Exxon Research and Engineering Company

Aerojet-General Corporation

Exxonmobil Research and Engineering Company

Leonard Schoenman

Frank Hershkowitz

Harry William Deckman

Robert P Reynolds

Constantine P Gonatas

Jack I Ito

John W Fulton

Teh Chung Ho

George A Swan, Iii

Russell J Koveal

Dean C Draemel

Jackson I Ito

LeRoy R Clavenna

James H Taylor, Jr

Lavanga R Veluswamy

Jerrold E Franklin

Leroy Russell Clavenna

John B Mouritsen

Costas A Coulaloglou

Kris E Baxter

Kenneth G Kirk

Alfredo M Lopez

A process and apparatus for atomizing a fluid is disclosed. The processes and apparatuses are useful for atomizing a feed oil for a fluid cat cracking (FCC) or other suitable process.

Fluid atomization process

An atomizing gas, such as steam, and a hot fluid comprising a hot liquid to be atomized, are passed under pressure, through separate fluid conduits in a heat exchange means, in which the hot liquid heats the steam to a superheat temperature, by indirect heat exchange. The superheated steam is then injected into the hot fluid, which comprises a two-phase fluid comprising steam and the hot liquid, subsequent to the superheated steam injection. The two-phase fluid is passed through an atomizing means, such as an orifice, into a lower pressure atomizing zone, which causes the steam to expand and atomize the liquid into a spray of liquid droplets. The two-phase fluid is formed before or as a consequence of the superheated steam injection and is preferably steam-continuous when passed through the atomizing means. This process is useful for atomizing a hot feed oil for a fluid cat cracking (FCC) process.

Superheating atomizing steam with hot FCC feed oil

A novel injector/reactor apparatus and an efficient process for the partial oxidation of light hydrocarbon gases, such as methane, to convert such gases to useful synthesis gas for recovery and/or subsequent hydrocarbon synthesis. Sources of a light hydrocarbon gas, such as methane, and oxygen or an oxygen-containing gas are preheated and pressurized and injected through an injector means at high velocity into admixture with each other in the desired relative proportions, at a plurality of mixing nozzles which are open to the catalytic partial oxidation reaction zone and are uniformly-spaced over the face of the injector means, to form a reactant gaseous premix having a pressure drop equal to at least about 3% of the lowest upstream pressure of either of said gases. The gaseous premix is injected in a time period which is less than its autoignition time, preferably less than 9 milliseconds, at a velocity between about 25 to 1000 feet/second, into a catalytic partial oxidation zone so that the gaseous premix reacts in the presence of the fixed catalyst to reduce the amounts of CO,, H,O and heat produced by the partial oxidation reaction, to form a useful syngas which is cooled and recovered.

Distributed injection catalytic partial oxidation process and apparatus for producing synthesis gas

A novel fluidized bed syngas (FBSG) injector/reactor apparatus and an efficient process for the partial oxidation and steam reforming of light hydrocarbon gases such as methane, to convert such gases to useful synthesis gas containing CO and H.sub.2 for recovery and/or subsequent hydrocarbon synthesis. Sources of a light hydrocarbon gas, such as methane, and oxygen or an oxygen-containing gas are preheated and pressurized and injected through gas orifices of an injector at high velocity and comparable momentums into admixture with each other in the desired proportions, at a plurality of mixing chambers or recessed cups which are open to the fluidized bed reaction zone of a reaction chamber and are spaced over the face of the injector, to form a reactant gas premix having a pressure drop of at least 1% through the injector. The gaseous premix is injected in a time period which is less than its autoignition time, preferably less than 9 milliseconds, at a velocity between about 25 to 1000 feet/second, into a partial oxidation reaction zone comprising a fluid bed catalyst so that the gas mixture reacts in the catalyst bed, to reduce the amounts of CO.sub.2, H.sub.2 O and heat produced by the partial oxidation reaction to favor the desired stoichiometry. The formed syngas is cooled and recovered, such as use in further synthesis processing.

