Spectral Sciences, Inc.

Other

United States of America As Represented by the Secretary of the Air Force

Lawrence S Bernstein

Fritz Bien

Steven M Adler-Golden

Alexander Berk

Gail P Anderson

Michael W Matthew

Neil M Goldstein

Michael E Gersh

Timothy C Perkins

James H Chetwynd

Prabhat K Acharya

Mitchell R Zakin

Richard A Moody

Robert Y Levine

John A Jamieson

David C Robertson

Eric P Shettle

Paul Lewis

Mitchelle Ross Zakin

Michael L Hoke

A radiative transport band model algorithm has been developed for prediction and analysis of high spectral resolution radiometric measurements. Atomic and molecular line center absorption is determined from finite spectral bin equivalent widths. A new mathematically exact expansion for finite bin equivalent widths provides high accuracy at any desired spectral resolution. The temperature and pressure dependent Voigt line tail spectral absorption contributing to each spectral bin is pre-computed and fit to Pad&#xe9; approximants for rapid and accurate accounting of neighboring-to-distant lines.

Band model method for modeling atmospheric propagation at arbitrarily fine spectral resolution

This invention discloses several improved methods of correcting for atmospheric effects on a remote image of the Earth's surface taken from above, wherein the image comprises a number of simultaneously acquired images of the same scene, each including a large number of pixels, each at a different wavelength band, and including infrared through ultraviolet wavelengths. One method is for retrieving the aerosol/haze amount (i.e., visible range) from an assumed ratio of in-band reflectances, rather than from an assumed reflectance value. Another method is for identifying cloud-containing pixels. This is used to improve the calculation of the spatially averaged radiance L*and reflectance &#x3c1;images in standard equations. Another method greatly reduces the number of mathematical operations required to generate the reflectance values. This method operates by averaging the water vapor and &#x3c1;values over small groups of neighboring pixels, so that the same A, B, S, L*parameter values may also be assigned to all pixels within the group. Yet another new method accounts for shifts in the wavelength calibration within the image, such as would be caused by spectral 'smile'. This method loops the calculation of A, B, S and L*over a set of possible wavelength shifts with respect to the input channel centers, and assigns the appropriate set of parameters to each pixel based on a pixel-location-dependent formula for the wavelength shift.

Methods for atmospheric correction of solar-wavelength hyperspectral imagery over land

A method of automatically determining a measure of atmospheric aerosol optical properties using a multi- or hyper-spectral, multi-pixel image. A plurality of spectrally-diverse pixels are resolved from the image. A statistical spectral deviation of the spectrally-diverse pixels is determined, and then corrected for non-aerosol transmittance losses. One or more wavelength-dependent aerosol optical depths are derived from the statistical spectral deviation. Wavelength-dependent gaseous optical depths can be derived from the statistical spectral deviation.

Methods for determining a measure of atmospheric aerosol optical properties using a multi- or hyperspectral, multi-pixel image

A method of automatically compensating a multi- or hyper-spectral, multi-pixel image for atmospheric effects, comprising resolving a plurality of spectrally-diverse pixels from the image, determining a spectral baseline from the spectrally-diverse pixels, determining a statistical spectral deviation of the spectrally-diverse pixels, normalizing the statistical spectral deviation by applying a scale factor, and compensating image pixels with both the spectral baseline and the normalized spectral deviation. Another embodiment features a method of automatically determining a measure of atmospheric aerosol optical properties using a multi- or hyper-spectral, multi-pixel image, comprising resolving a plurality of spectrally-diverse pixels from the image, determining a statistical spectral deviation of the spectrally-diverse pixels, correcting the statistical spectral deviation for non-aerosol transmittance losses, and deriving from the statistical spectral deviation one or more wavelength-dependent aerosol optical depths. A final embodiment features a method of automatically determining a measure of atmospheric gaseous optical properties using a multi- or hyper-spectral, multi-pixel image, comprising resolving a plurality of spectrally-diverse pixels from the image, determining a statistical spectral deviation of the spectrally-diverse pixels, and deriving from the statistical spectral deviation wavelength-dependent gaseous optical depths.

Method for performing automated in-scene based atmospheric compensation for multi-and hyperspectral imaging sensors in the solar reflective spectral region

A method and device for remotely analyzing an agent dispersed in the atmosphere is disclosed in which a body is dispensed into a volumetric region of the atmosphere overlapping the region containing the agent. The body is tailored to induce changes in an electromagnetic response of the volumetric region including the agent due to body the reactive probe and the agent. By sensing electromagnetic radiation from the region, information may be gained concerning the agent based upon the new electromagnetic response of the volumetric region induced by the reactions. Since a probe is used, source need not be known, and the electromagnetic signature may be tailored to atmospheric and device limitations.

System and method for remote detection and remediation of airborne and

Recent upgrades to the MOTRAN atmospheric radiation code improve the accuracy of its radiance predictions, especially in the presence of clouds and thick aerosols, and for multiple scattering in regions of strong molecular line absorption. MODTRAN3.5 features a generalized specification of cloud properties, while research version MODTRAN4 implements a Correlated-k (CK) approach for more accurate calculation of multiply scattered radiance. Comparisons to cloud measurements demonstrate the viability of the CK approach. The impact of these upgrades on predictions for AVIRIS viewing scenarios is discussed for both clear and clouded skies; the CK approach provides refined predictions for AVIRIS nadir and near-nadir viewing.

