Commonwealth Scientific and Industrial Research Organisation

The Furukawa Battery Co., Ltd.

International Lead Zinc Research Organisation Inc.

Lan Trieu Lam

Nigel Peter Haigh

Jun Furukawa

Rosalie Louey

Christopher G Phyland

Toshimichi Takada

Daisuke Monma

Daisuke Momma

David Anthony James Rand

Tetsuya Kanou

Yuichi Akasaka

Satoshi Shibata

Furukawa Jun

Yosuke Masuda

Akira Dobashi

Rosalle Louey

David Vella

Nicholas C Wilson

The present invention generally relates to electrodes for use in lead-acid battery systems, batteries and electrical storage devices thereof, and methods for producing the electrodes, batteries and electrical storage devices. In particular, the electrodes comprise active battery material for a lead-acid storage battery, wherein the surface of the electrode is provided with a coating layer comprising a carbon mixture containing composite carbon particles, wherein each of the composite carbon particles comprises a particle of a first capacitor carbon material combined with particles of a second electrically conductive carbon material. The electrical storage devices and batteries comprising the electrodes are, for example, particularly suitable for use in hybrid electric vehicles requiring a repeated rapid charge/discharge operation in the PSOC, idling-stop system vehicles, and in industrial applications such as wind power generation, and photovoltaic power generation.

Electrode and electrical storage device for lead-acid system

A lead-acid battery comprising: &#x2014;at least one negative electrode comprising lead-based battery electrode material and at least one region of capacitor material overlying the lead-based battery electrode material, each electrode being in electrical connection to an outer terminal of the battery, and &#x2014;at least one positive lead-dioxide based battery electrode, each positive electrode being in electrical connection to a second outer terminal of the battery, &#x2014;separator interleaving the facing electrodes; &#x2014;electrolyte filling at least the space of the electrodes and separators wherein the capacitor material overlying the lead-based battery electrode material comprises 20-65% by weight of a high electrical conductivity carbonaceous material, 30-70% of a high specific surface area carbonaceous material, at least 0.1% lead and binder.

Optimised energy storage device having capacitor material on lead based negative electrode

There is provided a method for producing a hybrid negative plate for a lead-acid storage battery which is improved in the production working efficiency and the productivity and enhances the quick charge and discharge characteristics and the discharge characteristics at a low temperature under PSOC of a lead-acid storage battery. A carbon mixture sheet produced by such a way that a carbon mixture prepared by mixing two types of carbon materials consisting of a first carbon material having electroconductivity and a second carbon material having capacitor capacitance and/or pseudocapacitor capacitance, and at least a binder, is adhered by pressure to the surface of a negative plate in a wet state, so that a hybrid negative plate is produced. The lead-acid storage battery provided with the hybrid negative plate is improved in the discharge characteristics.

Method for producing hybrid negative plate for lead-acid storage battery and lead-acid storage battery

[Problem] To provide a hybrid negative plate for a lead-acid storage battery, that inhibits decrease in hydrogen gas evolution potential and improves rapid discharge cycle characteristics in PSOC. [Means for Resolution] In a hybrid negative plate for a lead-acid storage battery, comprising a negative electrode active material-filled plate having formed on the surface thereof a coating layer of a carbon mixture comprising a carbon material for ensuring conductivity, activated carbon for ensuring capacitor capacity and/or pseudocapacitor capacity, and at least a binder, activated carbon modified with a functional group is used as the activated carbon. Preferably, activated carbon modified with an acidic surface functional group is used.

Hybrid negative plate for lead-acid storage battery and lead-acid storage battery

The present invention generally relates to electrodes, electrical storage devices comprising the electrodes, and methods for producing the electrodes and electrical storage devices. The electrodes comprise a current collector, an electrically conductive mat, and a first and second electroactive material, the first electroactive material having a higher energy density than the second electroactive material, and the second electroactive material having a higher rate capability than the first electroactive material. The electrically conductive mat provides a structural and conductive support for at least one of the high-rate and high-energy electroactive materials. The electrodes can be provided in various configurations and be used in high-rate high-energy electrical storage devices to provide improved cycle life.

Electrical storage device and electrode thereof

An energy storage device comprising at least one negative electrode, wherein each negative electrode is individually selected from (i) an electrode comprising negative battery electrode material; (ii) an electrode comprising capacitor electrode material; (iii) a mixed electrode comprising either&#x2014;a mixture of battery and capacitor electrode material or&#x2014;a region of battery electrode material and a region of capacitor electrode material, or&#x2014;a combination thereof, and wherein the energy storage device either comprises at least one electrode of type (iii), or comprises at least one electrode of each of types (i) and (ii),&#x2014;at least one positive electrode, wherein the positive electrode comprises positive battery electrode material and a charging ability-increasing additive, such as one or a mixture of: (a) carbon nanomaterial, vapor grown carbon fiber, fullerene, or a mixture thereof, and (b) tin dioxide conductive materials.

Energy storage device

A lead-acid battery comprising: The capacitor electrode may be a capacitor negative electrode comprising carbon and an additive mixture selected from oxides, hydroxides or sulfates of lead, zinc, cadmium, silver and bismuth, or a capacitor negative electrode comprising carbon, red lead, antimony in oxide, hydroxide or sulfate form, and optionally other additives. The capacitor electrode may be used in asymmetric capacitors and batteries of other types.

High performance energy storage devices

A method and apparatus for fast charging of batteries such as lead acid batteries is provided. A repeatedly pulsed current is applied to the battery to enable a determined resistance free maximum pulsed voltage to be reached where the determined resistance free maximum pulsed voltage is below that at which unacceptable gassing will occur. The determined resistance free maximum pulsed voltage is above that of a known average resistance free pulsed voltage for the battery type. When the determined maximum pulsed voltage is reached the pulsed current is continued to be applied to maintain the resistance free maximum pulsed voltage at approximately the determined resistance free maximum pulsed voltage by at least one of: (I) reducing the amplitude of the pulsed charging current, (II) increasing the OFF-time of pulses of the pulsed charging current, (III) decreasing the ON-time of pulses of the pulsed charging current, (IV) a combination of any two or more of (I), (II) or (III). In addition, the present invention may employ a combination of stages to charge the battery. Alternatively or in combination, the system may use a repeatedly pulsed charging current or a repeatedly pulsed charge voltage to control and adjust the charging of the battery.

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Springvale, Australia

Lan Trieu Lam