Mitsubishi Chemical Corporation

Nippon Chemi-con Corporation

Mitsubishi Petrochemical Company Limited

Seiko Epson Corporation

Sanyo Electric Co., Ltd.

Makoto Ue

Masayuki Takeda

Masashi Ozawa

Masahiro Takehara

Shoichiro Mori

Fumikazu Mizutani

Hiroo Miyauchi

Kazuhiko Ida

Takako Takahashi

Tomohiro Sato

Tatsunori Tsuji

Sachie Takeuchi

Shin Fujitani

Shinichi Kinoshita

Yutaka Yokoyama

Takashi Fujii

Takashi Inoue

Minoru Kotato

Maruo Kamino

Takumi Seki

Hitoshi Suzuki

Minoru Wada

Takeyoshi Ushiki

Kunihisa Shima

Noriyuki Tamura

Toshikazu Yoshida

Kenji Shizuka

Daisuke Noda

Hiroshi Takaha

Masahi Ozawa

Masayuku Takeda

Tomohiro Satoh

Sachie Sekigawa

A nonaqueous electrolyte secondary battery in which the decomposition of an electrolyte solution is reduced exhibits high coulombic efficiency and excellent charge and discharge cycle performance, and has high energy density. This nonaqueous electrolyte secondary battery includes a negative electrode that is formed by depositing a thin film of active material on a collector by a CVD method, sputtering, evaporation, thermal spraying, or plating, wherein the thin film of the active material can lithiate and delithiate and is divided into columns by cracks formed in the thickness direction, and the bottom of each column is adhered to the collector; a positive electrode that can lithiate and delithiate; and a nonaqueous electrolyte solution containing a lithium salt in a nonaqueous solvent. The electrolyte solution contains a compound expressed by a general formula (I).R-M=0&#x2003;&#x2003;(I)(wherein, Rs are alkyl groups optionally having a substituent, may be identical or different from one another, may be independent substituents, or may be bound together to form a ring; M is S or P; and n is 2 when M is S and is 3 when M is P).

Nonaqueous electrolyte solution for secondary battery and nonaqueous electrolyte secondary battery

An electrolytic capacitor having a low impedance characteristic, having a high withstand voltage characteristic of 100V class, wherein the electrolytic capacitor provides an excellent high temperature life characteristic and an excellent leakage characteristic. The electrolyte solution containing the aluminum tetrafluoride salt is used. The electrolytic capacitor of the present invention has a low impedance characteristic, a high withstand voltage characteristic, and an excellent high temperature life characteristic. Moreover, the aforementioned electrolyte solution is used, and a foil showing noble potential at least in the electrolyte solution than the electrode potential of the cathode tab, or a cathode electrode foil subjected to chemical treatment is used as the cathode electrode foil, so as to obtain an excellent leakage characteristic.

Electrolytic capacitor

An electrolytic capacitor having a low impedance characteristic, having a high withstand voltage characteristic of 100V class, wherein the electrolytic capacitor provides an excellent high temperature life characteristic. The electrolyte solution containing the aluminum tetrafluoride salt is used. The moisture content of the capacitor element is adjusted to 0.7% by weight or less, wit respect to the weight of the capacitor element, preferably 0.5% by weight or less, and most preferably 0.4% by weight or less. In this way, the electrolytic capacitor having the low impedance characteristic and the high resistance voltage characteristic, and the excellent high temperature life characteristic is provided.

Electrolytic capacitor manufacturing method

An electrolyte for an electrolytic capacitor which is high in electrolytic conductivity, excellent in heat stability and high in withstand voltage. An electrolyte for an electrolytic capacitor comprising a tetrafluoroaluminate ion; and an electrolyte for an electrolytic capacitor containing a salt and a solvent, characterized in that electrolytic conductivity X (mS&#xb7;cm) at 25&#xb0; C. and withstand voltage Y (V) of a capacitor satisfy the relationships of formulae (I): Y&#x2267;&#x2212;7.5X+150, and X&#x2267;4, Y&#x3e;0.

Electrolyte for electrolytic capacitor and electrolytic capacitor using the same

Electrolyte solution and an electrolytic capacitor using it having a low impedance characteristic, having a high withstand voltage characteristic of 100V class, and a high temperature life characteristic is provided. The electrolyte solution containing an aluminum tetrafluoride salt, and a solvent with high boiling point, such as sulfolane, 3-methyl sulfolane, and 2,4-dimethyl sulfolane, and the like are used. The electrolytic capacitor of the present invention has a low impedance characteristic, a high withstand voltage characteristic, and an excellent high temperature life characteristic.

