Mitsubishi Gas Chemical Company, Inc.

Hitachi Automotive Systems, Ltd.

Mitsubishi Electric Corporation

Maki Ito

Hidefumi Harada

Takehiko Isobe

Yoshinori Isahaya

Yousuke Shinkai

Atsushi Hirashima

Jun-ya Hayakawa

Taichi Tokutake

Toshiaki Ishii

Tomoyuki Yui

Masahiro Johno

Yuki Motoyama

Hiroshi Mineta

Keisuke Shimokawa

Yoshio Kawai

Masahiko Asano

Hongyu Liu

Kyohei Takakuwa

Teruyo Tomiyama

Takahiro Matsumoto

Yujiro Kaneko

Akitoyo Konno

Nobutake Tsuyuno

Masaru Kamoshida

Hirohiko Higuchi

Takayasu Fujimori

Hideto Yoshinari

Mitsuo Miura

Masato Saito

Takayuki Fukuzawa

Hiroki Furuhashi

Kunitoshi Mimura

Yuusuke Yasuda

Noriko Dodo

Hayakawa Jun-Ya

Jun-Ya Hayakawa

Display screen with animated graphical user interface

Provided is a box-type vehicle-mounted control device that effectively increases the amount of heat transfer from electronic components and a circuit board to a casing (base and cover) and that accordingly has achieved excellent heat dissipation property. The box-type vehicle-mounted control device includes a circuit board, a base, and a cover. In addition, a first heat radiating coating layeris formed on at least one surface of the circuit board, and a second heat radiating coating layeris formed on an inner surface of one or both of the baseand the coverfacing the first heat radiating coating layer

Box-type vehicle-mounted control device

Provided is a manufacturing method for a high molecular weight aromatic polycarbonate resin that has superior fluidity and for which a good color and a sufficiently high molecular weight can be achieved. A manufacturing method for a high molecular weight aromatic polycarbonate resin includes: a step in which a dialcohol compound expressed by general formula (1) and a catalyst are mixed to obtain a catalyst composition; a step in which the obtained catalyst composition is kept in a molten state, and is mixed with an aromatic polycarbonate prepolymer within ten hours after obtaining the catalyst composition, to obtain a prepolymer mixture; and a high molecular weight achievement step in which the obtained prepolymer mixture is heat-treated under reduced pressure conditions to obtain a high molecular weight aromatic polycarbonate resin.

Manufacturing method for high molecular weight aromatic polycarbonate resin

Provided is a high molecular weight aromatic polycarbonate resin manufacturing method that suppresses the occurrence of heterogeneous structures and can achieve a sufficiently high molecular weight. A high molecular weight aromatic polycarbonate resin manufacturing method including: a step in which a dialcohol compound expressed by general formula (1) and a catalyst are mixed to obtain a catalyst composition; a step in which the obtained catalyst composition is transferred to a prepolymer mixing tank via a transfer pipe, with a transfer period of 10 hours or less; a step in which the transferred catalyst composition and an aromatic polycarbonate prepolymer are mixed in the prepolymer mixing tank to obtain a prepolymer mixture; and a high molecular weight achievement step in which the obtained prepolymer mixture is heat-treated under reduced pressure conditions to obtain a high molecular weight aromatic polycarbonate resin.

A high molecular weight aromatic polycarbonate resin manufacturing method that can achieve good quality and sufficiently high molecular weight includes: a step in which a dialcohol compound expressed by general formula (1) and a catalyst are mixed to obtain a catalyst composition; a step in which the obtained catalyst composition is transferred to a prepolymer mixing tank via a transfer pipe; a step in which the transferred catalyst composition and an aromatic polycarbonate prepolymer are mixed in the prepolymer mixing tank, under a pressure that is greater than or equal to the vapor pressure of the dialcohol compound at the temperature of the prepolymer mixing tank and is less than or equal to 5 MPa, to obtain a prepolymer mixture; and a high molecular weight achievement step in which the obtained prepolymer mixture is heat-treated under reduced pressure conditions to obtain a high molecular weight aromatic polycarbonate resin. 

High molecular weight aromatic polycarbonate resin manufacturing method

An object is to provide the structure of an ECU enabling resin to be filled without deformation of an electronic circuit board. A resin-sealed vehicle-mounted control device includes: a circuit board; a base member housing the circuit board; and resin filled between the circuit board and the base member. The base member has: a base portion fixing the circuit board; and a side wall opposed to the side surface side of the circuit board. The resin is provided at least between the circuit board and the base portion. The side wall has an opening at any position on the side of the base portion from a position opposed to the side surface side of the electronic circuit board.

