Kao Corporation

Makoto Torizuka

Akira Kawamata

Noboru Nagatani

Masahiko Asahi

Tadayuki Tokunaga

Jouji Okada

Satoshi Sugawara

Toru Nishimura

Keiichi Tsuto

Yoshinobu Imaizumi

Kentaro Oshima

Shunji Kozaki

Takashi Oda

Takashi Komori

Toshio Miyake

Hirohisa Suzuki

Katsuhiko Rindo

Kazuhiro Yamaki

Nobushige Tanaka

Kana Fujiwara

Emulsified, water-in-oil type composition and skin cosmetic preparation

Compounds represented by the following general formula: ##STR1## wherein Rf and Rf' mean a perfluoroalkyl group having 1-20 carbon atoms or a (.omega.-H-perfluoroalkyl group represented by the formula H(CF.sub.2).sub.t in which t stands for an integer of 1-20, R.sup.2 denotes a hydrogen atom, a straight-chain or branched aliphatic hydrocarbon group having 1-20 carbon atoms, an alicyclic or aromatic hydrocarbon group having 5-10 carbon atoms, a perfluoroalkyl group having 1-20 carbon atoms, or .omega.-H-perfluoroalkyl group represented by the formula H(CF.sub.2).sub.u - in which u stands for an integer of 1-20, X and Y mean individually a single bond, --CO-- or a divalent hydrocarbon group having 1-6 carbon atoms, l stands for a number of 2-16, and m and n are individually a number of 1-6. The compounds are useful for preparing fluorine-modified silicone derivatives suitable for cosmetic compositions.

Fluoroalkyl substituted ethylenically unsaturated compounds

The present invention is directed to cosmetic compositions containing a fluorine-modified silicon derivative the organopolysiloxane chain which is partly substituted by the siloxane chain of the following general formula (1), (2) or (3) ##STR1## wherein Rf and Rf' mean individually a perfluoroalkyl group having 1-20 carbon atoms or a .omega.-H-perfluoroalkyl group represented by the formula H(CF.sub.2).sub.t -- in which t stands for an integer of 1-20, R.sup.1 may be identical with or different from each other and means a straight-chain or branched aliphatic hydrocarbon group having 1-20 carbon atoms, or an alicyclic or aromatic hydrocarbon group having 5-10 carbon atoms, R.sup.2 denotes a hydrogen atom, a straight-chain or branched aliphatic hydrocarbon group having 1-20 carbon atoms, an alicyclic or aromatic hydrocarbon group having 5-10 carbon atoms, a perfluoroalkyl group having 1-20 carbon atoms, or a .omega.-H-perfluoroalkyl group represented by the formula H(CF.sub.2).sub.u -- in which u stands for an integer of 1-20, R.sup.3 is a divalent hydrocarbon group having 2-16 carbon atoms, X and Y mean individually a single bond, --CO-- or a divalent hydrocarbon group having 1-6 carbon atoms, l stands for a number of 2-16, m and n are individually a number of 1-6, and r is a number of 0-50.

Fluorine-modified silicone derivative, production thereof, and cosmetic

Ultraviolet shielding composite fine particles, method for producing the

The present invention is directed to a fluorine-modified silicone derivative the organopolysiloxane chain which is partly substituted by the siloxane chain of the following general formula (1), (2) or (3), a preparation process thereof, intermediates useful for the preparation thereof and cosmetic compositions containing this derivative. ##STR1## wherein Rf and Rf' mean individually a perfluoroalkyl group having 1-20 carbon atoms or a .omega.-H-perfluoroalkyl group represented by the formula H(CF.sub.2).sub.t -- in which t stands for an integer of 1-20, R.sup.1 may be identical with or different from each other and means a straight-chain or branched aliphatic hydrocarbon group having 1-20 carbon atoms, or an alicyclic or aromatic hydrocarbon group having 5-10 carbon atoms, R.sup.2 denotes a hydrogen atom, a straight-chain or branched aliphatic hydrocarbon group having 1-20 carbon atoms, an alicyclic or aromatic hydrocarbon group having 5-10 carbon atoms, a perfluoroalkyl group having 1-20 carbon atoms, or a .omega.-H-perfluoroalkyl group represented by the formula H(CF.sub.2).sub.u --in which u stands for an integer of 1-20, R.sup.3 is a divalent hydrocarbon group having 2-16 carbon atoms, X and Y mean individually a single bond, --CO-- or a divalent hydrocarbon group having 1-6 carbon atoms, l stands for a number of 2-16, m and n are individually a number of 1-6, and r is a number of 0-50. Cosmetic compositions containing this compound have excellent water and oil repellency and are also good in lastingness of makeup and feeling upon use.

Cosmetics comprising a hydrophobic powder or a fluorine compound-treated powder, and a liquid perfluoro organic compound are disclosed. These cosmetics are excellent in water repellency, water resistance, sebum resistance and oil resistance, prevents cosmetic components from the removal due to sweat or sebum, shows a good spreadability on the skin and gives a desirable feel at the use, for example, a moist and refreshing feel.

Cosmetic

Fluorine-modified silicone derivative, production thereof and cosmetic

A fluorine-modified silicon compound having a polymerization degree of from 1 to 400 and containing at least one siloxane unit represented by formula (1): ##STR1## wherein R.sup.1 represents an aliphatic straight-chain or branched hydrocarbon group having 1 to 20 carbon atoms or an alicyclic hydrocarbon group having 5 to 10 carbon atoms or an aromatic hydrocarbon compound having 6 to 10 carbon atoms; and m represents 0 or an integer of from 1 to 10; a process for preparing the same; and a cosmetic containing the same are disclosed. The fluorine-modified silicone derivative exhibits high water- and oil-repellency to provide cosmetics which wear long and have a good feel on use.

Fluorine-modified silicone, process for preparing the same, and

Growing community of inventors

Tokyo, Japan

Makoto Torizuka