Kao Corporation

Makoto Okubo

Kazunari Takemura

Masahiro Mori

Masaaki Shimoda

Toshimasa Hamai

Akito Itoi

Takayuki Nomura

Takeshi Tomifuji

Shoichiro Harada

Masato Nomura

Mitsuru Sakai

Kenichi Miyamoto

Ryoichi Hashimoto

Takao Taniguchi

Kazuhiko Kiuchi

Minoru Sawai

Atsushi Ishikawa

Hiroshi Kitagawa

Kazuo Fukumoto

Kenichi Suzuki

The present invention provides the early strengthening agent for hydraulic compositions containing a compound (a) obtained by reacting (A) one or more compounds selected from polyhydric alcohols having 3 to 20 hydroxy groups and alkylene oxide adducts thereof with (B) a sulfating agent, and the additive composition for hydraulic compositions containing the compound (a).

Early strengthening agent for hydraulic composition

The present invention produces the hydraulic powder through grinding of the hydraulic compound in the presence of a compound (a) prepared by reacting (A) at least one compound selected from polyhydric alcohols and alkylene oxide adducts thereof with (B) a sulfating agent.

Method for producing hydraulic powder

In a method for improving antistatic properties, the improvement comprising the use of an antistatic composition comprising an ionic antistatic compound and a polar organic solvent; an antistatic composition comprising a nonmetallic antistatic compound, a metallic antistatic compound and a polar organic solvent; a formed article containing an antistatic composition comprising an ionic antistatic compound and a polar organic solvent; and a process for producing a polyurethane foam comprising reacting a polyol solution comprising a polyol component, a blowing agent and a catalyst, with an isocyanate prepolymer in the presence of an antistatic composition comprising an ionic antistatic compound and a polar organic solvent. The antistatic composition can be suitably used as shoe soles for safety shoes, working shoes, and the like.

Antistatic composition

Process for producing a molded article comprising pouring or injecting a liquid molding material into a mold in the presence of a surface-treating agent comprising a contact angle-reducing substance under the condition that the contact angle between the liquid molding material and the inner surface of the mold is not more than 30&deg;, and curing the liquid molding material; surface-treating agent comprising a contact angle-reducing substance which reduces the contact angle between the liquid molding material and a flat plate made of the same material as the mold to not more than 30&deg;; method for reducing surface voids during molding, comprising using the above surface-treating agent; and use of the above surface-treating agent for reducing surface voids. The molded article has a shape accurately corresponding to the shape of an inner surface of a mold.

Process for producing molded article

Microcellular polyurethane elastomer shoe sole components having exceptional physical properties may be prepared from isocyanate-terminated prepolymers derived from polyoxypropylene diols having a molecular weight of from about 2000 Da to 8000 Da, an unsaturation less than about 0.02 meq/g, and a random oxyethylene content of from about 5 to about 15 weight percent. The shoe sole components exhibit high tensile strength, elongation, resilience, and in addition have excellent tear strength, particularly 90&deg; angle tear.

Polyurethane foam for shoe soles

A process for preparing a polyurethane foam comprising, reacting a polyol composition comprising a polyol component containing a polyoxypropylene-based polyol having an unsaturation degree of not more than 0.06 meq/g, a catalyst and water with a polyisocyanate compound. The polyurethane foam can be suitably used as shoe soles and the like.

Process for preparing polyurethane foam

A polyester-polyol being liquid at 40&deg; C. and having a viscosity of not more than 10,000 mPa&middot;s at 60&deg; C., prepared by polycondensation of an acid component including at least one phthalic acid component selected from phthalic anhydride and o-phthalic acid, and an aliphatic polybasic acid, with a polyhydric alcohol; a process for preparing a polyurethane foam including reacting a polyisocyanate component with a polyol component including the polyester-polyol; a process for preparing an isocyanate prepolymer from a polyisocyanate component and a polyol component including the polyester-polyol; and a process for preparing a polyurethane foam including reacting an isocyanate prepolymer prepared from a polyisocyanate component and a polyol component including the polyester-polyol, with a polyol component. The resulting polyurethane foam shows remarkably improved physical properties such as tensile strength and tear strength, while having low density, acceptable appearance and texture.

Low viscosity polyester-polyols and polyurethane foams prepared therefrom

Urethane foam for shoe soles

A polyester-polyol prepared by polycondensation of an acid component comprising terephthalic acid and adipic acid, and a polyhydric alcohol component, wherein the molar ratio of the terephthalic acid/adipic acid is 0.05 to 0.3; a process for preparing a polyurethane foam comprising reacting a polyisocyanate component and a polyol component, wherein the polyol component contains the above polyester-polyol; and a process for preparing a polyurethane foam comprising reacting an isocyanate prepolymer made of a polyisocyanate component and a polyol component (I) with a polyol component (II), wherein the polyol component (I) comprises the above polyester-polyol.

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Wakayama, Japan

Makoto Okubo