General Electric Company

Leonard W Niedrach

Young Jin Kim

Fritz G Will

Peter Louis Andresen

George Charles Sogoian

Robert Lee Cowan, Ii

Oliver H LeBlanc, Jr

Jeffrey H Wengrovius

Dale F Taylor

Maurice E Indig

Laura L King

William H Stoddard, Jr

A metal cooling tube of a water-cooled nuclear reactor, having an inner surface thereof exposed to an aqueous cooling medium containing hydrogen peroxide. The cooling tube has its inner surface coated with matter selected from the group consisting of the element manganese, molybdenum, zinc, copper, cadmium for absorbing such hydrogen peroxide and then affecting decomposition of the hydrogen peroxide in the aqueous medium. In preferred embodiment such coating is manganese and oxides thereof. A method for lowering the electrochemical corrosion potential of a metal allow cooling tube exposed to an aqueous medium in a water-cooled nuclear reactor is also disclosed. Such method comprises the step of coating an inner surface of such tube with matter selected from the group of elements comprising manganese, molybdenum, zinc, copper, cadmium, so as to permit absorption and hydrogen peroxide in such aqueous medium and effect decomposition of hydrogen peroxide in such aqueous medium.

Catalytic hydrogen peroxide decomposer in water-cooled reactors

A method of reducing flow assisted corrosion of a carbon steel component exposed to flowing low-oxygen water is disclosed. The method comprises forming a coating of a platinum group metal on the carbon steel component, and providing a ratio of hydrogen to oxygen of about 1:8 or greater in the water.

Method for reducing flow assisted corrosion of carbon steel components

A high-chromium stainless steel alloy having improved resistance to stress corrosion cracking in high temperature water is comprised of, in weight percent; about 22 to 32 percent chromium, about 16 to 40 percent nickel, up to about 10 percent manganese, up to about 0.06 percent carbon, and the balance substantially iron. A preferred high-chromium alloy is further comprised of about 2 to 9 weight percent of a metal from the group consisting of titanium, niobium, tantalum, and mixtures thereof. Another preferred high-chromium alloy is further comprised of a platinum group metal in an effective amount to reduce the corrosion potential of the alloy in high-temperature water provided with hydrogen.

Corrosion resistant high chromium stainless steel alloy

A method for lowering the corrosion potential on components formed from carbon steel, alloy steel, stainless steel, nickel based alloys, or cobalt based alloys, and exposed to high-temperature water comprised of oxidizing species, comprising: providing a reducing species in the high temperature water that can combine with the oxidizing species, and forming the component to have a catalytic layer of a platinum group metal.

Method for reducing corrosion of components exposed to high-temperature

A method of extending the life of components of newly constructed nuclear reactors or newly replaced components of existing reactors is taught. The method involves forming a deposit on the surfaces of metallic elements of the nuclear containment, as well as on the surfaces of internal components which are exposed to high-temperature, high-pressure water and steam. The deposit formed is a deposit of at least one member of the platinum group of metals. The deposit is formed by any of a number of conventional methods such as electroless deposition, electrochemical deposition, chemical vapor deposition, sputtering or other conventional method. In operation, this deposit facilitates the combination of hydrogen and oxygen to form water and thereby aids in reducing the electrochemical corrosion potential of the system to values below a critical potential range that prevents stress corrosion cracking.

Method of providing extended life expectancy for components of boiling

A method of extending the life of components of in service nuclear reactors or components of existing reactors is taught. The method involves forming a deposit on the surface coatings of metallic elements of the nuclear containment, as well as on the surfaces of encrusted internal components which are exposed to high-temperature, high-pressure water and steam. The deposit formed is a deposit of at least one member of the platinum group of metals. The deposit is formed by electroless deposition. In operation, this deposit facilitates the combination of hydrogen and oxygen to form water and thereby aids in reducing the electrochemical corrosion potential of the system to values below a critical potential that prevents stress corrosion cracking.

Operation life of on-life boiling water reactors

A conductivity probe able to withstand high water temperatures and pressures, and intense nuclear radiation is suitable for use within the core of the nuclear reactor. The probe is made with a ceramic insulator, such as sapphire, and a central electrode that is mounted on the insulator. A sleeve that supports the insulator and the central electrode is made from metals having a coefficient of thermal expansion compatible with the coefficient of thermal expansion of the insulator, such as Kovar. The central electrode and sleeve are bonded to the insulator by a brazed compressive seal that protects an internal conductor in the probe from intrusion of the reactor water. A counter electrode made from a corrosion resistant metal, such as Kovar, is attached to the sleeve so that it extends over the central electrode a fixed, spaced distance. A positioning and signal transfer arrangement operatively supports the sleeve and conveys electrical signals to and from the two electrodes.

Conductivity probe for use in the presence of high intensity nuclear

An electrode probe suited for employment as a reference electrode in a high pressure, high temperature, and high radiation field environment such as adjacent the core of a nuclear reactor is described. The electrode is a brazed and welded assembly consisting of only ceramic and metal parts including a sapphire crucible which is brazed to a kovar/stainless steel housing, welded in turn, to a coaxial cable assembly for signal transfer. The crucible incorporates an integrally formed pedestal through which a conductor wire extends and over which is positioned a selectively coated cylindrically shaped sealing retainer. The device is particularly suited for employment with a silver/silver chloride electrode system.

Electrode probe for use in aqueous environments of high temperature and

An improved oxygen sensor is provided which gives oxygen concentration readings immediately and without the uncertain delays of a break-in period. The break-in period is decreased substantially by imparting to a copper counter electrode a uniform distribution of cuprous oxide throughout its structure. More reliable performance of the sensor is achieved.

Portable oxygen sensor with shortened break-in time

An oxygen sensor having increased stability in its sensitivity is provided. The oxygen sensor includes a sensing electrode spaced from a cadmium counter electrode. An alkaline electrolyte extends between the electrodes and permits the formation of cadmium hydroxide in the counter electrode as the cell is used. An electrical circuit connects the counter electrode and sensing electrode externally of the cell. The circuit includes a resistor and thermistor network and a voltmeter. Readings on the voltmeter can be calibrated to show the concentration of ambient oxygen diffusing a polymer membrane to the sensor electrode.

Long life portable oxygen sensor with high stability

Room temperature vulcanizable organopolysiloxane compositions are provided which exhibit improved stability and a reduced tendency to corrode copper upon contact resulting from the employment of an effective amount of a tin condensation catalyst having organo radicals attached to tin by carbon tin linkages and whose remaining valences are satisfied by a chelate radical or a dicarboxylate radical in combination with an organic triazole such as benzotriazole.

Room temperature vulcanizable organopolysiloxane compositions and method

A hydrogen ion sensor comprising in combination a gas impervious membrane sheath of an oxygen ion conducting ceramic, an electrochemical system partially contained therein, a terminal external to the ceramic sheath electrically connected to the electrochemical system and means for sealing the interior of the ceramic sheath from the ambient, the electrochemical system providing a fixed steady electrical potential that varies only with temperature between the inner surface of the ceramic sheath and the terminal.

Hydrogen ion sensor having a membrane sheath of an oxygen ion conducting

The reference electrode, which is physically removed from the sensing electrode, is functionally connected by means of a Ringer's solution formulation serving as an electrolyte bridge between the reference electrode and the fluid or tissue of the patient under test.

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Schenectady, NY, United States of America

Leonard W Niedrach