Electrolyte for electrolytic capacitor and electrolytic capacitor containing the same

There are provided an aluminum electrolytic capacitor comprising an anode, a cathode comprising aluminum and an electrolytic solution containing an onium salt of fluorine-containing anion, wherein the electrolytic solution has a water concentration of 1% by weight or less, or wherein the cathode has a peak top of Al2p spectrum of 74.0 to 75.8 eV as measured by a method in which the surface of the cathode in the aluminum electrolytic capacitor heated at 125&#xb0; C. for 50 hours is analyzed by X-ray photoelectron spectroscopy (XPS); an electrolytic solution for electrolytic capacitor comprising a quaternary cyclic amidinium tetrafluoroaluminate and a solvent and containing specific impurity compounds in a total amount of 0.6% by weight or less, and an electrolytic capacitor using the electrolytic solution; and a method for preparing an organic onium tetrafluoroaluminate which is advantageously used in an aluminum electrolytic capacitor.

Electrolyte for electrolytic capacitor, electrolytic capacitor and process for producing tetrafluoroaluminate salt of organic onium

An electrolytic capacitor having a low impedance characteristic, and a high withstand voltage characteristic in the 100V class, provides excellent high temperature life and leakage characteristics. An electrolyte solution containing an aluminum tetrafluoride salt is used. Moreover, a ceramics coating layer or an insulating synthetic resin layer is formed at a contact portion with a sealing component of a rivet or a cathode leading means. Alternatively, a partial cross-linking peroxide butyl rubber with added peroxide as a cross-linking agent to a butyl rubber polymer containing isobutylene, isoprene, and divinylbenzene copolymer is used as the sealing member. The electrolytic capacitor of the present invention has a low impedance characteristic, a high withstand voltage characteristic, and an excellent high temperature life characteristic.

A non-aqueous electrolyte solution that contains an organic solvent, and a lithium salt and an electrolyte, that is useful for the preparation of a secondary battery that is equipped with a negative electrode and a positive electrode, each of which is capable of storing and releasing lithium, wherein the non-aqueous electrolyte solution contains partially hydrogenated terphenyl that is a mixture of two or more compounds of which one is diphenylcyclohexane that is present in an amount ranging from 10 to 65 wt % of the partially hydrogenated terphenyl and the partially hydrogenated terphenyl has a solubility of not less than 0.5 wt % in the electrolyte solution at room temperature.

Non-aqueous electrolyte solution and non-aqueous electrolyte solution secondary battery using the same

An object of the present invention is to provide an electrolyte for an electrolytic capacitor, which is advantageous not only in that both electric conductivity and withstand voltage property are high, but also in that thermal stability is excellent, and an electrolytic capacitor using the electrolyte. Specifically, the present invention provides an electrolyte for an electrolytic capacitor, comprising a solvent, at least one quaternary amidinium salt selected from the group consisting of a quaternary amidinium salt of a hydroxy-substituted aromatic monocarboxylic acid and a quaternary amidinium salt of phthalic acid, and metal oxide particles, and an electrolytic capacitor using the electrolyte.

Electrolytic solution for electrolytic capacitor and electrolytic capacitor using the same

An electrolyte for an electrolytic capacitor which is high in electrolytic conductivity, excellent in heat stability and high in withstand voltage. An electrolyte for an electrolytic capacitor including a tetrafluoroaluminate ion; and an electrolyte for an electrolytic capacitor containing a salt and a solvent, characterized in that electrolytic conductivity X (mS&#xb7;cm) at 25&#xb0; C. and withstand voltage Y (V) of a capacitor satisfy the relationships of formulae (I):Y&#x2267;&#x2212;7.5X+150, and X&#x2266;4, Y&#x3e;0.

A nonaqueous electrolyte solution for secondary batteries which is an electrolyte solution for secondary batteries obtained by dissolving a lithium salt in a nonaqueous solvent, wherein the nonaqueous solvent is a solvent mainly comprising a lactone compound and the content of hydroxy carboxylic acids in the electrolyte solution is 1 mmol/kg or lower and a secondary battery employing the same are excellent in high-temperature storage characteristics, cycle characteristics, and capacity retention characteristics and in various cell characteristics in a wide temperature range and safety such as firing properties.

Nonaqueous electrolyte solution and secondary battery employing the same

A non-aqueous electrolyte comprises an organic solvent and a solute, and also has an electrolytic conductivity that is greater than or equal to 1 mS/cm but less than or equal to 100 mS/cm. This solute preferably includes at least one of a carboxylate and a salt of inorganic oxoacid. In addition, the non-aqueous electrolyte preferably comprises water in a proportion of 1 to 10 wt %. In an MIM nonlinear element ( ), an insulated film ( ) is formed by anodic oxidation using the above non-aqueous electrolyte. In addition, the insulated film comprises at least one of carbon atoms and atoms of families 3 to 7 that were originally the central atoms of the salt of inorganic oxoacid, and has a relative permittivity of 10 to 25. With this MIM nonlinear element, the capacitance is sufficiently small, the steepness of the voltage-current characteristic is sufficiently large, and also the resistance is sufficiently uniform over a wide area.

Method of fabricating two-terminal nonlinear element using non-aqueous electrolyte

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Ibaraki, Japan

Makoto Ue