Bayer Aktiengesellschaft

Bayer Corporation

Covestro Deutschland Ag

Lothar Kahl

Christian Wamprecht

Manfred Bock

Hans-Ulrich Meier-Westhues

Josef Pedain

Nusret Yuva

Klaus Nachtkamp

Hans-Josef Laas

Harald Blum

Bernd Klinksiek

Wieland Hovestadt

Wolfgang Schultz

Reinhard Halpaap

Knud Reuter

Walter Schafer

Manfred Schonfelder

Christian Zwiener

Volker Schneider

Wolfgang Fischer

Hanns P Muller

Lutz Schmalstieg

Hanns-Peter Muller

Douglas A Wicks

Jurgen Meixner

Eberhard Konig

Peter Hohlein

Oswald Wilmes

Wolfgang Wellner

Theodor Engbert

Beate Baumbach

Ulrich Freudenberg

Karl-Arnold Weber

Dieter Schleenstein

Juergen Meixner

Berta Vega Sanchez

Hans-Gunter Schmitz

Manfred Schoenfelder

The invention relates to a method for producing polyurethanes containing silane groups by reacting at least A) a composition containing a) one or more compounds containing isocyanate and silane groups of general formula (I) and b) &#x3c;=1 percent by weight, relative to the total mass of composition A), one or more monomeric diisocyanates with aliphatically, cycloaliphatically, araliphatically and/or aromatically bonded isocyanate groups of general formula (II), where R1, R2 and R3 are the same or different radicals and respectively indicate a saturated or unsaturated, linear or branched, aliphatic or cycloaliphatic or an optionally substituted aromatic or araliphatic radical with up to 18 carbon atoms, which can contain optionally up to 3 heteroatoms from the series oxygen, sulphur, nitrogen, X is a linear or branched organic radical with at least 2 carbon atoms and Y is a linear or branched, aliphatic or cycloaliphatic radical with 4 to 18 carbon atoms or an optionally substituted aromatic or araliphatic radical with 6 to 18 carbon atoms, with B) an at least difunctional polyol with a numerically average molecular weight Mn of 62 to 22000 g/mol, preferably 90 to 12000 g/mol, while maintaining an equivalent ratio of isocyanate groups to hydroxyl groups of 0.7:1 to 1.2:1. The invention further relates to the products which can be obtained using the method according to the invention. Moreover, the invention relates to the use of the products which can be obtained using the method according to the invention as starting components in the production of cross-linkable binders, varnish, and raw materials for sealants or adhesives.

Silane functional binder with thiourethane structure

Aqueous coating compositions containing urethane (meth)acylates having UV-hardening isocyanate groups

An aqueous coating composition including a combination of hydroxyl group-containing polyols and blocked polyisocyanate cross-linking agents, which dries preferably in pulverulent manner on the surface to be coated and, after stoving, affords coatings having a high resistance to water, chemicals and solvents, in particular on metallic substrates, and a process for the production of the coating composition.

Aqueous coating composition for stoving finishes and process for the production thereof

An aqueous binder composition having a reduced tendency to yellow containing

Aqueous binder compositions and their use in heat curable coating

The present invention relates to aqueous polyurethane-urea dispersions having a resin solids content of at least 35 wt. % and a pH of at least 7.5 which are prepared by

High solids polyurethane-urea dispersions having improved storage

The present invention relates to a process for the production of aqueous dispersions which form powder coatings at room temperature, have an average particle size of 0.1 to 10 .mu.m, contain polyols and blocked polyisocyanate crosslinking agents, and, after stoving, yield coatings with improved water and solvent resistance, in particular on metallic substrates.

Process for the production of aqueous stoving coating compositions

The present invention relates to polyisocyanate-modified dicarboxylic acid derivatives obtainable by reacting organic polyisocyanates with excess quantities, based on the equivalent ratio of NCO/COOH groups, of dicarboxylic acid (poly)anhydrides containing free carboxyl groups and water. The present invention also relates to coating compositions, in particular powder coating compositions, containing these polyisocyanate-modified dicarboxylic acids as curing agents for resins containing epoxy groups.

