Schott Glaswerke

Other

Ludwig Ross

Volkmar Geiler

Burkhard Speit

Georg Gliemeroth

Karl Mennemann

Danuta Grabowski

Hans-Georg Krolla

Lothar Meckel

Uwe Eichhorn

Werner Schumann

Hans-Jurgen Hoffmann

Danuta Grabowski Geb Marszalek

Werener Schumann

Eva Holzel

Eva G Hoelzel

A method of production of mono- or multimodal lightwave guides from special substrate glasses of the glass system SiO.sub.2 -B.sub.2 O.sub.3 -Al.sub.2 O.sub.3 - K.sub.2 O-F.sup.-, with partial exchange of the Li.sup.+, Na.sup.+, and/or K.sup.+ ions present in the glass against Cs.sup.+ ions, the substrate glasses having the following compositions (in mol.-%): SiO.sub.2 45-72, B.sub.2 O.sub.3 8-25, Al.sub.2 O.sub.3 1-25, Li.sub.2 O 0-1, Na.sub.2 O 0-2, K.sub.2 O 6-18, MO 0-1 (MO= MgO, CaO, SrO, BaO, ZnO, PbO), in which a portion of the O.sup.- ions present in the glass are replaced by 1-15 mol % F.sup.- ions.

Lightwave guide produced by ion exchange of cs+ ions

Production of mono- or multimodal lightwave guides from special substrate glasses of the glass system SiO.sub.2 --B.sub.2 O.sub.3 --Al.sub.2 O.sub.3 -- K.sub.2 O--F.sup.-, with partial exchange of the Li.sup.+, Na.sup.+, and/or K.sup.+ ions present in the glass against Cs.sup.+ ions, the substrate glasses having the following compositions (in mol.-%): SiO.sub.2 45-72, B.sub.2 O.sub.3 8-25, Al.sub.2 O.sub.3 1-25, Li.sub.2 O 0-1, Na.sub.2 O 0-2, K.sub.2 O 6-18, MO 0-1 (MO=MgO, CaO, SrO, BaO, ZnO, PbO), in which a portion of the O.sup.- ions present in the glass are replaced by 1-15 mol % F.sup.- ions.

Lightwave guide produced from special substrate glasses by ion exchange

A new, CdO-and ThO.sub.2 -free optical glass with refractive indices of 1.73-1.78 and Abbe numbers of 30-34 and with particularly good devitrification stability comprises (in weight %):

Optical CdO and ThO.sub.2 -free glass with refractive indices of

An optical glass, n.sub.d .gtoreq.1.60 and v.sub.d .gtoreq.58, having a high chemical stability as well as resistance to phase separation and crystallization, comprises in percent by weight:

Optical glass with refractive index 1.60, an abbe number 58, with high

A highly refractive optical glass (n.sub.d .gtoreq.1.83) with high dispersion (v.sub.d .ltoreq.25) and very good chemical stability at relatively low density (.delta..ltoreq.3.5 g/cm.sup.3) consists of (in weight percent) SiO.sub.2 19-25, Na.sub.2 O 7-10, K.sub.2 O 4-7, Cs.sub.2 O 0-12, Cao 0.5-2.0, BaO 9-15, TiO.sub.2 25-30, ZrO.sub.2 0-6, Nb.sub.2 O.sub.5 16-20, WO.sub.3 0-3, with Nb.sub.2 O.sub.5 :TiO.sub.2 =0.6-0.71.

Highly refractive optical glass with refractive indices &gt;1.83 and Abbe

High PbO-content glass in the optical range of flint and heavy flint glasses from the system SiO.sub.2 --PbO--M.sub.2 O wherein M.sub.2 O=alkali metal oxides, said glass having a minimum PbO content of 30 wt. % and a minimum M.sub.2 O content of 0.5 wt. %, are provided with enhanced chemical stability without loss of the desired optical position by replacing a portion of the SiO.sub.2 and PbO such that the glass contains 1.5-6 wt. % (TiO.sub.2 +ZrO.sub.2) and the ratio of TiO.sub.2 :ZrO.sub.2 is about 0.3-2.0.

High PbO-content glasses in the system SiO.sub.2 --PbO--M.sub.2 O with

An optical and ophthalmic glass with high refractive index, high Abbe number and low density, which is distinguished by good chemical stability, good crystallization behavior and capability of chemical hardening, comprises (in % by weight):

Optical and ophthalmic glass with refractive indices greater than or

A phototropic glass with the optical characteristics of n.sub.d greater than to or equal to 1.59 and v.sub.d greater than or equal to 44, and with a density less than or equal to 3.0 g/cm.sup.-3 is provided having a composition comprising:

Phototropic glass with a refractive index greater than or equal to 1.59,

Optical glass with refractive indicies.gtoreq.1.90, Abbe numbers.gtoreq.25 consisting essentially of, in weight percent; 0-10 SiO.sub.2, 2-20 B.sub.2 O.sub.3, 0-2 Al.sub.2 O.sub.3, the sum of SiO.sub.2, B.sub.2 O.sub.3, and Al.sub.2 O.sub.3 being 7.5-25, 1-16 TiO.sub.2, 0-10 ZrO.sub.2, 35-55 La.sub.2 O.sub.3, 0.5-10 Y.sub.2 O.sub.5, 0.5-15 Nb.sub.2 O.sub.5, 0-10 Gd.sub.2 O.sub.3, 0-15 Ta.sub.2 O.sub.5, 0-3 P.sub.2 O.sub.5 wherein the ratio of SiO.sub.2 to B.sub.2 O.sub.3 is between 0.1 and 1.6, and the sum of Nb.sub.2 O.sub.5 and Ta.sub.2 O.sub.5 is from 9 to 20%.

Optical glass with refractive indices&gt;1.90, Abbe numbers&gt;25 and high

An optical and ophthalmic glass with high refractive index, high Abbe number and low density, which is distinguished by good chemical stability, good crystallization behavior and capability for chemical hardening, comprises (in % by weight):

An optical glass with the familiar optical position of n.sub.d &gt;1.70 and v.sub.d &gt;22, which differs from the familiar optical glasses of the optical position due to its lower density and good chemical stability, and is composed of (in percent by weight): SiO.sub.2 25-42, TiO.sub.2 15-35, B.sub.2 O.sub.3 0.5-7, BaO 3-13, CaO 1-3, Nb.sub.2 O.sub.5 1-20, GeO.sub.2 0-2, Al.sub.2 O.sub.3 0-4, Na.sub.2 O 7.5-15, Li.sub.2 O 0-9, K.sub.2 O 2-10, SrO 0-6, ZnO 0-5, ZrO.sub.2 0-3, and WO.sub.3 0-3.

Optical light weight glass with a refractive index of &gt;1.70, an Abbe

A spectacle glass which is colorless in the visible spectrum range, not transmissive in the ultraviolet spectrum range below 350 nm, has a refractive index n.sub.d higher than 1.56 and an Abbe number of more than 45, and which has an extremely low density, has the following composition (in % by weight):

Spectacle glass with increased refractive index

A new phototropic glass in which the phototropic properties arise from precipitations of silver halide and which in the unirradiated condition is slightly tinted or completely colorless while showing a brown color in the light-exposed condition, comprises, in known phototropic glass compositions, an additional content of at least 0.001 wt % of TeO.sub.2 and/or Yb.sub.2 O.sub.3.

Growing community of inventors

Klein-Winternheim, Germany

Ludwig Ross