Covestro Deutschland Ag

Covestro Intellectual Property Gmbh & Co. Kg

Manfred Kobylka

Michael Merkel

Dominik Duerig

Bernhard Seidel

Martin Ehrig

Jan Morbach

Philipp Frenzel

Achim Kuepper

Maria Carrascosa Mas

Christian Morten Jens

Dominik DÜRIG

The present invention relates to a process for thermally separating a mixture comprising a first main component and a second main component, where the boiling point of the first main component is lower than the boiling point of the second main components. The invention further relates to a system for thermal separation comprising a computer for control of the thermal separation which is set up to control the process of the invention. By means of predetermined thermodynamic models, pressure and temperature data are used to ascertain the proportions of first and second main component in bottom product streams.

Distillation method with controlled energy supply

Provided is a process for separating an organic isocyanate prepared by reacting an organic amine with a stoichiometric excess of phosgene in the gas phase from the gaseous crude product obtained in the reaction, the process comprising the steps of (i) at least partially condensing the crude product stream containing at least the isocyanate, hydrogen chloride and unconverted phosgene by contacting with at least one liquid stream containing at least one quench liquid in a first separation apparatus to obtain a liquid stream containing at least some of the quench liquid and some of the isocyanate and a gas stream containing at least hydrogen chloride, evaporated quench liquid and phosgene, (ii) discharging the liquid stream obtained in step (i) via a first liquid outlet and of the gas stream obtained in (i) via a first gas conduit and (iii) at least partially condensing and/or absorbing the gas stream discharged in step (ii) through the first gas conduit, wherein that the at least partial condensation and/or absorption is effected in step (iii) by direct introduction of at least one cooling fluid, wherein the cooling fluid is introduced directly into the first gas conduit via at least one addition unit assigned to the first gas conduit.

Process for separating an organic isocyanate

The invention relates to a cleaning device for separating an organic isocyanate produced by the reaction of an organic amine with a stoichiometric excess of phosgene in the gas phase from the gaseous raw product obtained in the reaction, said device comprising a first separating body comprising at least one raw product supply line for a gaseous raw product flow containing at least the isocyanate, hydrogen chloride and non-reacted phosgene, a first liquid supply line for a liquid flow containing at least one quench liquid, and a first liquid discharge line for a liquid flow containing at least part of the quench liquid and part of the isocyanate, a first gas line for transporting a gas flow containing at least hydrogen chloride, evaporated quench liquid and phosgene leading away from the first separating body. The invention is characterized in that at least one addition body for directly introducing at least one cooling fluid for an at least partial condensation and/or absorption of the gas flow that can be guided via the first gas line is associated with the first gas line.

Cleaning device for gas flows from isocyanate production

The present invention relates to a method for producing purified phosgene vapor, comprising the following steps: 1) providing a gas flow obtainable from the reaction of chlorine with carbon monoxide and comprising phosgene and carbon monoxide; 2) one-stage or multi-stage condensation of the gas flow and separation of non-condensable residue gases; 3) one-stage or multi-stage evaporation of the liquid phosgene obtained in step 2) and optional overheating of the produced phosgene vapour, wherein there is an energy integration between one or more of the condensation steps of step 2) and one or more of the evaporation steps in step 3) and the pressure in the last condensation step is between &#x2265;0.2 and &#x2264;6.0 bar higher than in the first evaporation step.

Energy-efficient method for providing a purified phosgene vapor

Growing community of inventors

Burscheid, Germany

Manfred Kobylka