Face-mixing fluid bed process and apparatus for producing synthesis gas

A novel injector/reactor apparatus and an efficient process for the partial oxidation of light hydrocarbon gases, such as methane, to convert such gases to useful synthesis gas for subsequent hydrocarbon synthesis. Sources of a light hydrocarbon gas, such as methane, and oxygen or an oxygen-containing gas are preheated and pressurized and injected through an injector means at high velocity into admixture with each other in the desired proportions, preferably at comparable momentums, at a plurality of mixing nozzles which are open to the reaction zone of a reactor and are spaced over the face of the injector, to form a reactant gas premix having a pressure drop equal to at least 1% of the lowest upstream pressure of either of said gas streams. The gas premix is ejected in a time period which preferably is less than 9 milliseconds, at a velocity between about 25 to 1000 feet/second, into a reaction zone comprising a partial oxidation zone, so that the gas mixture reacts therein. The partially-oxidized effluent is then passed into a steam reforming catalyst zone to reduce the amounts of CO.sub.2, H.sub.2 O and heat produced by the partial oxidation reaction to form the useful syngas, which is cooled, recovered and/or further processed.

Multi-injector autothermal reforming process and apparatus for producing

A novel injector/reactor apparatus and an efficient process for the partial oxidation of light hydrocarbon gases, such as methane, to convert such gases to useful synthesis gas for recovery and/or subsequent hydrocarbon synthesis. Sources comprising a light hydrocarbon gas, such as methane, and oxygen or an oxygen-containing gas, preheated and pressurized, are injected through an injector means at high velocity into admixture with each other in the desired relative proportions, at a plurality of mixing nozzles which are open to the partial oxidation zone of a reactor and are uniformly-spaced over the face of the injector means, to form a reactant gaseous premix having a pressure at least 3% lower than the lowest upstream pressure of either of the streams of the individual gases. The gaseous premix is injected in a time period which is less than its autoignition time, preferably less than 9 milliseconds, at a velocity between about 25 to 1000 feet/second, into the partial oxidation zone of the reactor. The gas mixture reacts before or simultaneously with the autoignition time delay of the mixture, to reduce the amounts of CO.sub.2, H.sub.2 O and heat produced by the partial oxidation reaction to form a useful syngas which is cooled and recovered.

Distributed injection process and apparatus for producing synthesis gas

A novel injector/reactor apparatus and an efficient process for the partial oxidation of light hydrocarbon gases, such as methane, to convert such gases to useful synthesis gas for recovery and/or subsequent hydrocarbon synthesis. Sources of a light hydrocarbon gas, such as methane, and oxygen or an oxygen-containing gas are preheated and pressurized and injected through an injector means at high velocity into admixture with each other in the desired relating proportions, at a plurality of mixing nozzles which are open to the partial oxidation zone of a reactor and are uniformly-spaced over the face of the injector means, to form a gaseous premix having a pressure drop through the injector. The gaseous premix is injected in a time period which is less than 5 milliseconds, preferably at a velocity between about 25 to 1000 feet/second, into a partial oxidation reaction zone so that the gaseous premix reacts therein, to reduce the amounts of CO.sub.2, H.sub.2 O and heat produced by the partial oxidation reaction and form, cool and recover a useful syngas.

Rapid injection process and apparatus for producing synthesis gas (law

A novel injector/reactor apparatus and an efficient process for the partial oxidation of light hydrocarbon gases, such as methane, to convert such gases to useful synthesis gas for recovery and/or subsequent hydrocarbon synthesis. Sources of a light hydrocarbon gas, such as methane, and oxygen or an oxygen-containing gas are preheated and pressurized and injected through an injector means at high velocity into admixture with each other in the desired proportions, at a plurality of mixing nozzles which are open to the catalytic partial oxidation reaction zone of a reactor and are uniformly-spaced over the face of the injector, to form a reactant gaseous premix having a pressure drop through the injector. The gaseous premix is injected in a time period which is less than 5 milliseconds, at a velocity between about 25 to 1000 feet/second, into a reaction zone comprising a catalytic partial oxidation zone so that the gaseous premix reacts in the presence of the fixed catalyst arrangement to reduce the amounts of CO.sub.2, H.sub.2 O and heat produced by the partial oxidation reaction and form, cool and recover a useful syngas.

