Ppg Industries Ohio, Inc.

Ppg Industries, Inc.

Lawrence D Meyers

Christopher A Verardi

William A Humphrey

Kurt Gordon Olson

Jonathan T Martz

Paul H Lamers

James Rowley

Carolyn A Novak

A polyurethane material, the coatings prepared therefrom, and methods of making the same are provided. An anionic self-crosslinkable polyurethane material has a weight average molecular weight of less than 15,000 grams per mole and, when cured, has a toughness of at least 20 MPa according to TOUGHNESS TEST METHOD at a temperature of 25&deg; C.

Curable polyurethanes, coatings prepared therefrom, and method of making the same

A polyurethane material, the coatings prepared therefrom, and methods of making the same are provided. A polyurethane material may be formed from components comprising at least one polyisocyanate, at least one active hydrogen-containing material, at least one material having at least one primary or secondary amino group and at least one hydroxyl group, and at least one acid functional material or anhydride having a functional group reactive with isocyanate or hydroxyl groups of other components from which the polyurethane material is formed. The polyurethane can provide improved physical properties, such as chip resistance, when incorporated into a coating composition.

A liquid coating composition has: from about 5 to 45 percent by weight of resin solids of substantially saturated polyhydroxylated polydiene polymer having terminal hydroxyl groups; from about 10 to 50 percent by weight of resin solids of crosslinking material; from about 5 to 85 percent by weight of resin solids of polymeric film forming resin; and solvent. The solvent has at least 5 percent by weight of the solvent composition consisting of water; and/or at least one organic solvent having Hansen Solubility Parameters Sp.sub.o from about 8.0 to 10.0 (cal/cm.sup.3).sup.1/2, Sp.sub.h from about 0.5 to 5.0 (cal/cm.sup.3).sup.1/2 ; and Sp.sub.p from about 0.2 to 3.0 (cal/cm.sup.3).sup.1/2 ; and/or mixtures thereof. The liquid coating composition can be solvent-based or aqueous-based and can additionally contain at least one pigment. The liquid coating composition can be coated directly onto thermoplastic and thermosetting plastic substrates, such as TPO and RIM, without the aid of flame or corona pretreatment, or the use of an adhesion promoter. A method of coating plastic substrates comprising the use of the liquid coating composition and a plastic article coated with the liquid coating composition are also disclosed.

Thermosettable primer and topcoat for plastics a method for applying and

A liquid coating composition has: from about 5 to 45 percent by weight of resin solids of substantially saturated polyhydroxylated polydiene polymer having terminal hydroxyl groups; from about 10 to 50 percent by weight of resin solids of crosslinking material; from about 5 to 85 percent by weight of resin solids of polymeric film forming resin; and solvent. The solvent has at least 5 percent by weight of the solvent composition consisting of water; and/or at least one organic solvent having Hansen Solubility Parameters Sp.sub.o from about 8.0 to 10.0 (cal/cm.sup.3).sup.1/2, SP.sub.h from about 0.5 to 5.0 (cal/cm.sup.3).sup.1/2, and Sp.sub.p from about 0.2 to 3.0 (cal/cm.sup.3).sup.1/2 ; and/or mixtures thereof. The liquid coating composition can be solvent-based or aqueous-based and can additionally contain at least one pigment. The liquid coating composition can be coated directly onto thermoplastic and thermosetting plastic substrates, such as TPO and RIM, without the aid of flame or corona pretreatment, or the use of an adhesion promoter. A method of coating plastic substrates comprising the use of the liquid coating composition and a plastic article coated with the liquid coating composition are also disclosed.

Thermosettable primer and topcoat for plastics, a method for applying

A liquid coating composition, comprising (a) from about 5 to 100 percent of resin solids of a mixture of (i) a substantially saturated polyhydroxylated polydiene polymer, having terminal hydroxyl groups, and (ii) a chlorinated polyolefin, wherein the weight of the polydiene polymer is between about 5 and 95 percent of the total weight of the mixture of polyhydroxylated polydiene polymer and chlorinated polyolefin; (b) about 0 to about 95 percent by weight of resin solids of a film forming polymer selected from liquid and carrier-reducible film forming polymers; and (c) a carrier material. The liquid coating composition can be solvent-based or aqueous based and can additionally contain at least on pigment. The liquid coating composition can be coated onto plastic substrates to improve the adhesion of subsequently applied coatings and to substantially improve the solvent resistance, especially to gasoline, of the finally coated plastic part.

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Allison Park, PA, United States of America

Lawrence D Meyers