Sk Chemicals Co., Ltd.

Kolon Industries, Inc.

Kwang Sei Oh

Ji-Hoon Kim

Jong-In Lee

Il-Hoon Cha

Dong Hoon Lee

Na Young Kim

Eun Su Lee

Jung Hwa Park

Seung Jib Yum

Sun-Hee Lee

Myung-Se Lee

A heat-resistant, bio-based polycarbonate ester prepared by melt polycondensation of 1,4:3,6-dianhydrohexitol and a carbonate or 1,4-cyclohexanedicarboxylate is disclosed. The heat-resistant, bio-based polycarbonate ester includes a repeat unit 1 of Formula 1, a repeat unit 2 of Formula 2, and a repeat unit 3 of Formula 3. The polycarbonate ester has excellent heat resistance, transparency, and processability. A method of producing the polycarbonate includes a step of melt polycondensation of 1,4:3,6-dianhydrohexitol and a carbonate or 1,4-cyclohexanedicarboxylate.

Highly heat-resistant polycarbonate ester and preparation method therefor

A copolycarbonate ester produced from a polymerizable composition according to the present invention can have various physical properties including a melt flow index (MFI) of 43 g/10 minutes to 85 g/10 minutes under a load of 2.16 kg at 260°C. according to ASTM D1238 by being copolymerized through the melt-polycondensation of: 1,4:3,6-dianhydrohexitol and/or a diol compound other than 1,4:3,6-dianhydrohexitol including 1,14-tetradecanediol, 1,4-cyclohexanedimethanol, tricyclodecane dimethanol, 3,9-bis(1,1-dimethyl-2-hydroxyethyl)-2,4,8,10-tetraoxaspiro[5,5]udecane, bicycle[2.2.2]octane-2,3-dimethanol, 2,2-bis(4-hydroxycyclohexyl)propane, 2,2,4,4-tetramethyl-1,3-cyclobutanediol, 1,1-bis(4-hydroxyphenyl)-3,3,5-trimethylcyclohexane, 9,9-bis(4-hydroxyphenyl)fluorene, or tetrahydofuran-2,5-dimethanol; a carbonate compound; and a petroleum-based and/or bio-based diphenyl ester and/or an additional diphenyl ester compound other than the petroleum-based and/or bio-based diphenyl ester including diphenyl sebacate, diphenyl decahydronaphthalene-2,6-dicarboxylate, diphenyl tetrahydrofuran-2,5-dicarboxylate, or 2,5-diphenyl-furandicarboxylate, and can thus be usefully applied to the manufacture of segmented products.

Polymerizable composition, and copolycarbonate ester and method for producing same

Disclosed are: a reinforced composite membrane-type polymer electrolyte membrane which can prevent the loss of an ion conductor even when the ion conductor is chemically deteriorated due to long-term use, and thus has remarkably enhanced mechanical and chemical durability; a method for manufacturing same; and an electrochemical device comprising same. The polymer electrolyte membrane of the present invention comprises: a non-crosslinked ion conductor; and a porous support having a plurality of pores filled with the ion conductor, wherein the porous support comprises a polymer having at least one crosslinking functional group, and the crosslinking functional group is a functional group which, when the ion conductor is deteriorated, can cause crosslinking of the ion conductor by binding to the deteriorated ion conductor.

Polymer electrolyte membrane, manufacturing method therefor, and electrochemical device comprising same

The present invention relates to a highly bio-based polycarbonate ester and a method for producing same. The highly bio-based polycarbonate ester has a bio-based carbon content of 80% or more since the highly bio-based polycarbonate ester is obtained by copolymerization of 1,4:3,6-dianhydrohexitol, which is a bio-based monomer derived from biomass, and 1,4-cyclohexanedicarboxylate and/or terephthalate, and therefore, the highly bio-based polycarbonate ester is not only human-friendly and environmentally friendly, but also advantageous in terms of biodegradability.

Highly bio-based polycarbonate ester and method for producing same

The present invention is a composition for liquid crystal polymer synthesis comprising an alicyclic dicarboxylic acid or its derivative (e.g., 1,4-cyclohexanedicarboxylic acid (CHDA)); an aromatic diol (e.g., hydroquinone (HQ)); an aromatic monocarboxylic acid having 7 to 10 carbon atoms and containing a hydroxyl group (e.g., 4-hydroxybenzoic acid, (HBA)); and an aromatic monocarboxylic acid having 11 to 20 carbon atoms and containing a hydroxyl group (e.g., 6-hydroxy-2-naphthalenecarboxylic acid (HNA)), and a liquid crystal polymer for electrical/electronic products, a polymer resin composition, and a molded product using the same.