System and method for modelling moderate resolution atmospheric

A system and method for optical interrogation and measurement of a hydrocarbon fuel gas includes a light source generating light at near-visible wavelengths. A cell containing the gas is optically coupled to the light source which is in turn partially transmitted by the sample. A spectrometer disperses the transmitted light and captures an image thereof. The image is captured by a low-cost silicon-based two-dimensional CCD array. The captured spectral image is processed by electronics for determining energy or BTU content and composition of the gas. The innovative optical approach provides a relatively inexpensive, durable, maintenance-free sensor and method which is reliable in the field and relatively simple to calibrate. In view of the above, accurate monitoring is possible at a plurality of locations along the distribution chain leading to more efficient distribution.

Systems and methods for optically measuring properties of hydrocarbon

A selective chemical species detector including a conductive polymer based sensing element having a detectable characteristic, for example, the polymer resistivity, permanently altered on exposure to a first chemical species and not permanently altered on exposure to a second chemical species. The detector then determines a permanent change in the detected characteristic and indicates the presence of a chemical species on detection of a such a permanent characteristic change. Also disclosed is a method of fabricating such a sensing element to achieve the desired selectivity.

Method of making a conductive polymer selective species sensor

Conductive polymer selective species sensor

A wavelength-locked laser gaseous species monitor including a variable wavelength laser with a laser output actively stabilized to a wavelength at or near an absorption wavelength of the species being monitored. The laser is modulated about that wavelength to establish a modulated output with a known frequency and bandwidth. The modulated output is passed through the sample being monitored and then collected. An even harmonic of the collected output with respect to the modulation frequency is determined, and the presence in the sample of the species being monitored is detected from the even harmonic signal.

Gaseous species absorption monitor

An infrared trace element detection system including an optical cell into which the sample fluid to be examined is introduced and removed. Also introduced into the optical cell is a sample beam of infrared radiation in a first wavelength band which is significantly absorbed by the trace element and a second wavelength band which is not significantly absorbed by the trace element for passage through the optical cell through the sample fluid. The output intensities of the sample beam of radiation are selectively detected in the first and second wavelength bands. The intensities of a reference beam of the radiation are similarly detected in the first and second wavelength bands. The sensed output intensity of the sample beam in one of the first and second wavelength bands is normalized with respect to the other and similarly, the intensity of the reference beam of radiation in one of the first and second wavelength bands is normalized with respect to the other. The normalized sample beam intensity and normalized reference beam intensity are then compared to provide a signal from which the amount of trace element in the sample fluid can be determined.

Infrared trace element detection system

An infrared monitor for measuring the presence of at least one gas phase molecular species including a sample path for containing a sample to be monitored for the molecular species. A sample beam of infrared source emission of the molecular species to be monitored for passage through the sample path is provided to the sample path. The sample beam includes at least one primary spectral emission line which is significantly absorbed by the molecular species. The decrease in the intensity of the at least one primary infrared source spectral emission line passing through the sample path is detected as a function of the absorption of the at least one line by the molecular species present in the sample.

Infrared molecular species monitor

A spark discharge trace element detection system is provided which includes a spark chamber including a pair of electrodes for receiving a sample of gas to be analyzed at no greater than atmospheric pressure. A voltage is provided across the electrodes for generating a spark in the sample. The intensity of the emitted radiation in at least one primary selected narrow band of the radiation is detected. Each primary band corresponds to an element to be detected in the gas. The intensity of the emission in each detected primary band is integrated during the afterglow time interval of the spark emission and a signal representative of the integrated intensity of the emission in each selected primary bond is utilized to determine the concentration of the corresponding element in the gas.

Spark discharge trace element detection system

A spark spectroscopic high-pressure gas analyzer including a spark chamber, having a pair of electrodes, for receiving a sample of the pressurized gas to be analyzed. A voltage is provided across the electrodes for generating a spark in the pressurized gas sample. A selected wavelength band of radiation emitted from the spark discharge in the pressurized gas corresponding to a component to be sensed in the gas is detected. The intensity of the emission in the wavelength band is integrated during the afterglow time interval of the spark emission and a signal representative of the integrated intensity of the emission in the selected narrow wavelength band is employed to determine the proportion of the component in the gas.

Spark spectroscopic high-pressure gas analyzer

An ultraviolet absorption hygrometer is provided including a source of pulsed ultraviolet radiation for providing radiation in a first wavelength region where water absorbs significantly and in a second proximate wavelength region where water absorbs weakly. Ultraviolet radiation in the first and second regions which has been transmitted through a sample path of atmosphere is detected. The intensity of the radiation transmitted in each of the first and second regions is compared and from this comparison the amount of water in the sample path is determined.

Growing community of inventors

Lexington, MA, United States of America

Lawrence S Bernstein