Stratasys, Inc.

Lev Kuno

Shai Hirsch

Ira Yudovin-Farber

Mariana Pokrass

Yuval Vidavsky

Eynat Matzner

Dani Peri

Diana Ravich

Asher Razlan

Liora Damari

Oren Zoran

Eviatar Golan

Gilles Recher

Elena Shpayzer

Gil Shelef

Shai Sultan

Uri Zadok

Renata Drozdzak-Matusiak

Omer Sinwani

Jankiel Kimelblat

A method of additive manufacturing (AM) includes dispensing a first building material formulation to form an outer region, and dispensing a second building material formulation to form an inner region, the outer region surrounding the inner region, the inner and outer regions being shaped to form a layer of the object; exposing the layer to a first curing condition, repeating the dispensing and the exposing to sequentially form a plurality of layers of the object and collectively exposing the plurality of layers to a second curing condition. The selections are such that the first building material formulation is hardened to a higher degree than the second building formulation. The outer regions form a hardened coating that at least partially encapsulates the inner regions. The second curing condition is other than the first curing condition and is selected to increase the degree that the inner region is hardened.

Method for additive manufacturing with partial curing

Formulations usable in additive manufacturing, 3D inkjet printing in particular, of a three-dimensional object that contains a polyimide material, and additive manufacturing utilizing same are provided. The formulations contain a polyimide precursor (e.g., a bismaleimide) and an additional curable material, which is a multifunctional curable material, and are devoid of an organic solvent.

Additive manufacturing employing solvent-free polyimide-containing formulations

A support material formulation for use in additive manufacturing of a three-dimensional object, which, when hardened, is soluble upon immersion in water, is provided. The formulation includes a hydrophilic curable mono-functional material; a polyol (e.g., a branched polyol) having a molecular weight lower than 1,000, or lower than 800 grams/mol; and a polyester material having a molecular weight higher than 400, or higher than 500, grams/mol. Additive manufacturing using the disclosed formulation and objects made thereby are also provided.

Water-soluble support material formulation usable in additive manufacturing

A formulation system usable in additive manufacturing of a three-dimensional object that comprises, in at least a portion thereof, a cyanate ester-containing polymeric network, and additive manufacturing processes employing the formulation system are provided. Also provided are objects obtainable by the additive manufacturing and kits containing the formulation system. The formulation system includes a first modeling material formulation which includes a first curable material which is a thermally-curable cyanate ester and a second modeling material formulation which comprises an activating agent for promoting polymerization of the cyanate ester and is devoid of the first curable material, and further includes a second curable material which is different from the first curable material, and optionally an agent for promoting hardening of the second curable material.

Three-dimensional inkjet printing of a thermally stable object

Formulation systems usable for fabricating a three-dimensional object made of a polyamide-containing material, by three-dimensional 3D inkjet printing, and methods and systems utilizing same, are provided. The formulation systems are formed of at least a first and second model formulations containing a lactam and a catalyst for inducing anionic ring opening polymerization of the lactam in the first formulation, and an activator for promoting anionic ring opening polymerization of the lactam in the second formulation, and are further characterized as: including in the first and/or second formulation a compound capable of increasing a rate of said polymerization upon exposure to said curing energy; including as an activator a lactam-blocked polyisocyanate; and/or as including in the first model formulation at least one material capable of reducing a melting point of said first model formulation. Formulation systems usable at a selected ratio are also provided.

Three-dimensional inkjet printing using polyamide-forming materials

A method of additive manufacturing of a three-dimensional object, comprises: dispensing from a first array of nozzles a modeling material formulation containing a polyimide precursor to form a layer in a configured pattern corresponding to a shape of a slice of the object; applying to the layer ultraviolet radiation and infrared radiation from two different radiation sources; and repeating the dispensing and the application of radiation to form a plurality of layers in configured patterns corresponding to shapes of other slices of the object. Optionally, an additional modeling material formulation or a support material formulation is dispensed from a second array of nozzles.

Additive manufacturing employing polyimide-containing formulations

Methods for fabricating three-dimensional objects by 3D-inkjet printing technology are provided. The methods utilize curable materials that polymerize via ring-opening metathesis polymerization (ROMP) in combination with toughening agents for fabricating the object. Systems suitable for performing these methods and kits containing modeling material formulations usable in the methods are also provided.

Three-dimensional inkjet printing using ring-opening metathesis polymerization

Cyanate ester kit for a thermally stable object

Methods for fabricating three-dimensional objects by 3D-inkjet printing technology are provided. The methods utilize curable materials that polymerize via ring-opening metathesis polymerization (ROMP) for fabricating the object, in combination with acid-activatable pre-catalyst and an acid generator activator. Kits containing modeling material formulations usable in the methods are also provided.

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Tzur-Hadassah, Israel

Lev Kuno