3,2-b)-furane-3,6-diol based copolycarbonates useful as molding resins and to a method for their preparation.

Thermoplastic polycarbonates, their preparation and their use as shaped

The present invention relates to mixtures of polycarbonates containing hydrogenated dimeric fatty acid esters as condensed units, and polyolefines and, if appropriate, other high-molecular weight, aromatic thermoplastic polycarbonates.

Mixtures of polycarbonate elastomers, containing hydrogenated dimeric

The present invention relates to polycarbonate compounds characterized in that dimeric fatty acid ester soft segments are co-condensed therein. The invention further relates to processes for preparation of these compounds and their use in films and molded articles.

High-molecular, segmented, thermoplastically processable, aromatic

The present invention is directed to cross-linkable, thermoplastically processable, segmented, high molecular weight polycarbonate elastomers, to the process for their preparation and to their use in their cross-linked form.

Cross-linkable polycarbonate elastomers, a process for their preparation

The present invention relates to a process for the preparation of bis-carbonic acid aryl esters of polyester-diols, lengthened via --OCOO-- groups, characterized in that polyester-diols with molecular weights Mn (number-average) of over 250, preferably over 600, are heated with carbonic acid bis-aryl esters at temperatures between about 100.degree. C. and 200.degree. C., preferably between about 110.degree. C. and 180.degree. C., in vacuo below about 35 mm Hg, preferably between about 25 and 1 mm Hg, in the presence of catalysts, less than one mol of carbonic acid bis-aryl ester being employed per OH group of the polyester-diol and the hydroxyaryl compounds formed being distilled off. The invention further relates to the bis-carbonic acid aryl esters of polyester-diols lengthened via --OCOO-- groups obtained according to the instant invention and their use for the preparation of polyester diol bis-diphenol carbonates, lengthened via carbonate groups, characterized in that polyester-diol bis-aryl carbonates are reacted with a diphenol at a temperature of from about 100.degree. to about 200.degree. C. in vacuo below about 35 mm Hg in the presence of a catalyst, wherein more than 1 mol of diphenol is employed per mol of carbonic acid aryl ester groups of the polyester-diol bis-aryl carbonate, lengthened via carbonate groups, and the resulting hydroxyaryl compound is distilled off. The invention finally relates to the polyester-diol bis-diphenol carbonates, lengthened via carbonate groups obtained according to the instant invention and their use for the preparation of polyester/polycarbonates and the polycarbonate/polyesters so prepared.

Process for the preparation of carbonic acid aryl esters of

The subject of instant invention is a process for the preparation of aliphatic-aromatic polycarbonates with diphenol carbonate end groups, the polycarbonates obtained therefrom and their use for the preparation of high-molecular, segmented, aliphatic-aromatic polycarbonate elastomers which can be processed as thermoplastics.

Process for the preparation of aliphatic-aromatic polycarbonates with

This disclosure is concerned with a single step process for the production of diphenol terminated polycarbonates by the transesterification of diphenols, bis-aryl carbonates and polymeric diols with aliphatically bound terminal hydroxyl groups. These diols are selected from polyesters, polyethers, polythioethers and polyacetals. The transesterification is carried out at elevated temperatures under vacuum optionally in the presence of a catalyst with the ratios of the reactants being such as to avoid the retention of any terminal aliphatic hydroxyl groups or aryl carbonate groups.

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Krefeld, Germany

Manfred Schreckenberg