Mitsubishi Jukogyo Kabushiki Kaisha

Mamoru Tamai

Toshiro Okamoto

Michio Ohshima

Makoto Kamisaka

Kenichi Yoneda

Kiyomichi Taoda

Naruo Yokoyama

Tetsuya Imai

Hiroshi Fujita

Mitsuharu Murakami

Yoshifumi Ito

Yoshio Miyairi

Fumiaki Sato

Masatoshi Katayama

Takeyasu Watanabe

Michio Teramoto

A process for methanol which comprises cracking 100 moles of methanol in admixture with 1 to 99 moles of water, thereby obtaining a gas containing hydrogen and carbon monoxide, is described. The process is preferably carried out using a catalyst which consists of a carrier comprising copper and chromium oxides with or without manganese oxide and/or barium oxide and a catalytic component of nickel oxide or a mixture of nickel oxide and a basic oxide.

Process for reforming methanol

There is provided a process for the heat treatment of coal which comprises heating and drying low grade coal such as subbituminous coal and brown coal containing less than 80% of carbon and more than 33% of volatile matter (dry mineral matter-free basis) and having a high moisture content and a particle diameter smaller than 2 inches, with a high-temperature gas containing less than 5% of oxygen in a fluidized bed for 2-10 minutes until the coal temperature reaches 180.degree.-400.degree. C., and subsequently cooling the coal by spraying water in a fluidized bed for 2-10 minutes until the coal temperature decreases to 60.degree. C. or below at which time the coal holds the maximum moisture given by wetting. The heating process may be performed in two steps, in which case coal is heated with a high-temperature gas to 80.degree.-150.degree. C. in the first step so that the moisture of coal is reduced below the inherent moisture. The cooling process may be performed in two steps, in which case heated coal is rapidly cooled to about 120.degree. C. with a cooling gas of high steam content in the first step.

Process for heat treatment of coal

Gas-liquid contactor

In methods of manufacturing olefines by thermally cracking hydrocarbons, there is disclosed a thermal cracking method for producing olefines from hydrocarbons, characterized in that hydrocarbon in burnt with oxygen in the presence of steam to generate a high-temperature gas containing steam of 1500.degree.-3000.degree. C., methane and hydrogen are supplied into the high-temperature gas containing said steam, with the molar ratio of methane to hydrogen in said high temperature gas being 0.05 or more, then hydrocarbon to be cracked is supplied into said high-temperature gas containing said methane, hydrogen and steam, so that the hydrocarbon is subjected to thermal cracking by maintaining the partial pressure of hydrogen at more than at least 0.1 bar at the outlet of a reactor, under conditions of reaction temperature, 800.degree.-1200.degree. C. and residence time in the reactor 5-300 milli second, and then the reaction product is cooled in a rapid manner.

Thermal cracking method for producing olefines from hydrocarbons

In methods of manufacturing olefines by thermally cracking hydrocarbons, there is disclosed a thermal cracking method for producing olefines from hydrocarbons, characterized in that hydrocarbon is burnt with oxygen in the presence of steam to generate a high-temperature gas containing steam of 1500.degree.-3000.degree. C.; methane and hydrogen are supplied into the high-temperature gas containing said steam, with the molar ratio of methane to hydrogen in said high-temperature gas being 0.05 or more, then hydrocarbon to be cracked is supplied into said high-temperature gas containing said methane, hydrogen and steam, so that the hydrocarbon is subjected to thermal cracking by maintaining the partial pressure of hydrogen at more than at least 0.1 bar at the outlet of a reactor, under conditions of reaction temperature, 800.degree.-1200.degree. C. and residence time in the reactor 5-300 milli second, and then the reaction product is cooled in a rapid manner.

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Hiroshima, Japan

Mamoru Tamai