Amoco Corporation

Opta Food Ingredients, Inc.

Monsanto Company

The Standard Oil Company

Standard Oil Company (indiana)

Enzytech, Ltd.

Leonard E Stark

Akiva T Gross

David R Marsh

Kenneth J Abrams

Martin A Zeitlin

James G Yarger

Michael M Schwartz

Harold A Lindahl

Ralph I Murray

Samuel Perry

Animal feed premix particles containing a carrier and a food additive is disclosed. The carrier is plant seed product having an ash content of less than about 10 percent by weight. The food additive 25-hydroxycholecalciferol, is soluble in organic solvents and is water-insoluble. An additive-effective amount of the food additive is homogeneously admixed with the carrier to prepare the premix particles.

Stabilized food additive

A process for ameliorating the effects of tibial dyschondroplasia while maintaining weight gain in poultry is disclosed as are a supplemented poultry feed and a feed supplement concentrate. The process contemplates feeding the bird with a poultry feed that contains 35 to 350 micrograms of 25-hydroxycholecalciferol per kilogram of feed. The supplement feed is used in the above process, whereas a feed supplement concentrate comprises a comestible diluent containing about 0.05 to about 100 mg of 25-hydroxycholecalciferol per gram of concentrate.

Use of 25-hydroxycholecalciferol in a dietary supplement process for

Water-dispersible microparticles of hydrophobic, water-insoluble, non-denatured protein, and method for preparing a suspension of these microparticles by the controlled precipitation of the protein, is described. The suspension can be used as a substitute for most dietary fats, or to encapsulate selected molecules. The water-insoluble proteins used in the process can be chemically or enzymatically modified to enhance the properties of the microparticles.

Hydrophobic protein microparticles

Hydrophobic protein microparticles and preparation thereof

The method and apparatus for manufacturing terephthalic acid (TA) are capable of producing TA having a closely controlled, desired amount of contaminant, 4-carboxy-benazldehyde (4-CBA), therein and/or a closely controlled optical density. In the method, a feed of para-xylene or similar feedstock mixed with catalyst components and solvent system is fed to a reactor stage comprising one or more reactors with oxygen for carrying out an exothermic oxidation reaction in the reactor stage, and an output slurry from the reactor stage is fed with oxygen to a first crystallizer of a crystallizing stage. The method comprises the steps of: determining empirical relationships between (1) the desired level of contaminant in the TA output product from the crystallizing stage and the oxygen uptake in the first crystallizer and (2) the oxygen uptake in the first crystallizer and the CO.sub.2 in the vent gas from the reactor stage; monitoring the CO.sub.2 in the vent gas from the reactor stage; and, adjusting operating variables of the reactor stage within minimum and maximum constraints thereof to adjust the reactor vent CO.sub.2 to a desired level. Also, the method includes the steps of: determining empirically a mathematical relationship between the oxygen in the vent gas from the reactor stage and the opticals or optical density of the TA output product; monitoring the oxygen in the vent gases; and, adjusting the air intake to the reactor stage until the oxygen in the reactor vent gas is at a desired level to provide TA output product with a desired optical density. The apparatus includes one or more reactors, one or more crystallizers, and control devices for carrying out the various steps of the method.

Method and apparatus for controlling the manufacture of terephthalic

This invention pertains to the production of high purity iso- or terephthalic acid by the catalytic liquid phase oxidation of m- or p-xylene with molecular oxygen gas in the presence of a solvent system consisting essentially of 85 to 97 weight percent liquid benzoic acid and 15 to 3 weight percent water to provide a fluid feed for the purification of such phthalic acid by hydrogenation of the fluid effluent of such oxidation in the presence of a heterogeneous catalyst containing a Group VIII noble metal at an elevated temperature at which all the aromatic oxygen-containing products are in solution under the requisite elevated pressure to maintain a liquid phase of said solution followed by the precipitation of such phthalic acid from solution and the separation washing and drying of the precipitate. Such integration of process steps eliminates expensive and time consuming intermediate steps of precipitating impure iso- or terephthalic acid from oxidation effluent, separation, washing and drying said impure precipitate as well as purification of solvent for recycle to oxidation.

Direct continuous flow integration of production and purification of

Continuous production of iso- or terephthalic acid in a stirred reaction zone by catalytic air oxidation of m- or p-xylene in the presence of a benzoic acid-water liquid solvent system at constant gauge pressure within the range of 7 to 21 kg/cm.sup.2 wherein oxidation temperature within the range of 175.degree. to 235.degree. C. is maintained substantially constant by the novel control thereof by only varying the flow rate of water condensate reflux to the oxidation zone. The invention further pertains to novel means for achieving such temperature control. Also, the present invention relates to a novel continuous recovery of the phthalic acid product from the fluid effluent of said continuous process by a process wherein crystalline phthalic acid product is separated from essentially water-free benzoic acid mother liquor; the crystalline product is successively washed with liquid benzoic acid and the corresponding xylene; the washed product is dried; and the water removed from said fluid effluent, the benzoic acid and xylene wash liquors, xylene recovered from product drying, and a major proportion of the benzoic acid mother liquor are charged to the oxidation process. The invention further relates to a novel combination of apparatus for the continuous conduct of said oxidation and recovery processes.

Apparatus for iso- or terephthalic acid production in and recovery from

This invention relates to the continuous production of iso- or terephthalic acid in a stirred reaction zone by catalytic air oxidation of m- or p-xylene in the presence of a benzoic acid-water liquid solvent system at constant gauge pressure within the range of 7 to 21 kg/cm.sup.2 wherein oxidation temperature within the range of 175.degree. to 235.degree. C. is maintained substantially constant by the novel control thereof by only varying the flow rate of water condensate reflux to the oxidation zone. The invention further pertains to novel means for achieving such temperature control. Also, the present invention relates to a novel continuous recovery of the phthalic acid product from the fluid effluent of said continuous process by a process wherein crystalline phthalic acid product is separated from essentially water-free benzoic acid mother liquor; the crystalline product is successively washed with liquid benzoic acid and the corresponding xylene; the washed product is dried; and the water removed from said fluid effluent, the benzoic acid and xylene wash liquors, xylene recovered from product drying, and a major proportion of the benzoic acid mother liquor are charged to the oxidation process. The invention further relates to a novel combination of apparatus for the continuous conduct of said oxidation and recovery processes.

Growing community of inventors

Naperville, IL, United States of America

Leonard E Stark