Hoechst Aktiengesellschaft

Lothar Jaeckel

Rolf Kleber

Frank Wehowsky

Frank Weinelt

Hans-Jerg Kleiner

Rainer Kupfer

Bernhard Mees

Siegfried Billenstein

Wolfgang Knaup

Ignaz Wimmer

Fritz-Joachim Gohlke

Ohannes Balekdijan

Specific ester products obtainable by esterifying a selected polyethylene glycol with a dicarboxylic acid in a molar ratio of 1:0.25 to 1 are described. The novel ester compounds are efficient and easily biodegradable spin finishes.

Ester compounds, process for their preparation and their use

The invention relates to spin finishes comprising compounds of the formula ##STR1## in which R.sub.1 is a straight-chain or branched alkyl radical of the empirical formula C.sub.n H.sub.2n+1 or a straight-chain or branched alkenyl radical of the empirical formula C.sub.n H.sub.2n-1 where n is in each case 1 to 9 and R.sub.2 is a straight-chain or branched alkyl radical of the empirical formula C.sub.n H.sub.2n+1 where n is 2 to 16, and also to their use as spooling oils for synthetic fibers.

Biodegradable spin finishes

The invention relates to spin finishes which contain compounds of the formula

The urethanes described are synthesized from aliphatic fluoro alcohols, triisocyanate and a carboxylic acid. They are prepared by reaction of the aliphatic fluoro alcohol with the triisocyanate to give the fluoro alcohol/triisocyanate adduct and by reaction of this adduct with the carboxylic acid. The new urethanes are preferably used for the finishing of textiles for the purpose of achieving water, oil and soil repellency.

Urethanes made from aliphatic fluoro alcohols, isocyanates and

Compounds of the formula ##STR1## where R.sub.1 denotes a group of the formula ##STR2## R.sub.2 denotes C.sub.1 -C.sub.4 -alkyl, R.sub.3 denotes hydrogen or methyl, n denotes a number from 5 to 100, m denotes an integer from 0 to 4 and x denotes the number of free valences of the particular R.sub.1 radical, a process for the preparation thereof, and the use thereof as fiber spin finishes.

Poly(alkoxy ether) mixed formals

Urethanes made from aliphatic fluorinated alochols, isocyanates and substituted aromatic compounds, a process for their preparation, and their use. The novel urethanes are synthesized from an aliphatic fluorinated alcohol, an isocyanate and a specific substituted phenol or aniline compound. They are prepared by reacting an aliphatic fluorinated alcohol with a di- or triisocyanate to form a fluorinated alcohol/isocyanate adduct and reacting this adduct with a certain substituted phenol or aniline to form the urethanes intended. The novel urethanes are preferably used for oleophobic and hydrophobic finishing of textiles and leather.

Urethane made from aliphatic fluorinated alcohols, isocyanates and

Amino-containing alkenylsuccinic esters of the formulae ##STR1## where R denotes linear or branched C.sub.1 -C.sub.20 -alkyl, R.sub.1 denotes hydroxy-C.sub.2 -C.sub.6 -alkyl or C.sub.1 -C.sub.4 -alkyl, R.sub.2 denotes methyl or ethyl, R.sub.3 denotes C.sub.6 -C.sub.20 -alkyl, preferably C.sub.12 -C.sub.18 -alkyl, or C.sub.6 -C.sub.20 -alkenyl, preferably C.sub.12 -C.sub.18 -alkenyl, A denotes --C.sub.2 H.sub.4 -- or C.sub.3 H.sub.7 -- and n denotes a number from 1 to 10, preferably from 3 to 8, the preparation thereof and the use thereof as thermostable lubricants in spin finishes.

Amino-containing alkenylsuccinic esters

Novel alkanephosphonic monoester salts, preparation thereof and use thereof as spin finishes for textile fibers Alkylphosphonic monoester salts of the formula ##STR1## where R, if p=1, is alkyl, and, if p=4, a carbon atom, R.sup.1 denotes C.sub.1 -C.sub.4 -alkyl, A denotes C.sub.2 H.sub.4 and/or C.sub.3 H.sub.7, m denotes a number from 15 to 35, R.sup.2 denotes C.sub.6 -C.sub.24 -alkyl, n denotes a number from 0 to 15, and p denotes 1 or 4 . These compounds are suitable for use as spin finishes for textile fibers and are distinguished by very good thermostability.

Novel alkanephosphonic monoester salts, preparation thereof and use

The molecule of the new urethanes contains an aliphatic fluoroalcohol, an isocyanate and an aromatic dihydroxy, diamino, aminohydroxy, aminocarboxy or hydroxycarboxy compound. They are prepared by reacting an aliphatic fluoroalcohol with a diisocyanate or triisocyanate to give the fluoroalcohol/isocyanate adduct and by reacting this adduct with said aromatic compound to give the desired urethanes composed of an aliphatic fluoroalcohol, an isocyanate and the bifunctional aromatic compound mentioned, and also be reacting a urethane of this type which also carries an active hydrogen atom on the bifunctional aromatic compound, with an isocyanate compound containing one or more isocyanate groups. The new urethanes are preferably used for imparting an oleophobic and hydrophobic finish to textiles and leather.

Urethanes composed of aliphatic fluoroalcohols, isocyanates and aromatic

The novel urethanes, in addition to at least one perfluoroalkyl group, also contain epichlorohydrin groups and dialcohol radicals in the molecule. They are prepared by reacting a fluorine-containing alcohol with epichlorohydrin to give the perfluoroalkyl-epichlorohydrin adduct, reacting this adduct with a di- or triisocyanate to give the perfluoroalkyl-epichlorohydrin-isocyanate adduct and by reacting this adduct with a dialcohol or a monoetherified dialcohol to give the desired urethanes having a perfluoroalkyl group and having epichlorohydrin groups and dialcohol radicals, and by reacting a suitable urethane compound of this type with a perfluoroalkyl-containing di- or triisocyanate to give the desired urethanes having a plurality of perfluoroalkyl groups and having epichlorohydrin groups and dialcoholradicals. The novel urethanes are preferably used for the oleophobic and hydrophobic finishing of textiles.

Urethanes which contain perfluoroalkyl groups, epichlorohydrin groups

Agent for the liquid paraffin waxing of yarns which consists of

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Florsheim am Main, Germany

Lothar Jaeckel