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Recherche Et Developement Du Groupe Cockerill Sambre En Abrege: 'Rd-Cs'

'Recherche Et Developpment Du Groupe Cockerill Sambre' En Abrege 'Rd-Cs'

Lucien Martinot

Robert Jerome

Marc Mertens

Jean Schrijnemackers

Cedric Calberg

Philippe Dubois

Isabelle Bodart

The invention concerns a method for forming a coating on conductive particles by grafting a polymer and/or a copolymer of the particles from a bath containing at least a monomer from which the polymer and/or copolymer is formed. The method consists of producing the grafting by electrochemical reduction of the monomer in an electrolytic solution, where at least a cathode and an anode are provided, and containing an aprotic solvent, a support electrolyte and the monomer(s) required for polymerizing or copolymerizing the coating, by suspending the particles and moving the solution so as to produce an intermittent contact between the particles and the cathode, and to form, by polymerization or copolymerization, the coating on the particles by applying an electric potential.

Method for coating electrically conductive particles by grafting a polymer layer

A method for making composites uses electrochemical polymer or copolymer coating of a carbon-based support by using a reaction system including (a) at least a monomer capable of forming a polymer on said support, (b) an aprotic solvent and (c) an electrolyte providing the resulting organic medium with an electrical conductivity for conducting therein electrolysis. The carbon support permanently forms the cathode, by applying either a potential or an electric current bringing the reaction system into the passivation zone corresponding to the first inhibition peak. The method forms a polymer grafted on the support.

Method for making composites

A film of a composite material is deposited by electropolymerization onto electrically conductive surface. A mixture comprising a monomer, a substance forming a dopant, a supporting electrolyte and a solvent is subjected to electrolysis in which the conductive surface to be coated is used as either cathode or anode. The cathode or anode is polarized to a potential between the electron transfer between the electrically conductive surface and the monomer. Prior to electrolysis, a solution is made from the mixture containing the substance forming a dopant either as anion, cation, molecule, and/or as undissociated complex.

Process of depositing by electropolymerization a film of a composite

A process for depositing by electropolymerization an organic film onto an electrically conductive surface, wherein use is made of a mixture comprising (a) at least one monomer suited for forming a polymer onto said surface, (b) at least one material which can be linked to said polymer, (c) a supporting electrolyte and (d) a solvent, said process comprising the use, as material to be linked to said polymer, of a reactive substance which can react chemically with the growing polymeric chains formed starting from the monomer.

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Olne, Belgium

Lucien Martinot