Hoechst Aktiengesellschaft

Manfred Hofinger

Martin Hille

Roland Bohm

Dieter Ohlendorf

Friedrich Staiss

Willibald Bose

Alwin K Reng

Jochen M Quack

Hans-Walter Bucking

Detlef Wehle

Michael Mitzlaff

Werner Ritschel

Hermann Hoffmann

Hans-Jurgen Kalz

Karl H Wallhausser

Herbert Wirtz

Thomas Blumenthal

Wllibald Bose

Dietrich Wolter

Flow accelerating with mixtures of organic ammonium salts composed of 20 to 80% of a quaternary ammonium salt of the formula ##STR1## 80 to 20% by weight of an amine salt of the formula ##STR2## where in both formulae R.sup.1 denotes C.sub.12 -C.sub.26 -alkyl, C.sub.12 -C.sub.26 -alkenyl, C.sub.12 -C.sub.26 -fluoroalkyl, C.sub.12 -C.sub.26 -fluoroalkenyl or a group of the formula ##STR3## R.sub.f --(CH.sub.2).sub.y B(CH.sub.2).sub.x --, R.sup.2 and R.sup.3 denote C.sub.1 -C.sub.3 -alkyl, preferably methyl, R.sup.4 denotes C.sub.1 -C.sub.4 -alkyl and, for the case where R.sup.1 =alkyl or alkenyl, also a group of the formula --(C.sub.2 H.sub.4 O).sub.z H,

Mixtures of organic ammonium salts and their use as flow accelerators

Mixtures of organic ammonium salts composed of 20 to 80% of a quaternary ammonium salt of the formula ##STR1## and 80 to 20% by weight of an amine salt of the formula ##STR2## where in both formulae R.sup.1 denotes C.sub.12 -C.sub.26 -alkyl, C.sub.12 -C.sub.26 -alkenyl, C.sub.12 -C.sub.26 -fluoroalkyl, C.sub.12 -C.sub.26 -fluoroalkenyl or a group of the formula ##STR3## R.sup.2 and R.sup.3 denote C.sub.1 -C.sub.3 -alkyl, preferably methyl, R.sup.4 denotes C.sub.1 -C.sub.4 -alkyl and, for the case where R.sup.1 =alkyl or alkenyl, also a group of the formula --(C.sub.2 H.sub.4 O).sub.z H,

Mixtures of organic ammonium salts as flow accelerators

Fatty acid esters of oxalkylated alkylalkylenediamines, which may be quaternized:

Esters of fatty acids, which may be quaternized, from oxalkylated

The microbicidal agents consist esentially of 5 to 50% by weight of the salt of an alkyl-di-guanidine of the formula ##STR1## in which R' and R' denote hydrogen or C.sub.8 -C.sub.18 -alkyl, and R' and R' may not simultaneously be hydrogen, m denotes a number from 2 to 6 and n denotes 0 to 1, 5 to 50% by weight of a quaternary ammonium compound of the formula ##STR2## in which R.sup.1 denotes C.sub.8 -C.sub.22 -alkyl or C.sub.8 -C.sub.22 -alkenyl, R.sup.2 and R.sup.3 denote C.sub.1 -C.sub.4 -alkyl or C.sub.2 -C.sub.3 -hydroxyalkyl and R.sup.4 denotes hydrogen or methyl, or R.sup.1 and R.sup.2 denote C.sub.8 -C.sub.12 -alkyl, R.sup.3 denotes C.sub.1 -C.sub.4 -alkyl or C.sub.2 -C.sub.3 -hydroxyalkyl and R.sup.4 denotes hydrogen or methyl, X in both cases denotes a number from 1 to 3, preferably from 1 to 2 and in particular 1,5, and A.sup..crclbar. denotes an anion of a carboxylic acid from the group comprising propiionic acid, lactic acid, glycolic acid, tartronic acid, malic acid, tartaric acid, citric acid, maleic acid and benzoic acid, and, as the remainder, water and/or a lower alcohol or a water-soluble glycol.

