Sulzer Metco (us) Inc.

General Electric Company

Oerlikon Metco (us) Inc.

Liangde Xie

Mitchell R Dorfman

Matthew Gold

Jacobus Cornelis Doesburg

Richard Karl Schmid

Jacobus C Doesburg

Michael Mueller

Ashish Patel

Srikanth Chandrudu Kottilingam

Byron Andrew Pritchard, Jr

Ambarish Jayant Kulkarni

Steven Charles Woods

Mark Lawrence Hunt

Jere Allen Johnson, Jr

Ronald Lee Souther

Gene Arthur Murphy, Jr

Matthew Charles Sabo

Jr Byron Andrew Pritchard

A vapor-based system and method for treating one or more components of a gas turbine engine. The system includes a treatment compound contained in a storage vessel. The storage vessel being operably coupled to a delivery module. The delivery module delivering the treatment compound at one or more locations of the gas turbine engine such that the treatment compound is a vapor when exposed to an engine air-path.

System and method for cleaning, restoring, and protecting gas turbine engine components

A high purity yttria or ytterbia stabilized zirconia powder wherein a purity of the zirconia is at least 99.5 weight percent purity and with a maximum amount of specified oxide impurities.

Ceramic material for high temperature service

Thermal barrier coating made from a thermally sprayable powder that includes yttria stabilized zirconia and hafnia, from 6 to 9 weight percent yttria, and total impurities less than or equal to about 0.1 weight percent. The thermal barrier coating has from about 5 to 250 vertical macro cracks per 25.4 mm length measured along a coating surface and the macro cracks are oriented perpendicular to a surface of a substrate containing said coating.

A hybrid diffusion-brazing process and hybrid diffusion-brazed article are disclosed. The hybrid diffusion-brazing process includes providing a component having a temperature-tolerant region and a temperature-sensitive region, brazing a braze material to the temperature-tolerant region during a localized brazing cycle, then heating the component in a furnace during a diffusion cycle. The brazing and the heating diffusion-braze the braze material to the component, and the localized brazing cycle is performed independent of the diffusion cycle in the hybrid diffusion-brazing process. The hybrid diffusion-brazed article includes a component, and a braze material diffusion-brazed to the component with a filler material. The filler material has a melting temperature that is above a tolerance temperature of the component.

Hybrid diffusion-brazing process and hybrid diffusion-brazed article

The present invention provides a high-purity fused and crushed stabilized zirconia powder. The powder&#x2014;with or without further processing, such as plasma spheroidization&#x2014;is used in thermal spray applications of thermal barrier coatings (TBCs) and high-temperature abradables. The resulting coatings have a significantly improved high temperature sintering resistance, which will enhance the durability and thermal insulation effect of the coating.

High-purity fused and crushed zirconia alloy powder and method of producing same

A metal oxide powder includes a powder feed material structured and arranged to form molten droplets when melted in a plasma stream. The molten droplets are structured and arranged to form frozen spherical droplets under free-fall conditions such that said molten droplets have ample time for complete in-flight solidification before reaching a collection chamber.

High purity and free flowing metal oxides powder

A process for modifying or repairing a metallic component, such as a combustion cap effusion plate for a gas turbine, is disclosed. The method includes generating a notch or groove in the metallic component and depositing a filler material in the notch or groove. A pulsed laser is applied to the filler material. The pulsed laser has a power, frequency, and pulse width sufficient to apply heat to the metallic component and to the filler material to make at least a portion of the metallic component and the filler material melt in order to weld the filler material to the metallic component and repair or modify the metallic component. Various operating parameters of the pulsed laser can be configured to reduce undesirable heating affects.

Combustion cap effusion plate laser weld repair

The invention is directed to a material and method for obtaining a ceramic abradable system for high temperature applications. High purity partially stabilized zirconia and/or hafnia base material has higher sintering resistance compared to conventional 6-9 weight percent yttria stabilized zirconia systems. The benefits of these systems are higher service lifetime and low thermal conductivity to achieve high operating temperatures. System includes a superalloy substrate, oxidation resistant bond coat and a thick ceramic abradable top coat. Total coating thickness is about 0.5-5 mm. In some applications an intermediate layer of high purity partially stabilized zirconia or a partially stabilized YSZ/MCrAlY cermet is applied over the oxidation resistant bond coat. In other applications an abradable system is applied on top of a grid. Additional benefits should be reduced blade wear at high operating conditions.

High purity ceramic abradable coatings

The invention is directed to high purity zirconia-based and/or hafnia-based materials and coatings for high temperature cycling applications. Thermal barrier coatings made from the invention high purity material was found to have significantly improved sintering resistance relative to coatings made from current materials of lower purity. The invention materials are high purity zirconia and/or hafnia partially or fully stabilized by one or any combinations of the following stabilizers: yttria, ytterbia, scandia, lanthanide oxide and actinide oxide. Limits for impurity oxide, oxides other than the intended ingredients, that lead to significantly improved sintering resistance were discovered. High purity coating structures suitable for high temperature cycling applications and for application onto a substrate were provided. In one structure, the coating comprises a ceramic matrix, porosity and micro cracks. In another structure, the coating comprises a ceramic matrix, porosity, macro cracks and micro cracks. In another structure, the coating comprises ceramic columns and gaps between the columns. In another structure, the coating comprises ceramic columns, gaps between the columns and nodules distributing randomly in the gaps and columns.

Optimized high temperature thermal barrier

According to aspects of the present invention, metal oxide powder, such as yttria and alumina powder (feed material), is processed using a plasma apparatus. The process generally consists of in-flight heating and melting of the feed material by the plasma apparatus. The plasma apparatus contains a plasma torch with required power supply and cooling systems, a powder feeder, a chamber to collect the powder and a dedusting system. The heated powder forms molten spherical droplets that are rapidly cooled under free fall conditions. The plasma densification process removes some impurity oxides, modifies the morphology of the particle and increases the apparent density of the powder.

Method for making high purity and free flowing metal oxides powder

The present invention provides a low density and porous zirconia (ZrO) powder partially alloyed with one or more of yttria, scandia, dysprosia, ytterbia, or any of the oxides of lanthanide or actinide. The total amount of alloying oxides should be less than about 30 weight percent. The powder is manufactured by controlled sintering or light plasma densification of physically agglomerated, or chemically derived zirconia composite powder that contains proper amounts of yttria, scandia, dysprosia, ytterbia, or any of the oxides of lanthanide or actinide, or any combination of the aforementioned oxides. The resulting coating from use of the inventive powder has a monoclinic phase content of less than 5 percent.

Partially-alloyed zirconia powder

The invention is directed to a ceramic material for use in thermal barriers for high temperature cycling applications and high temperature abradable coatings. The material is an alloy formed predominantly from ultra-pure zirconia (ZrO) and/or hafnia (HfO) that has uncharacteristically high sintering resistance to achieve a high service lifetime and low thermal conductivity to achieve high operating temperatures. In the material, oxide impurities such as soda (NaO), silica (SiO), alumina (AlO), titania (TiO), hematite (FeO), calcia (CaO), and magnesia (MgO) make up no more than 0.15 weight percent. The invention provides materials to produce a coating structure so that the changes in the coating microstructure over the in-service lifetime are either limited or beneficial.

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Pearl River, NY, United States of America

Liangde Xie