Uop Lcc

W. R. Grace Co.-conn.

Lawrence L Upson

Rusty M Pittman

William E Cormier, Jr

John S Magee

Gerald M Woltermann

Fred J Baars

Robert L Mehlberg

Brian W Hedrick

Keith Allen Couch

Laszlo T Nemeth

James P Glavin

Julie E Wesling

Pieter J Van De Gender

Lazlo T Nemeth

Wim Van Dijk

One exemplary embodiment can be a process for fluid catalytic cracking. The process can include withdrawing a catalyst from a reaction vessel to replace a catalyst inventory over a period of about 10- about 35 days for maximizing propylene yield.

Maintaining catalyst activity for converting a hydrocarbon feed

One exemplary embodiment can be a fluid catalytic cracking system. Generally, the fluid catalytic cracking system includes a first reaction vessel and a second reaction vessel. The first reaction vessel may contain a first catalyst having pores with openings greater than about 0.7 nm and a second catalyst having pores with smaller openings than the first catalyst. What is more, the second reaction vessel may contain the second catalyst. Generally, at least a portion of the second catalyst is directly communicated with the first reaction vessel.

Fluid catalytic cracking system and process

Catalyst compositions comprising a siliceous zeolite component, either in separately formed catalyst particles or dispersed in the same binder or matrix as other zeolites of the compositions, are described. The catalyst compositions, for example as blends of three different bound zeolite catalysts, are particularly useful in fluid catalytic cracking (FCC) processes due to the reductions in coke and dry gas yields that allow FCC throughput, which is normally constrained by gas handling and/or catalyst regeneration capacity, to be increased.

Catalyst compositions for improved fluid catalytic cracking (FCC) processes targeting propylene production

An FCC process for obtaining light olefins comprises contacting a hydrocarbon feed stream with blended catalyst comprising regenerated catalyst and coked catalyst. The catalyst has a composition including a first component and a second component. The second component comprises a zeolite with no greater than medium pore size wherein the zeolite comprises at least 1 wt-% of the catalyst composition. The contacting occurs in a riser to crack hydrocarbons in the feed stream and obtain a cracked stream containing hydrocarbon products including light olefins and coked catalyst. The cracked stream is passed out of an end of the riser such that the hydrocarbon feed stream is in contact with the blended catalyst in the riser for less than or equal to 2 seconds on average. The hydrocarbon products including light olefins are separated from the coked catalyst. The first portion of the coked catalyst is passed to a regeneration zone in which coke is combusted from the catalyst to produce a regenerated catalyst. A second portion of the coked catalyst is blended with the regenerated catalyst and introduced to the riser. The regenerated catalyst has substantially the same relative proportions of the first component and the second component as the blended catalyst that contact the hydrocarbon feed stream.

FCC process with improved yield of light olefins

A high efficiency FCC process obtains the necessary regenerated catalyst temperature for a principally thermal cracking stage by cracking a light feedstock such as naphtha or a middle distillate in a first riser that principally performs thermal cracking and then cracks a heavy FCC feed in a second riser with a blend of catalyst from the principally thermal cracking step and recycle catalyst from the heavy feed to provide the necessary coke content on the catalyst that will produce high regenerated catalyst temperatures. The high temperature of the regenerated catalyst in the first riser provides a convenient means of cracking naphtha under high severity conditions and then using the remaining activity of the contacted catalyst for the principally catalytic reaction of the heavier feed. A separate thermal cracked product may be recovered from an intermediate blending vessel downstream of the first riser. Alternately, the thermal products such as cracked naphtha products may remain with the effluent from the second riser for separation from the heavy cracked products in a downstream separation zone.

FCC process with temperature cracking zone

An FCC process for obtaining light olefins comprises contacting a hydrocarbon feed stream with blended catalyst comprising regenerated catalyst and coked catalyst. The catalyst has a composition including a first component and a second component. The second component comprises a zeolite with no greater than medium pore size wherein the zeolite comprises at least 1 wt-% of the catalyst composition. The contacting occurs in a riser to crack hydrocarbons in the feed stream and obtain a cracked stream containing hydrocarbon products including light olefins and coked catalyst. The cracked stream is passed out of an end of the riser such that the hydrocarbon feed stream is in contact with the blended catalyst in the riser for less than or equal to 2 seconds on average.

An FCC process converts a secondary feed comprising a heart cut of a gasoline product stream with spent catalyst at mild conditions to obtain a surprising increase in the octane number of the resulting gasoline product. More surprisingly, the increase in gasoline stream octane number occurs with very low production of dry gas. Limiting the presence of heavy gasoline components was found to significantly raise the octane number produced by the process.

FCC process for upgrading gasoline heart cut

FCC process with high temperature cracking zone

An FCC catalyst system and a process using the catalyst system are disclosed. The catalyst system comprises a metal trap component, such as bastnaesite or barium titanate, and a sulfur oxide acceptor such as a magnesium spinel in addition to a zeolite. The metal trap and sulfur oxide components are preferably in separate particles. The catalyst formulation results in improved activity believed to result from the sulfur oxide acceptor protecting the metal trap component from the harmful effects of sulfur oxides such as the formation of stable metal oxides.

Increasing metal-tolerance of FCC catalyst by sulfur oxide removal

A metals-tolerant FCC catalyst and a process using the catalyst are disclosed. The catalyst matrix comprises bastnaesite and a limited quantity of a large pore boehmite alumina having an average pore diameter greater than 90 Angstroms. The catalyst preferably also contains a molecular sieve component, a siliceous binder and a clay component. The catalyst formulation reduces the harmful effects of accumulated nickel and vanadium on catalyst activity and selectivity. Hydrogen and coke production are reduced.

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Barrington, IL, United States of America

Lawrence L Upson