Huels Aktiengesellschaft

Chemische Werke Huels Aktiengesellschaft

Huls Aktiengesellschaft

Lothar Fischer

Dieter Hess

Wilhelm Droste

Bernd Nowitzki

Walter K Homann

Kurt Wember

Gerhard Ludwig

Manfred Z Hausen

Hans-Gerd L Uken

The present invention relates to a catalyst for the selective hydrogenation of an unsaturated compound, based on a noble metal and/or a noble-metal oxide on an aluminum oxide support, and to a process for the preparation of the catalyst. The present invention further relates to a process for the selective hydrogenation of unsaturated compounds.

Catalyst, process for the preparation thereof and process for the

A process for the preparation of saturated alcohols from aldehydes is disclosed. The hydrogenation of saturated and unsaturated aldehydes to alcohols can be carried out over catalysts containing cooper and nickel. In the present process, the selectivity of the alcohol preparation is further improved by a combination of an alkaline copper catalyst and a nickel-containing catalyst whose carrier material has acidic centers of a certain acid strength H.sub.o.

Process for the preparation of saturated alcohols from aldehydes

In order to produce pure alpha, omega-C.sub.4 to C.sub.20 alkenols having purities in excess of 90% by dehydrating the corresponding alpha, omega-C.sub.4 to C.sub.20 diols, a catalyst is used which was prepared by using an alkaline earth orthophosphate or alkaline earth hydrogen phosphate or by reacting an alkaline earth compound with phosphoric acid into the corresponding phosphate and then adding an alkali or alkaline earth compound. This catalyst is suitable to be shaped, next it is dried and then calcined at temperatures between 350.degree. and 950.degree. C. The educt dehydration takes place at temperatures between 300.degree. and 500.degree. C. in selective and partial manner to obtain pure alpha, omega-C.sub.4 to C.sub.20 alkenols at conversions exceeding 90%.

Catalytic system and a process for preparing alpha, omega-C.sub.4

For the continuous manufacture of n-butyraldehyde by selective hydrogenation of crotonaldehyde, the hydrogenation is conducted in the liquid phase in the presence of a palladium-aluminum oxide supported catalyst containing the palladium in the outer layer of the supporting grain of a thickness of 0.05-0.2 mm. The palladium content of this catalyst is 0.1-0.6% by weight. The aluminum oxide support, with a specific pore volume of 0.4-0.6 cm.sup.3 /g, has 40-60% of its pores of a diameter of &gt;0.5 nm and an internal surface area of 130-160 m.sup.2 /g. The hydrogenation is conducted under absolute pressures of 5-50 bar and at temperatures of 20.degree.-100.degree. C. The resultant n-butyraldehyde is of a high purity without interfering by-products.

Process for the continuous manufacture of n-butyraldehyde by selective

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Marl, Germany

Lothar Fischer