Betz Laboratories, Inc.

Betzdearborn, Inc.

Ge Betz, Inc.

Libardo A Perez

William S Carey

Donald T Freese

Andrew Solov

Judith B Rockett

J Michael Brown

Khac Truc Nguyen

Donald Carroll Roe

Fu Chen

David M Polizzotti

Keith A Bair

Judith L Barron

Methods for inhibiting depletion of mineral values from pregnant lixiviant solutions comprise contacting the requisite metal ore with a preg-robbing inhibition agent (PRIA) comprising (I) alkyl polyglucoside surfactants; (II) imidazoline based amphoteric surfactants; (III) hydroformylation products of lower (C&#x2013;C) alkanes in an organic solvent medium, and (IV) esters and aldehydes.

Inhibition of the depletion of metal values from pregnant lixiviant solutions

A composition for of controlling scale formation and deposition and corrosion in aqueous systems is described wherein a treatment solution of a substoichiometric amount of a composition comprising a scale/corrosion inhibitor in combination with a substituted alkylpolycarboxylate is employed. The scale/corrosion inhibitor can be a phosphonate such as hydroxyethylidene diphosphonic acid, 2-phosphonobutane-1,2,4-tricarboxylic acid, hydroxyphosphonoacetic acids, amino phosphonates; terpolymers, copolymers and homopolymers of acrylic acid, maleic acid, epoxysuccinic acids such as polyepoxysuccinic acid or mixtures thereof. The substituted alkylpolycarboxylates are compounds of the general structure: R--X.sub.m --Y.sub.n wherein R is a hydrocarbon functionality having 4 to 18 carbons; X, when present, is --NH--, --NY.sup.1 --, --N--&gt;O, --N--OC--Y.sup.1, --O-- or --S--; n is greater than or equal to 1; m=O or 1; and Y and Y.sup.1 each independently represent a substituted or nonsubstituted carboxylic acid functionality such that said alkylpolycarboxylate has at least 2 carboxylic acid functional groups.

Composition for controlling scale formation in aqueous systems

A method and compounds for inhibiting the formation of scale, e.g., barium scale, and controlling corrosion is disclosed. The method is particularly effective at inhibiting or preventing corrosion of ferrous-based metals in contact with the aqueous systems such as cooling water systems. The method comprises introducing into the aqueous system a compound of the general formula: ##STR1## wherein R is hydrogen, alkyl, aryl, substituted alkyl or substituted aryl; R' and R' are each independently hydrogen, C.sub.1-4 alkyl or C.sub.1-4 substituted alkyl; Z is O, S, NH or NR, where R is as described above; n is a positive integer greater than 1; f is a positive integer; and M is hydrogen, a water soluble cation (e.g., NH.sub.4.sup.+, alkali metal), or a C.sub.1-3 alkyl group.

Inhibition of scale and corrosion in aqueous systems

A method for simultaneously controlling the deposition of scale and the formation of corrosion in a cooling water system consisting of adding to the system a water soluble copolymer having the structure: ##STR1## wherein R.sub.1 is H or lower (C.sub.1 -C.sub.4) alkyl, F is H.sub.2 or O, M is a water soluble cation, R.sub.2 is (CH.sub.2 --CH.sub.2 --O).sub.n, ##STR2## or mixture of both, n is an integer of from 1 to about 40, R.sub.3 is H, lower (C.sub.1 -C.sub.4) alkyl or an acetate.

Method of inhibiting scale and controlling corrosion in cooling water

A method and composition for controlling the formation and deposition of scale imparting compounds in an aqueous system is disclosed. A treatment comprising a sulfonated polymer and a polymaleic acid is effective in controlling the formation and deposition of such compounds.

Method for controlling scale formation and deposition

A method of controlling scale formation and deposition and corrosion in aqueous systems is described wherein a treatment solution of a substoichiometric amount of a scale/corrosion inhibitor in combination with a substituted alkylpolycarboxylate is employed. The scale/corrosion inhibitor can be a phosphonate such as hydroxyethylidene diphosphonic acid, 2-phosphonobutane-1,2,4-tricarboxylic acid, hydroxyphosphonoacetic acids, amino phosphonates; terpolymers, copolymers and homopolymers of acrylic acid, maleic acid, epoxysuccinic acids such as polyepoxysuccinic acid or mixtures thereof. The substituted alkylpolycarboxylates are compounds of the general structure: R--X--Y.sub.n wherein R is a hydrocarbon functionality having 4 to 18 carbons; X, when present, is --NH--, --NY.sup.1 --, --N--&gt;O, --N--OC--Y.sup.1, --O-- or --S--; n is greater than or equal to 1; and Y and Y.sup.1 each independently represent a substituted or non-substituted carboxylic acid functionality such that said alkylpolycarboxylate has at least 2 carboxylic acid functional groups.

Methods for controlling scale formation in acqueous systems

A method and compounds for inhibiting the formation of scale is disclosed. The method is particularly effective at inhibiting the formation and deposition of calcium scales in circulating aqueous systems such as cooling water systems. The method comprises introducing into the aqueous system a compound of the general formula: ##STR1## wherein R is hydrogen, alkyl, aryl, substituted alkyl or substituted aryl; R' and R' are each independently hydrogen, C.sub.1-4 alkyl or C.sub.1-4 substituted alkyl; Z is 0, S, NH, or NR, where R is as described above; n is a positive integer greater than 1; f is a positive integer; and M is hydrogen, a water soluble cation (e.g., NH.sub.4.sup.+, alkali metal) or a C.sub.1 -C.sub.3 alkyl group.

Control of scale formation in aqueous systems

A method and composition for inhibiting silica and silicate deposition on metal surfaces in contact with aqueous systems is disclosed.

Method for inhibiting silica and silicate deposition

A method for the inhibition of silica and silicate deposits on the internal surfaces of a water system consisting of adding to the water system a composition comprised of a blend of two water soluble copolymers. The first copolymer contains repeat units of maleic or acrylic acids and a phosphinic acid, or salt forms thereof. The second copolymer contains repeat units of acrylic acid and allyl hydroxy propyl sulfonate ether, or salt forms thereof.

Composition for controlling silica and water soluble silicate deposition

A method and composition for controlling the formation and deposition of scale forming salts in a circulating aqueous system is described wherein a treatment solution of a substoichiometric amount of polyepoxysuccinic acid in combination with agaric acid is employed.

A method and polymers for inhibiting the formation of scale is disclosed. The method is particularly effective at inhibiting the formation and deposition of calcium scales in circulating aqueous systems such as cooling water systems. The method comprises introducing into the aqueous system a polymer of the general formula: ##STR1## wherein R is hydrogen, alkyl, aryl, substituted alkyl or substituted aryl; R' and R' are each independently hydrogen, C.sub.1-4 alkyl or C.sub.1-4 substituted alkyl; Z is O, S, NH, or NR, where R is as described above; n is a positive integer greater than 1; f is a positive integer; and M is hydrogen, a water soluble cation (e.g., NH.sub.4.sup.+, alkali metal), or a C.sub.1 -C.sub.3 alkyl group.

The treatment of an aqueous system to inhibit scale formation with a polyepoxysuccinic acid scale inhibitor, an acrylic acid copolymer and a lanthanide ion blending agent.

Compositions for controlling scale formation in aqueous system

A method of controlling the formation and deposition of scale forming salts in a circulating aqueous system is described wherein a treatment solution of a substoichiometric amount of polyepoxysuccinic acid in combination with agaric acid is employed.

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Morrisville, PA, United States of America

Libardo A Perez