Polyisocyanate-modified polycarboxylic acids and their use as

The present invention relates to novel aqueous or water-dilutable blocked polyisocyanates and to their use for the production of one-component polyurethane coating compositions, which are stovable at relatively low temperatures of 130.degree. to 150.degree. C. and provide clear coatings having substantially reduced thermal yellowing.

Aqueous or water-dilutable blocked polyisocyanates and their use for

A method is described for the preparation of aqueous coating compositions based on resin binders containing isocyanate-reactive hydrogen atoms and polyisocyanates, by mixing the components with water, wherein the mixture is forced at a pressure of from 1 to 30 MPa through a nozzle of small size in at least one dimension.

Aqueous two-component polyurethane coating compositions and a method for

Polyisocyanate-modified dicarboxylic (poly)anhydrides which are solid below 40.degree. C., liquid above 120.degree. C. and based on the reaction product of organic polyisocyanates with more than equivalent quantities, based on the NCO/COOH reaction, of dicarboxylic (poly)anhydrides containing free carboxyl groups and optional subsequent modification of the reaction product with less than equivalent quantities, based on the anhydride groups, of anhydride-reactive amino and/or hydroxyl groups; and powder coating compositions containing as binder these polyisocyanate-modified dicarboxylic (poly)anhydrides as curing agents for polyepoxides.

Polyisocyanate-modified dicarboxylic (poly) anhydrides

Powder coating compositions based on A) copolymers prepared from olefinically unsaturated monomers, containing epoxide and anhydride groups and having a glass transition temperature T.sub.g of 30.degree. to 80.degree. C., an average molecular weight M.sub.n of 1,000 to 6,000 and a molecular weight distribution M.sub.w /M.sub.n of 2.5 to 10.0, B) a hardener component selected from (i) (cyclo)aliphatic dicarboxylic acids, (ii) anhydrides of such dicarboxylic acids, (iii) polyol-modified polymeric anhydrides of such dicarboxylic acids and (iv) aliphatic hydroxycarboxylic acids and optionally C) additional crosslinking agents in the form of polyaddition products having uretidione groups, and the use of these compositions for coating heat-resistant substrates.

Powder coating compositions and their use for the production of coatings

A powder coating composition for the production of non-yellowing, flexible coatings which contains a mixture of a polyisocyanate component which contains one or more lacquer polyisocyanates having free (unblocked) isocyanate groups bound to primary and/or secondary carbon atoms and a polyol component containing one or more polyhydroxyl compounds selected from polyhydroxy polyurethanes, polyhydroxy polyacrylates and polyhydroxy polyesters, wherein at least 50% of the hydroxyl groups are bound to secondary or tertiary carbon atoms; and its use for coating heat-resistant substrates, in particular as clear coating compositions for automobiles.

Powder coating compositions and their use for coating heat-resistant

A powder coating composition which is curable at 120.degree. to 150.degree. C. and contains A) one or more copolymers prepared from olefinically unsaturated monomers and containing epoxy groups and optionally hydroxyl groups, B) one or more curing agents containing carboxylic acid or carboxylic acid anhydride groups, and C) one or more polyaddition compounds which contain uretdione groups, have a melting point or range of 40.degree. C. to 120.degree. C. and are prepared from (cyclo)aliphatic diisocyanates; and its use for coating of heat-resistant substrates, especially automotive substrates.

Powder coating compositions and their use for coating heat resistant

The present invention relates to polyisocyanate mixtures which are solid below 40.degree. C. and liquid above 125.degree. C. and which have

Polyisocyanate mixtures, a process for their production and their use

The present invention relates to water dilutable, urethane group-containing polyester polyols having an acid number of 6 to 45 mg KOH/g, wherein 25 to 100% of the acid groups are neutralized by bases, a hydroxyl number of 20 to 250 mg KOH/g, a molecular weight (M.sub.w) of 2,000 to 150,000 and a urethane content (--NH--CO--O--) of 2 to 16% by weight, wherein the polyester polyol is the at least partly neutralized reaction product of

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Bergisch Gladbach, Germany

Lothar Kahl