Inphase Technologies, Inc.

Lucent Technologies Inc.

Bayer Materialscience Ag

Akonia Holographics LLC

Lisa Dhar

Howard Edan Katz

Melinda Lamont Schnoes

Arturo Hale

Marcia Lea Schilling

Mark David Michaels

Kevin R Curtis

Songvit Setthachayanon

Melinda G Schnoes

Friedrich-Karl Bruder

Michael Christopher Cole

Fredric R Askham

Timothy J Trentler

Sean Quirin

Nicolas Stöckel

Sam Miller

Marianela T Lemon

Marianela Trujillo-Lemon

Timothy John Trentler

Songvit Settachayanon

Samuel John Miller

High performance media suitable for recording with a blue laser is disclosed. The blue-sensitized holographic media provides greater dynamic range and higher sensitivity than previously disclosed blue-sensitized holographic media. These media can be used for diverse applications such as data storage where the articles provide denser data storage and more rapid hologram writing times or for optical waveguides where the articles provide greater optical confinement and more rapid manufacturing times.

Advantageous recording media for holographic applications

The present invention provides a method and apparatus for a multilayer optical articles. A method comprises forming a first multilayer article with a first substrate and a second substrate with a first adherent disposed between the first and second substrate. A first surface of a third substrate is then grasped with a first holder and a second adherent is then disposed on one or more surfaces selected from a second surface of the third substrate and a surface of the first multilayer article while the multilayer article is grasped by a second holder. The second adherent is then at least partially cured while the first and second holders maintain their grasp and while the inner surfaces of the first and second holders are in the selected angular relationship to form a second multilayer article.

Method and apparatus for multilayer optical articles

The present invention provides a solution to the needs described above through a method for forming multiply patterned optical articles. The method comprises providing a micromold having a pre-patterned surface structure, disposing a photorecording medium comprising a matrix precursor and a photoactive monomer on a holder surface, moving the micromold to the photorecording medium on the holder surface such that the pre-patterned surface structure contacts the photorecording medium, wherein the photorecording medium conforms to the pre-patterned surface structure of the micromold, at least partially curing the photorecording medium adherent while the micromold pre-patterned surface structure contacts the photorecording medium, and further patterning the photorecording medium by irradiating the photorecording medium with laser light to polymerize the photoactive monomer.

Method for forming multiply patterned optical articles

The optical article of the invention, e.g., holographic recording medium or polymeric waveguide, is formed by mixing a matrix precursor and a photoactive monomer, and curing the mixture to form the matrix in situ. The reaction by which the matrix precursor is polymerized during the cure is independent from the reaction by which the photoactive monomer is polymerized during writing of data. In addition, the matrix polymer and the polymer resulting from polymerization of the photoactive monomer are compatible with each other. Use of a matrix precursor and photoactive monomer that polymerize by independent reactions substantially prevents cross-reaction between the photoactive monomer and the matrix precursor during the cure and inhibition of subsequent monomer polymerization. Use of a matrix precursor and photoactive monomer that result in compatible polymers substantially avoids phase separation. And in situ formation allows fabrication of articles with desirable thicknesses.

Optical article and process for forming article

Holographic articles having self-sealing properties such as moisture resistance and environmental durability are disclosed. The holographic articles are formed by the reaction of a composition containing an excess amount (i.e. non-stoichiometric amount) of polyisocyanates to polyols. The holographic recording articles exhibit high optical clarity and low scattering.

Environmentally durable, self-sealing optical articles

A holographic storage medium, a method of manufacturing the holographic storage medium and a holographic storage device incorporating the storage medium. In one embodiment, the holographic storage medium includes: (1) first and second spaced-apart substrates, the first substrate being plastic and (2) a photopolymer core located between said first and second substrates and having a coefficient of thermal expansion such that said first and second substrates and said photopolymer core cooperate to respond substantially isotropically to a change in temperature.

Holographic storage medium having enhanced temperature operating range and method of manufacturing the same

The invention relates to use of a material containing a polymerizable monomer or oligomer, the material exhibiting desirable shrinkage compensation upon polymerization. The material contains an expansion agent having a cleaving moiety with the capacity to be cleaved or fragmented by a catalytic reaction, e.g., acid catalysis. The cleavage, by increasing the number of molecules in the material, causes expansion that compensates, at least in part, for shrinkage induced by polymerization of the monomer or oligomer. The expansion agent is capable of providing compensation such that no more than 0.4%, advantageously no more than 0.2%, volume shrinkage per molar concentration of polymerized monomer functional groups occurs, where such compensation is performed at relatively low temperatures of less than 40&deg; C.

Material exhibiting compensation for polymerization-induced shrinkage and recording medium formed therefrom

The invention relates to use of a material containing a polymerizable monomer or oligomer, the material exhibiting desirable shrinkage compensation upon polymerization. The material contains an expansion agent having a cleaving moiety with the capacity to be cleaved or fragmented by a catalytic reaction, e.g., acid catalysis. The cleavage, by increasing the number of molecules in the material, causes expansion that compensates, at least in part, for shrinkage induced by polymerization of the monomer or oligomer. The expansion agent is capable of providing compensation such that no more than 0.4%, advantageously no more than 0.2%, volume shrinkage per molar concentration of polymerized monomer functional groups occurs, where such compensation is performed at relatively low temperatures of less than 40.degree. C.

Material exhibiting compensation for polymerization-induced shrinkage

The photorecording medium of the invention is formed by mixing a matrix precursor and a photoactive monomer, and curing the mixture to form the matrix in situ. The reaction by which the matrix precursor is polymerized during the cure is independent from the reaction by which the photoactive monomer is polymerized during writing of data. In addition, the matrix polymer and the polymer resulting from polymerization of the photoactive monomer are compatible with each other. Use of a matrix precursor and photoactive monomer that polymerize by independent reactions substantially prevents cross-reaction between the photoactive monomer and the matrix precursor during the cure and inhibition of subsequent monomer polymerization. Use of a matrix precursor and photoactive monomer that result in compatible polymers substantially avoids phase separation. And in situ formation allows fabrication of media with desirable thicknesses.

Growing community of inventors

New Providence, NJ, United States of America

Lisa Dhar