Uniwersytet Jagiellonski

Maciej Hodorowicz

Janusz Szklarzewicz

A molecular magnetic material comprising salt molecules of a hexsacyanide tungsten anion complex of the formula: [WIV(CN)6(NN)]2-, a hexsacyanide tungsten anion complex of the formula: [WV(CN)6(NN)]—, wherein: W is a tungsten cation, CN is a cyano ligand, and NN is an NN-donating bidentate organic ligand forming a five-membered ring with the tungsten atom; and at least one type of a cation [A]n+¬, where n is an integer in the range of 1 to 4.

Molecular magnetic material and a method for preparation thereof

A method for synthesising a molecular magnetic material from a paramagnetic reactant including a d-electron metal in a paramagnetic form, a diamagnetic reactant comprising a d-electron metal in a diamagnetic form, and at least one donor of cyanide (CN&#x2014;) ligands being a separate compound and/or contained in the paramagnetic reactant and/or in the diamagnetic reactant.

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Cracow, Poland

Maciej Hodorowicz