Monsanto Company

Ciba Specialty Chemicals Corporation

Brady Worldwide Corp.

Basf Se Corporation

Leonard Harris Davis

Aubert Y Coran

Ramanathan Ravichandran

Stephen Mark Andrews

Douglas Wayne Horsey

Anunay Gupta

Joseph Stephen Puglisi

Rangarajan Srinivasan

Bruce Vincent Hein

Robert Leo Gray

Paul Shields

Darrell David Dyas, Jr

David J Haas

Samuel J Tremont

Frederick Ignatz-Hoover

Robert J Holt

Martin P McGrath

Joseph Steven Puglisi

A long term rapid color changing time indicator includes a front part and a back part. The front part includes a transparent layer, an opaque layer, a colorant layer, and a neutralizing layer. The colorant layer includes a matrix and a colorant having a non-migratory form that does not migrate in the matrix and having a migratory form that migrates in the matrix. The back part has a reactant. When the front part and the back part are placed in contact, the reactant migrates into the neutralizing layer and a portion of the reactant is depleted by a coreactant. The unreacted reactant migrates into the colorant layer and reacts with the non-migratory form of the colorant converting the non-migratory form to the migratory form such that the migratory form of the colorant migrates through the opaque layer to cause a visual color indication in the transparent layer.

Long term rapid color changing time indicator

Polyolefins, especially polypropylene, can be made flame retardant by the incorporation therein of a synergistic mixture of a selected hindered amine substituted by an alkoxy, cycloalkoxy or hydroxyalkoxy moiety and a selected organic or inorganic brominated and/or phosphorus containing flame retardant, such as ammonium polyphosphate or decabromodiphenyl oxide wherein the amount of organic or inorganic flame retardant required to achieve an acceptable level of flame retardancy is significantly reduced compared to that needed when the hindered amine is not present.

Flame retardant compositions

Polyolefins, especially polypropylene, can be made flame retardant by the incorporation therein of a synergistic mixture of a selected hindered amine substituted by an alkoxy, cydoalkoxy or hydroxyalkoxy moiety and a selected organic or inorganic brominated and/or phosphorus containing flame retardant, such as ammonium polyphosphate or decabromodiphenyl oxide wherein the amount of organic or inorganic flame retardant required to achieve an acceptable level of flame retardancy is significantly reduced compared to that needed when the hindered amine is not present.

Vulcanizable rubber compositions are disclosed which contain co-activator of vulcanization which is a polymeric amine, that is, a hydrocarbon polymer with pendent alkyl amine groups. The co-activators impart increased rates of vulcanization with little decrease in scorch delay and very little increase in the modulus of the cured compositions. No increase in heat build-up or decrease in flex-fatigue life is shown. Typical polymers forming the backbone of the co-activators include EPDM rubber and polymers from butadiene or isoprene, with optional co-monomers.

Rubber compositions comprising a polymeric amine co-activator

Butadiene polymer rubber compositions containing a polymeric activator have particularly beneficial characteristics. The activator is an interpolymer of 2-vinylpyridine monomer and 1,3-butadiene monomer, optionally with styrene, which interpolymer contains from 20% to 65% by weight of vinylpyridine units, and is mostly insoluble in boiling tetrahydrofuran.

Rubber compositions containing polymeric activators

Butadiene polymer rubber compositions containing a polymeric activator have particularly beneficial characteristics. The activator is an interpolymer of a vinylpyridine monomer and a diene hydrocarbon monomer which interpolymer contains from 20% to 65% by weight of vinylpyridine units. Composite articles made from these rubber compositions together with contiguous portions of a dissimilar rubber compound show greater strength and adhesion as a result of the presence of a activator in the butadiene polymer rubber composition.

Butadiene polymer rubber compositions containing a polymeric activator have particularly beneficial characteristics. The activator is an interpolymer of a vinylpyridine monomer and a diene hydrocarbon monomer which interpolymer contains from 20% to 65% by weight of vinylpyridine units. Composite articles made from these rubber compositions together with contiguous portions of a dissimilar rubber compound show greater strength and adhesion as a result of the presence of the activator in the butadiene polymer rubber composition.

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New City, NY, United States of America

Leonard Harris Davis