Rapid injection catalytic partial oxidation process and apparatus for

A combustor liner (2) for convectively cooling a combustor chamber (16) in a gas turbine (4) comprises a chamber wall (30) with an array of coolant channels (60) formed therein. Supply manifolds (50) are coupled to the coolant channel inlets for directing bypass air through the channels, where the bypass air removes heat from the chamber wall, and discharge manifolds (52) are coupled to the coolant channel outlets for discharging the heated bypass air to the turbine (10). The coolant channels are spaced and distributed throughout the combustor liner so that the coolant flows through a substantial portion of the liner. The coolant channels are minute channels with relatively short flow paths to minimize both the pressure drop and the quantity of bypass air required to cool the wall. In addition, the channels are completely enclosed within the chamber wall to significantly improve the heat transfer characteristics of the combustor liner. Because the chamber wall is cooled convectively, without bleeding air directly into the combustion chamber, the combustor liner is particularly suited for fuel-rich combustors, such as the first stage of a two stage low NOx combustor.

Convectively cooled liner for a combustor

A relatively inexpensive system and method for regulating the temperature of a cryogenic liquid in a storage vessel (2), such as vehicle refueling station, comprises inner and outer walls (6, 8) defining a inner chamber (12) for housing the cryogenic liquid. To provide a variable thermal resistance around the inner chamber, a thermal control fluid is disposed within an insulation space (10) between the inner and outer walls. A fluid conduit (30) has an inlet and outlet in fluid communication with the chamber and a heat exchanger coil (36) disposed within the insulation space. A control valve (38) allows the cryogenic liquid to flow through the fluid conduit so that the cryogenic liquid is in heat exchange relationship with the thermal control gas as the liquid passes through the coil (i.e., the cryogenic liquid cools and condenses the thermal control gas to reduce the control gas pressure). The pressure of the control gas within the insulation space can be modulated to thereby control the heat flow into the inner chamber by controlling the flow rate of the cryogenic liquid through the fluid conduit.

System and method for regulating the temperature of cryogenic liquids

Lightweight compressed gas cylinders are incorporated into a module which contains manifolding and which is designed for easy loading, unloading and transport on a flat-bed truck or other vehicle, particularly a roll-on roll-off transport truck, which is a specialized truck for mechanized handling of large containers. The module eliminates the need to retain the vehicle itself at the site of use. While a variety of cylinders of composite construction to achieve light weight can be used, certain novel composite cylinders whcih are particularly useful are also disclosed. These cylinders have a lightweight metallic liner or core cylinder wrapped with three layers of wound fiber. The inner and outer layers are axially-wound glass fiber and the intermediate layer is hoop-wound carbon fiber.

Compressed gas mobile storage module and lightweight composite cylinders

A method for operating a rocket engine by injecting fuel and oxidizer into an elongated combustion chamber in two flows, a core flow where the fuel and oxidizer are intimately mixed and immediately combusted and a peripheral curtain flow which surrounds the core flow and which is in contact with the combustion chamber wall to cool it and limit the heat transfer from the wall to the injector to prevent vapor locks in the injector. To prevent decomposed or partially combusted propellant products from chemically reacting with the chamber wall no mixing of fuel and oxidizer takes place in the curtain flow. The curtain flow is deflected radially inward into the core flow, before decomposed or partially combusted products can come into contact with the wall, into the core flow to fully combust the curtain flow out of contact with the wall. The rocket engine is defined by serially arranged first and second combustion chambers and an injector constructed to form the core and curtain flows. A ring plate projects radially inward at the downstream end of the first chamber and deflects the curtain flow into the coreflow.

Two stage rocket combustor

A method for operating a rocket engine by injecting fuel and oxidizer into an elongated combustion chamber in two flows, a core flow where the fuel and oxidizer are intimately mixed and immediately combusted and a peripheral curtain flow which surrounds the core flow and which is in contact with the combustion chamber wall to cool it and limit the heat transfer from the wall to the injector to prevent vapor locks in the injector. To prevent decomposed or partially combusted propellant products from chemically reacting with the chamber wall no mixing of fuel and oxidizer takes place in the curtain flow. The curtain flow is deflected radially inward into the core flow, before decomposed or partially combusted products can come into contact with the wall, into the core flow to fully combust the curtain flow out of contact with the wall. The rocket engine is defined by serially arranged first and second combustion chambers and an injector constructed to from the core and curtain flows. A ring plate projects radially inward at the downstream end of the first chamber and deflects the curtain flow into the coreflow.

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Citrus Heights, CA, United States of America

Leonard Schoenman