Nissan Motor Company Limited

Envision Aesc Japan Ltd.

Manabu Nishijima

Fumihiro Kawamura

Yoshiaki Nitta

Yuji Muroya

Masanori Suenaga

Osamu Shimamura

Shigeo Ibuka

Satoru Ichikawa

Gentaro Kano

Masahiro Takaya

Kenji Ohara

Manabu Kaseda

Tamaki Hirai

Kousuke Hagiyama

Kuniharu Nomoto

Yosuke Suzuki

Kazuyuki Sakamoto

Hidenori Murata

A non-aqueous electrolyte secondary battery with improved cycle durability includes a power generating element including a positive electrode obtained by forming a positive electrode active material layer containing a positive electrode active material on a surface of a positive electrode current collector, a negative electrode obtained by forming a negative electrode active material layer containing a negative electrode active material on a surface of a negative electrode current collector, and a separator, a ratio of a rated capacity to a pore volume of the separator being 1.55 Ah/cc or more, a ratio of a battery area to a rated capacity being 4.0 cm/Ah or more, and a rated capacity being 30 Ah or more, wherein a variation in porosity in the separator is 4.0% or less.

Non-aqueous electrolyte secondary battery

A flat stacked type non-aqueous electrolyte secondary battery includes: a positive electrode comprising a a positive electrode active material formed on a surface of a positive electrode current collector, a negative electrode comprising a negative electrode active material formed on a surface of a negative electrode current collector, and an electrolyte layer, wherein a ratio of a rated capacity to a pore volume of the negative electrode active material layer is 1.12 Ah/cc or more, a ratio of a battery area to a rated capacity is 4.0 cm/Ah or more, and a rated capacity is 30 Ah or more, and the electrolyte layer contains an electrolyte solution containing an electrolyte salt dissolved and a value obtained by dividing a weight of an electrolyte salt in pores in the negative electrode active material layer by a weight of the negative electrode active material is 0.031 or more.

A non-aqueous electrolyte secondary battery has improved battery durability, a high capacity, a high density, and a large area and includes a power generating element including a positive electrode in which a positive electrode active material layer containing a positive electrode active material is formed on a surface of a positive electrode current collector, a negative electrode in which a negative electrode active material layer containing a negative electrode active material is formed on a surface of a negative electrode current collector, and a separator, a ratio of a rated capacity to a pore volume of the negative electrode active material layer being 1.12 Ah/cc or more, a ratio of a battery area to a rated capacity being 4.0 cm/Ah or more, and a rated capacity being 30 Ah or more, wherein a variation in porosity in the negative electrode active material layer is 6.0% or less.

An electric device having a power generating element contains a positive electrode with a positive electrode active material formed on a surface of a positive electrode current collector, a negative electrode, and a separator containing an electrolyte. The positive electrode active material contains a lithium nickel-based composite oxide having a layered crystal structure capable of insertion and desorption of lithium ions, the composition represented by: [LiNi][NiMnMCO]O, wherein M is at least one selected from the group consisting of Ti, Zr, Nb, W, P, Al, Mg, V, Ca, Sr, Cr, Fe, B, Ga, In, Si, Mo, Y, Sn, V, Cu, Ag, and Zn, and x+y+z&#x2264;1, &#x3b2;&#x2264;0.032, 0.9&#x2264;&#x3b1;+&#x3b2;&#x2264;1.2, 0&#x3c;x&#x3c;1, 0&#x3c;y&#x3c;1, 0&#x3c;z&#x3c;1, and 0&#x2264;r&#x2264;0.3, and the electrolyte has a cyclic sulfonic acid ester.

Electric device

[Object] Provided is a means for improving cycle characteristics by suppressing electrode deterioration resulting from non-uniformity of voltage across an electrode plane in a high-capacity and large-area non-aqueous electrolyte secondary battery that includes lithium nickel-based composite oxide as a positive electrode active substance. [Solving Means] Disclosed is a positive electrode for a non-aqueous electrolyte secondary battery used in a non-aqueous electrolyte secondary battery in which the ratio value of battery area (projected area of the battery including the battery outer casing body) to rated capacity is 5 cm/Ah or more and the rated capacity is 3 Ah or more, the positive electrode comprising a positive electrode current collector and a positive electrode active substance layer that is formed on a surface of the positive electrode current collector and has a positive electrode active substance containing a lithium nickel-based composite oxide and a spinel type lithium manganese composite oxide, in which, when the average secondary particle diameter (D50) of the lithium nickel-based composite oxide is D50(A) [&#x3bc;m], the content ratio of the lithium nickel-based composite oxide in the positive electrode active substance layer is A [% by mass], the average secondary particle diameter (D50) of the spinel type lithium manganese composite oxide is D50(B) [&#x3bc;m], and the content ratio of the spinel type lithium manganese composite oxide in the positive electrode active substance layer is B [% by mass], the positive electrode satisfies the following Mathematical Formula 1 and Mathematical Formula 2:

Positive electrode for non-aqueous electrolyte secondary battery and non-aqueous electrolyte secondary battery using the same

[Object] Provided is a means for improving cycle characteristics by suppressing electrode deterioration resulting from non-uniformity of voltage across an electrode plane in a high-capacity and large-area non-aqueous electrolyte secondary battery that includes lithium nickel-based composite oxide as a positive electrode active substance. [Solving Means] Disclosed is a positive electrode for a non-aqueous electrolyte secondary battery used in a non-aqueous electrolyte secondary battery in which the ratio value of battery area (projected area of the battery including the battery outer casing body) to rated capacity is 5 cm/Ah or more and the rated capacity is 3 Ah or more, the positive electrode comprising a positive electrode current collector and a positive electrode active substance layer that is formed on a surface of the positive electrode current collector and has a positive electrode active substance containing a lithium nickel-based composite oxide and a spinel type lithium manganese composite oxide, in which, when the average secondary particle diameter (D50) of the lithium nickel-based composite oxide is D50(A) [&#x3bc;m], the content ratio of the lithium nickel-based composite oxide in the positive electrode active substance layer is A [% by mass], the average secondary particle diameter (D50) of the spinel type lithium manganese composite oxide is D50(B) [&#x3bc;m], and the content ratio of the spinel type lithium manganese composite oxide in the positive electrode active substance layer is B [% by mass], the positive electrode satisfies the following Mathematical Formula 1 and Mathematical Formula 2:[Math. 1]0.5&#x2266;50()/50()&#x2266;2.0&#x2003;&#x2003;MathematicalFormula1:/()&#x2267;0.2&#x2003;&#x2003;MathematicalFormula2:

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Kanagawa, Japan

Manabu Nishijima