Microbicidal agents based on alkyl-di-guanidinium salts

Branched polyoxyalkylene copolyesters are described which are prepared by esterifying an oxyalkylated primary fatty amine and an at least trihydric oxyalkylated alkanol or an oxyalkylated polyamine using a dicarboxylic acid or a dicarboxylic anhydride with polycondensation. The novel branched polyoxyalkylene copolyesters are used as demulsifiers for breaking crude oil emulsions.

Branched polyoxyalkylene copolyesters, a process for their preparation,

Branched, quaternary polyoxyalkylene copolyesters are described which are prepared by esterifying an oxyalkylated primary fatty amine and an at least trihydric oxyalkylated alkanol or an oxyalkylated polyamine using a dicarboxylic acid or a dicarboxylic anhydride with polycondensation, and quaternizing the esterification product obtained using ethylene oxide or propylene oxide in the presence of a mineral acid or carboxylic acid. The novel, branched, quaternary polyoxyalkylene copolyesters are used as demulsifiers and corrosion inhibitors in the processing of crude oil emulsions.

Branched, quaternary polyoxyalkylene copolyesters, a process for their

Quaternary ammonium compounds of the formula ##STR1## in which R.sub.1 denotes an alkyl or alkenyl radical with 12 to 22 carbon atoms; R.sub.2 and R.sub.3 are identical or different and denote an alkyl radical with 1 to 4 carbon atoms; x denotes an integral or non-integral number from 1 to 3; and A.sup..crclbar. denotes an alkyl- or alkenyl-sulfonate anion, an alkyl or alkenyl-carbonate anion or a benzoate, naphthoate or phenylsulfonate anion, the tosylate ion being excluded, a process for their preparation and their use as drag reducing agents in liquids with turbulent flow.

Oxyalkylated quaternary ammonium compounds and their use as drag

An agent for treatment of hair and skin, containing a quarternary ammonium compound of the formula ##STR1## in which R.sub.1 and R.sub.2 may be identical or different and denote C.sub.8 -C.sub.22 -alkyl or C.sub.8 -C.sub.22 -alkenyl, R.sub.3 denotes C.sub.1 -C.sub.3 -alkyl, x denotes a number from 1 to 3, and A.sup..crclbar. denotes the anion of C.sub.2 -C.sub.6 -carboxylic acid, which may contain 1 to 3 hydroxyl groups, or the hydrogen phosphate anion.

Cosmetic agents for hair and skin treatment

Oxalkylated polyester-amines which are prepared by esterifying, with polycondensation, an oxalkylated primary fatty amine with a diol and with a dicarboxylic acid, are described. These polyester-amines are used as demulsifiers for breaking crude oil emulsions.

Oxalkylated polyester-amines, a process for their preparation and their

Quaternary oxalkylated polycondensates are described; these are prepared by esterifying, with polycondensation, an oxalkylated primary fatty amine with a diol and with a dicarboxylic acid, and oxalkylating the resulting reaction product in the presence of a carboxylic acid. These polycondensates are used as demulsifiers for breaking crude oil emulsion and as corrosion inhibitors in plants for the recovery and treatment of natural gas and crude oil.

Quaternary oxalkylated polycondensates

Gel-forming organophilic layer silicate whose exchangeable cations have been wholly or partly replaced by a quaternary ammonium compound of the formula ##STR1## where R.sub.1 and R.sub.2 can be identical or different and denote C.sub.6 C.sub.30 -alkyl or C.sub.6 -C.sub.30 -alkenyl, R.sub.3 denotes C.sub.1 -C.sub.6 -alkyl, R.sub.4 denotes C.sub.1 -C.sub.6 -alkyl, A denotes the group --C.sub.2 H.sub.4 -- or --C.sub.3 H.sub.6 -- and n denotes 1 or 2. These organically modified layer silicates are used as thixotroping agents, for example for surface coatings and antirust primers.

Gel-forming organophilic layer silicate, process for its preparation and

Novel quaternary oxalkylated polyesters prepared from oxalkylated fatty amines by polycondensation with a dicarboxylic acid and subsequent reaction with an alkylene oxide and a carboxylic acid or a mineral acid or with a quaternizing agent such as methyl chloride, are described. The compounds are suitable for use as cosmetic active compounds, in particular for cosmetic care of the hair.

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Burgkirchen, Germany

Manfred Hofinger