Taiwan Semiconductor Manufacturing Comp. Ltd.

Entegris, Inc.

Advanced Technology Materials, Inc.

Entegris Asia LLC

Li-Min Chen

Jian-Jou Lian

Neng-Jye Yang

Emanuel Israel Cooper

Kuo-Bin Huang

Kuo Bin Huang

Chia-Wei Wu

Steven Lippy

Yao-Wen Hsu

Kuan-Lin Chen

Sheng-Hung Tu

Ming-Hsi Yeh

Shun Wu Lin

Jeffrey A Barnes

Rekha Rajaram

Chia-Jung Hsu

Chieh Ju Wang

Lingyan Song

Yi-Nien Su

Yu-Yu Chen

Kuan-Wei Huang

Daniela White

Min-Chieh Yang

Hsing-Chen Wu

Embodiments described herein relate generally to methods for forming a conductive feature in a dielectric layer in semiconductor processing and structures formed thereby. In some embodiments, a structure includes a dielectric layer over a substrate, a surface modification layer, and a conductive feature. The dielectric layer has a sidewall. The surface modification layer is along the sidewall, and the surface modification layer includes phosphorous and carbon. The conductive feature is along the surface modification layer.

Surface modification layer for conductive feature formation

A method includes etching a dielectric layer to form an opening. A first conductive feature underlying the dielectric layer is exposed to the opening. A sacrificial spacer layer is deposited to extend into the opening. The sacrificial spacer layer is patterned. A bottom portion of the sacrificial spacer layer at a bottom of the opening is removed to reveal the first conductive feature, and a vertical portion of the sacrificial spacer layer in the opening and on sidewalls of the dielectric layer is left to form a ring. A second conductive feature is formed in the opening. The second conductive feature is encircled by the ring, and is over and electrically coupled to the first conductive feature. At least a portion of the ring is removed to form an air spacer.

Air spacer surrounding conductive features and method forming same

A semiconductor device and method of manufacture are provided. After a patterning of a middle layer, the middle layer is removed. In order to reduce or prevent damage to other underlying layers exposed by the patterning of the middle layer and intervening layers, an inhibitor is included within an etching process in order to inhibit the amount of material removed from the underlying layers.

Semiconductor device and method of manufacture

An etchant is utilized to remove a semiconductor material. In some embodiments an oxidizer is added to the etchant in order to react with surrounding semiconductor material and form a protective layer. The protective layer is utilized to help prevent damage that could occur from the other components within the etchant.

A method includes forming a tri-layer. The tri-layer includes a bottom layer; a middle layer over the bottom layer; and a top layer over the middle layer. The top layer includes a photo resist. The method further includes removing the top layer; and removing the middle layer using a chemical solution. The chemical solution is free from potassium hydroxide (KOH), and includes at least one of a quaternary ammonium hydroxide and a quaternary ammonium fluoride.

Chemical composition for tri-layer removal

Compositions useful for the selective removal of titanium nitride and/or photoresist etch residue materials relative to metal conducting, e.g., cobalt, ruthenium and copper, and insulating materials from a microelectronic device having same thereon. The removal compositions contain at least one oxidant and one etchant, may contain various corrosion inhibitors to ensure selectivity.

Compositions and methods for selectively etching titanium nitride

A method of manufacturing a semiconductor device includes exposing a material to a semi-aqueous etching solution. The semi-aqueous etching solution comprises a solvent which chelates with the material and acts as a catalyst between the etching driving force and the material. As such, the etching driving force may be used to remove the material.

Semiconductor device and method

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Zhubei, Taiwan

Li-Min Chen