Lockheed Martin Corporation

William Marsh Rice University

Madhuri Thakur

Michael Wong

Steven L Sinsabaugh

Sibani Lisa Biswal

Mark Joseph Isaacson

Michael S Wong

Sibani L Biswal

Embodiments of the present disclosure pertain to porous silicon particulates and anode materials that contain them. In some embodiments, each of the porous silicon particulates include a plurality of macropores, mesopores and micropores such that the micropores and mesopores are within the macropores. The porous silicon particulates also contain: a coating associated with the porous silicon particulates; and a binding material associated with the porous silicon particulates. The binding material can include binders, carbon materials, polymers, metals, additives, carbohydrates, and combinations thereof.

Porous silicon particulates with micropores and mesopores within macropores

In some embodiments, the present invention provides novel methods of preparing porous silicon films and particles for lithium ion batteries. In some embodiments, such methods generally include: (1) etching a silicon material by exposure of the silicon material to a constant current density in a solution to produce a porous silicon film over a substrate; and (2) separating the porous silicon film from the substrate by gradually increasing the electric current density in sequential increments. In some embodiments, the methods of the present invention may also include a step of associating the porous silicon film with a binding material. In some embodiments, the methods of the present invention may also include a step of splitting the porous silicon film to form porous silicon particles. Additional embodiments of the present invention pertain to anode materials derived from the porous silicon films and porous silicon particles.

Anode battery materials and methods of making the same

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Madhuri Thakur