Symyx Technologies, Inc.

Enovix Corporation

Intermolecular, Inc.

Symyx Solutions, Inc.

Freeslate, Inc.

Enovix Operations Inc.

Lynn Van Erden

John F Varni

Christopher J Spindt

Murali Ramasubramanian

Ashok Lahiri

Robert S Busacca

Harrold Jones Rust, Iii

James D Wilcox

Nirav S Shah

Bruno A Valdes

Kim Han Lee

Richard J Contreras

Gardner Cameron Dales

Geoffrey Matthew Ho

Jeremie James Dalton

Ken S Matsubayashi

Jason N Howard

Robert Keith Rosen

David M Lowe

Vladimir K Dioumaev

Anthony F Volpe

Yumin Liu

Claus G Lugmair

Michael J Armstrong

Anthony Calcaterra

William H Chandler, Jr

Neelam Singh

Jeffrey Glenn Buck

Kim Lester Fortunati

Neal Sarswat

Thomas John Schuerlein

Jonathan C Doan

Joshua David Winans

Xiao Ping Zhou

Benjamin L Cardozo

Howard W Turner

Alfred Gerhard Hagemeyer

Shenheng Guan

Ravi Srinivasan

Robert C Haushalter

Trevor G Frank

Xuejun Jason Wang

Adam Luke Safir

G Cameron Dales

H Sam Bergh

Rakesh Jain

Matthew F Smith

Thomas R Boussie

Eric W McFarland

Ralph B Nielsen

Keith Hall

Alfred Hagemeyer

Vince J Murphy

Christopher Goh

Youqi Wang

Jason Wells

Peijun Cong

Thomas Harding McWaid

Pei Wang

Richard Tiede

Tony N Wheeler

Victor Wong

Stephen J Turner

John Gallipeo

Christopher E Dube

Sam Bergh

Steven D Lacy

Jeffrey Maag

Iii Harrold J Rust

Jason Newton Howard

Harrold Jones Rust Iii

A secondary battery is provided for cycling between a charged and a discharged state, the secondary battery including a battery enclosure, an electrode assembly, carrier ions, a non-aqueous liquid electrolyte within the battery enclosure, and a set of electrode constraints. The set of electrode constraints includes a primary constraint system having first and second primary growth constraints and at least one primary connecting member, the first and second primary growth constraints separated from each other in the longitudinal direction, wherein the primary constraint array restrains growth of the electrode assembly in the longitudinal direction such that any increase in the Feret diameter of the electrode assembly in the longitudinal direction over 20 consecutive cycles of the secondary battery is less than 20%. The set of electrode constraints further includes a secondary constraint system having first and second secondary growth constraints connected by at least one secondary connecting member, wherein the secondary constraint system at least partially restrains growth of the electrode assembly in a second direction upon cycling of the secondary battery.

Dimensional constraints for three-dimensional batteries

A energy storage device for cycling between a charged state and a discharged state, the energy storage device including an enclosure, an electrode assembly and a non-aqueous liquid electrolyte within the enclosure, and a constraint that maintains a pressure on the electrode assembly as the energy storage device is cycled between the charged and the discharged states.

Longitudinal constraints for energy storage devices

Embodiments of secondary batteries having electrode assemblies are provided. A secondary battery can comprise an electrode assembly having a stacked series of layers, the stacked series of layers having an offset between electrode and counter-electrode layers in a unit cell member of the stacked series. A set of constraints can be provided with a primary constraint system with first and second primary growth constraints separated from each other in a longitudinal direction, and connected by at least one primary connecting member, and a secondary constraint system comprises first and second secondary growth constraints separated in a second direction and connected by members of the stacked series of layers. The primary constraint system may at least partially restrain growth of the electrode assembly in the longitudinal direction, and the secondary constraint system may at least partially restrain growth in the second direction that is orthogonal to the longitudinal direction.

Electrode assembly and secondary battery

A secondary battery for cycling between a charged and a discharged state, wherein a 2D map of the median vertical position of the first opposing vertical end surface of the electrode active material in the X-Z plane, along the length LE of the electrode active material layer, traces a first vertical end surface plot, EVP1, a 2D map of the median vertical position of the first opposing vertical end surface of the counter-electrode active material layer in the X-Z plane, along the length LC of the counter-electrode active material layer, traces a first vertical end surface plot, CEVP1, wherein for at least 60% of the length LC of the first counter-electrode active material layer (i) the absolute value of a separation distance, SZ1, between the plots EVP1 and CEVP1 measured in the vertical direction is 1000 μm≥|SZ1|≥5 μm.

Constrained electrode assembly

Secondary batteries and methods of manufacture thereof are provided. A secondary battery can comprise an offset between electrode and counter-electrode layers in a unit cell. Secondary batteries can be prepared by removing a population of negative electrode subunits from a negative electrode sheet, the negative electrode sheet comprising a negative electrode sheet edge margin and at least one negative electrode sheet weakened region that is internal to the negative electrode sheet edge margin, removing a population of separator layer subunits from a separator sheet, and removing a population of positive electrode subunits from a positive electrode sheet, the positive electrode sheet comprising a positive electrode edge margin and at least one positive electrode sheet weakened region that is internal to the positive electrode sheet edge margin, and stacking members of the negative electrode subunit population, the separator layer subunit population and the positive electrode subunit population.

Electrode assembly, secondary battery, and method of manufacture

A secondary battery for cycling between a charged and a discharged state, wherein a 2D map of the median vertical position of the first opposing vertical end surface of the electrode active material in the X-Z plane, along the length LE of the electrode active material layer, traces a first vertical end surface plot, EVP1, a 2D map of the median vertical position of the first opposing vertical end surface of the counter-electrode active material layer in the X-Z plane, along the length LC of the counter-electrode active material layer, traces a first vertical end surface plot, CEVP1, wherein for at least 60% of the length Lc of the first counter-electrode active material layer (i) the absolute value of a separation distance, SZ1, between the plots EVP1 and CEVP1 measured in the vertical direction is 1000 &#x3bc;m&#x2265;|SZ1|&#x2265;5 &#x3bc;m.

A secondary battery for cycling between a charged and a discharged state, wherein a 2D map of the median vertical position of the first opposing vertical end surface of the electrode active material in the X-Z plane, along the length Lof the electrode active material layer, traces a first vertical end surface plot, E, a 2D map of the median vertical position of the first opposing vertical end surface of the counter-electrode active material layer in the X-Z plane, along the length Lof the counter-electrode active material layer, traces a first vertical end surface plot, CE, wherein for at least 60% of the length Lof the first counter-electrode active material layer (i) the absolute value of a separation distance, S, between the plots Eand CEmeasured in the vertical direction is 1000 &#x3bc;m&#x2265;|S|&#x2265;5 &#x3bc;m.

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Livermore, CA, United States of America

Lynn Van Erden