United Microelectronics Corp.

Industrial Technology Research Institute

Taiwan Semiconductor Manufacturing Comp. Ltd.

Merck Patent Gesellschaft MIT Beschrankter Haftung

Lih-Juann Chen

Chee-Wee Liu

Yuan-Ching Peng

Sheng-Wei Lee

Pang-Shiu Chen

Chen-Hua Douglas Yu

Chung-Shi Liu

Jane-Bai Lai

Yong-Fen Hsieh

Jung-Chih Hu

Ting-Chang Chang

Wen-Yi Hsieh

Yu-Ru Yang

Kao-Feng Liao

Jenn-Tarng Lin

Yong-fen Hsieh

Ying-Hao Li

Ming-Shiann Feng

Chun-Lin Cheng

You-Shin Lin

Win-Yi Hsieh

Hsin-Yuan Huang

Wu-Chun Gau

A method for growing strained Si layer and relaxed SiGe layer with multiple Ge quantum dots (QDs) on a substrate is disclosed. The method can reduce threading dislocation density, decrease surface roughness of the strained silicon and further shorten growth time for forming epitaxy layers than conventional method. The method includes steps of: providing a silicon substrate, forming a multiple Ge QDs layers; forming a layer of relaxed SiGe; and forming a strained silicon layer in subsequence; wherein x is greater than 0 and less than 1.

Strained silicon forming method with reduction of threading dislocation density

A construction of thin strain-relaxed SiGe layers and method for fabricating the same is provided. The construction includes a semiconductor substrate, a SiGe buffer layer formed on the semiconductor substrate, a Si(C) layer formed on the SiGe buffer layer, and an relaxed SiGe epitaxial layer formed on the Si(C) layer. The Si(C) layer is employed to change the strain-relaxed mechanism of the relaxed SiGe epitaxial layer formed on the Si(C) layer. Therefore, a thin relaxed SiGe epitaxial layer with low threading dislocation density, smooth surface is available. The fabricating time for fabricating the strain-relaxed SiGe layers is greatly reduced and the surface roughness is also improved.

Construction of thin strain-relaxed SiGe layers and method for fabricating the same

The invention relates to a novel galvanizing solution for the galvanic deposition of copper. Hydroxylamine sulfate or hydroxylamine hydrochloride are utilized as addition reagents and added to the galvanizing solution during the galvanic deposition of copper which is used in the manufacture of semiconductors.

Galvanizing solution for the galvanic deposition of copper

A method for improving the moisture absorption of porous low dielectric film in an interconnect structure is disclosed. The porous low-k dielectric layer such as porous hydrosilsesquioxane (porous HSQ) or porous methyl silsesquioxane (porous MSQ) is spun-on the etching stop layer. After plasma process, the porous low dielectric film has a plurality of dangling bonds. Then, the wafer is placed in the supplementary instrument with hydrophobic reactive solution. Next, the hydrophobic protection film is formed on surface and sidewall of porous low-k dielectric film to improve the moisture absorption of porous low-k dielectric film and the leakage current is reduced in subsequently processes.

Method for improving the moisture absorption of porous low dielectric film

A method for fabricating a copper interconnect structure, using a low resistivity Cu.sub.3 Ge intermetallic layer, as an adhesive layer, has been developed. Following an in situ, CVD of a titanium nitride barrier layer, a germanium layer, and a copper layer, an anneal procedure is used to form the Cu.sub.3 Ge intermetallic layer, with the intermetallic layer, located between the underlying titanium nitride barrier layer, and the overlying copper layer. The Cu.sub.3 Ge intermetallic layer can also be formed in situ, during deposition, if the deposition temperature exceeds 150.degree. C. Cu.sub.3 Ge layer exhibits a resistivity of about 5E-6 ohm - cm. A second iteration of this invention allows a thick copper layer to be plated on a thin copper seed layer, only on the top surface of a semiconductor substrate. This iteration, also incorporating the low resistivity, Cu.sub.3 Ge intermetallic, and the adhesive layer, prevents copper from being plated on the beveled edge of the semiconductor substrate.

Use of a low resistivity Cu.sub.3 Ge interlayer as an adhesion promoter

A method of fabricating a metal plug. On a semiconductor substrate comprising a MOS device, a dielectric layer, and a via hole penetrating though the dielectric layer, a conformal titanium layer is formed on the dielectric layer and the via hole. A low temperature annealing is formed in a nitrogen environment, so that a surface of the titanium layer is transformed into a first thin titanium nitride layer. A conformal second titanium nitride layer is formed on the first thin titanium nitride layer by using collimator sputtering. A metal layer is formed and etched back on the second titanium nitride layer to form a metal plug.

Method of fabricating contact plug

A method of manufacturing a cobalt suicide layer in the present invention has a silicon layer formation step. The silicon layer is formed at the interface between the cobalt layer and titanium layer, therefore the interface is smoother in this invention than in other conventional methods, and there are no voids formed at the interface. Moreover, consumption of the silicon can be controlled by adjusting the thickness of the silicon layer.

Method of manufacturing cobalt silicide layer

A method for fabricating a copper interconnect structure, using a Cu.sub.3 Ge intermetallic layer, as an adhesive layer, has been developed. Following the deposition of a copper seed layer, an ion implantation procedure is performed, placing germanium ions in a copper seed layer. After deposition of a thick copper layer, an anneal cycle, performed before or after deposition of the thick copper layer, is used to create a Cu.sub.3 Ge intermetallic layer at the interface between a copper seed layer and a titanium nitride barrier layer. A second embodiment of this invention uses a tilted, germanium ion implantation procedure, used to avoid the placement of germanium ions in a copper seed layer, at the bottom of a contact hole, thus avoiding possible implantation damage, to active device regions, exposed in the bottom of the contact hole.

Method to improve adhesion between copper and titanium nitride, for

The present invention relates to a method of manufacturing semiconductor components having a titanium nitride layer including the steps of providing a semiconductor substrate with a transistor including a gate and source/drain regions, depositing an insulating layer above the semiconductor substrate, etching the insulating layer to form an opening exposing the source/drain region below, depositing an ultra-thin titanium nitride layer having a grainy particulate profile and a thickness of about 0.5 nm to 2 nm around the edge and at the bottom of the opening, depositing a metallic layer over various aforementioned layers, and forming a metal silicide layer by heating the semiconductor substrate to allow the metallic layer to react with silicon on the semiconductor substrate surface.

Method of manufacturing semiconductor components having a titanium

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Hsinchu, Taiwan

Lih-Juann Chen