Resin-sealed vehicle-mounted control device

The invention provides an in-vehicle controller equipped with a heat radiation coating film which can efficiently radiate heat from a high temperature portion such as a heat generating body to a casing. An in-vehicle controller includes a heat radiation coating film, wherein the heat radiation coating film includes a first region that has a first boundary surface abutting on a base material, and a second region that has a second boundary surface where the heat radiation coating film abuts on air, wherein a thermal conductivity of the first region is higher than that of the second region, and wherein a thermal emissivity of the second region is higher than that of the first region.

In-vehicle controller

Copolymer having high fluidity and high molecular weight which is formed of a structural unit derived from an aliphatic diol compound and a structural unit derived from an aromatic dihydroxy compound. A polycarbonate resin composition is also provided comprising a highly polymerized aromatic polycarbonate resin as a main component and also comprising cyclic carbonate present in an amount of not more than 3000 ppm, wherein the highly polymerized aromatic polycarbonate resin is produced by a process which comprises a highly-polymerizing process wherein an aromatic polycarbonate is reacted with an aliphatic diol compound in the presence of a transesterification catalyst to increase the molecular weight.

High-fluidity polycarbonate copolymer, process for production highly polymerized aromatic polycarbonate resin and aromatic polycarbonate compound

The present invention is to provide a process for producing a high molecular-weight aromatic polycarbonate resin, the process includes mixing a dialcohol compound represented by the following Formula (1) with a first catalyst to obtain a catalyst composition; mixing the obtained catalyst composition with an aromatic polycarbonate prepolymer to obtain a prepolymer mixture; and obtaining a high molecular-weight aromatic polycarbonate by subjecting the obtained prepolymer mixture to heating treatment under reduced pressure condition. In the Formula (1), Rto Reach independently represent a hydrogen atom, an alkyl group and the like. Q represents a divalent group or a single bond. 

Process for producing a high molecular-weight aromatic polycarbonate resin

The present invention provides a method for producing a branched aromatic polycarbonate resin that is molecular weight-increased, which comprises subjecting an aromatic polycarbonate prepolymer and a linking agent comprising a trifunctional or more of an aliphatic polyol compound to transesterification reaction in the presence of a transesterification catalyst under a reduced pressure condition.

Method for producing branched aromatic polycarbonate resin

The present invention is to provide a process for preparing a highly polymerized aromatic polycarbonate resin, which comprises the steps of a highly polymerizing step for reacting an aromatic polycarbonate prepolymer and an aliphatic diol compound in the presence of a transesterification catalyst to obtain a highly polymerized aromatic polycarbonate resin, a cyclic carbonate removal step for removing at least part of the cyclic carbonate by-produced in the above highly polymerizing step out of the reaction system, and a recycle step of hydrolyzing the cyclic carbonate removed in the cyclic carbonate removal step to obtain an aliphatic diol compound and using the obtained aliphatic diol compound as at least a part of the aliphatic diol compound to be used in the highly polymerizing step.

Process for preparing highly polymerized aromatic polycarbonate resin

The invention provides a process for producing a highly polymerized aromatic polycarbonate resin including a molecular weight-increasing step of reacting an aromatic polycarbonate prepolymer with an aliphatic diol compound represented by Formula (g2) in the presence of a transesterification catalyst to obtain a highly polymerized aromatic polycarbonate resin. In the formula, Ra and Rb each independently represent a hydrogen atom, a halogen atom, a linear or branched alkyl group, a cycloalkyl group, an aryl group or an alkoxy group, or Ra and Rb may be bonded to each other to form a ring; Rto Reach independently represent a hydrogen atom, a halogen atom or an alkyl group; and n represents an integer of 0 to 30.

Process for producing highly polymerized aromatic polycarbonate resin

The present invention provides a process for preparing a highly polymerized aromatic polycarbonate resin which not only has excellent quality such that it has high molecular weight and high fluidity, but also has more excellent heat resistance. The process of the present invention comprises a highly polymerizing step for reacting an aromatic polycarbonate prepolymer with an aliphatic diol compound of the following formula (I) having hydroxymethyl groups (HO&#x2014;CH&#x2014;) each bonded to a quaternary carbon atom in the presence of a transesterification catalyst to obtain a highly polymerized aromatic polycarbonate resin: wherein Ra to Rf, n, and m are as defined in the present specification and claims.

The present invention provides an aromatic polycarbonate resin composition having a high molecular weight and less amount of a heterologous structure, retaining good qualities, and excellent in thermal stability, and an improved preparation process thereof.

Aromatic polycarbonate resin composition

The present inventions provide processes for producing a highly polymerized aromatic polycarbonate resin comprising a highly-polymerizing process wherein an aromatic polycarbonate is reacted with an aliphatic diol compound represented by formula (g1) in the presence of a transesterification catalyst to increase the molecular weight: wherein Ra and Rb each independently represent a hydrogen atom, a linear or branched alkyl group having 1-12 carbon atoms or a phenyl group, and 'm' represents an integer of 1-30.

Growing community of inventors

Tokyo, Japan

Maki Ito