Composition for liquid crystal polymer synthesis, liquid crystal polymer for electrical/electronic products, polymer resin composition, and molded product using the same

Disclosed is a bio-based polycarbonate ester comprising: (i) repeat unit 1 obtained from a condensation reaction of 1,4:3,6 -dianhydrohexitol and carbonate; and (ii) repeat unit 2 obtained from a condensation reaction of 1,4:3,6-dianhydrohexitol and 1,4-cyclohexanedicarboxylate; and a preparation method for the bio-based polycarbonate ester, comprising the steps of: (1) preparing a compound 1,4-diphenyl-cyclohexanedicarboxylate through a trans-esterification or esterification reaction of a compound represented by formula 2 and phenol; and (2) preparing a compound comprising a repeat unit represented by formula 1 through a polycarbonate melt polycondensation reaction of the 1,4-diphenyl -cyclohexanedicarboxylate prepared in step (1), a compound represented by formula 4 and 1,4:3,6-dianhydrohexitol.

Highly heat-resistant and highly transparent polycarbonate ester, and preparation method therefor

The present invention relates to a molded product manufactured from a high heat resistant bio-based polycarbonate ester. More specifically, the molded product has excellent heat resistance, and thus can be applied to various fields such as those of automobiles, electrical electronics, displays, aviation, machines, lighting, medicine or food.

Molded product manufactured from high heat resistant polycarbonate ester

A method for preparing a polycarbonate ester includes feeding a monomer mixture containing (i) at least one compound selected from the group consisting of compounds of the following Formulae 1 and 3; (ii) a compound of the following Formula 2; and (iii) a 1,4:3,6-dianhydrohexitol to a polycondensation reactor and allowing the monomers and the 1,4:3,6-dianhydrohexitol to react to prepare the polycarbontate ester. The prepared polycarbonate ester has improved mechanical properties including tensile strength and impact strength: 

Polycarbonate ester and preparation method therefor

A bio-based polycarbonate ester resin is environment friendly by not containing a bisphenol, and exhibits excellent heat resistance, transparency, strength, hardness, dimensional stability and chemical resistance. Thus, the bio-based polycarbonate ester resin is suitable for use in an eyeglass frame. In addition, various colors may be painted and coated on during post-processing, a separate additive is not required during a molding process, and processing is undergone at a temperature lower than that for conventional plastic materials for an eyeglass frame, and thus manufacturing costs may be reduced.

Bio-based polycarbonate ester resin for eyeglass frame

A heat-resistant, bio-based polycarbonate ester prepared by melt polycondensation of 1,4:3,6-dianhydrohexitol and a carbonate, 1,4-cyclohexanedicarboxylate, or a terephthalate is disclosed. The heat-resistant, bio-based polycarbonate ester includes a repeat unit 1 of Formula 1, a repeat unit 2 of Formula 2, and a repeat unit 3 of Formula 3:  The polycarbonate ester has excellent heat resistance, transparency, and processability. A method of producing the polycarbonate includes a step of melt polycondensation of 1,4:3,6-dianhydrohexitol and a carbonate, 1,4-cyclohexanedicarboxylate, or a terephthalate.

Disclosed is a bio-based polycarbonate ester comprising: (i) repeat unit 1 obtained from a condensation reaction of 1,4:3,6-dianhydrohexitol and carbonate; and (ii) repeat unit 2 obtained from a condensation reaction of 1,4:3,6-dianhydrohexitol and 1,4-cyclohexanedicarboxylate; and a preparation method for the bio-based polycarbonate ester, comprising the steps of: (1) preparing a compound 1,4-diphenyl-cyclohexanedicarboxylate through a trans-esterification or esterification reaction of a compound represented by formula 2 and phenol; and (2) preparing a compound comprising a repeat unit represented by formula 1 through a polycarbonate melt polycondensation reaction of the 1,4-diphenyl-cyclohexanedicarboxylate prepared in step (1), a compound represented by formula 4 and 1,4:3,6-dianhydrohexitol.

A method for preparing a bio-based polycarbonate ester containing a repeating unit according to Formula 1 which comprises residue of Isosorbide and residue of CHDA (1,4-cyclohexanedicarboxylic acid). The method includes a nucleophilic reaction with phenol to prepare a 1,4-diphenyl-cyclohexanedicarboxylate, followed by a polycarbonate melt polycondensation reaction 

Method for preparing highly transparent and highly heat-resistant polycarbonate ester

Disclosed is a bio-based polycarbonate ester comprising: (i) repeat unit 1 obtained from a condensation reaction of 1,4:3,6-dianhydrohexitol and carbonate; and (ii) repeat unit 2 obtained from a condensation reaction of 1,4:3,6-dianhydrohexitol and 1,4-cyclohexanedicarboxylate; and a preparation method for the bio-based polycarbonate ester, comprising the steps of: (1) preparing a compound 1,4-diphenyl-cyclohexanedicarboxylate through a trans-esterification or esterification reaction of a compound represented by and phenol; and (2) preparing a compound comprising a repeat unit represented by through a polycarbonate melt polycondensation reaction of the 1,4-diphenyl-cyclohexanedicarboxylate prepared in step (1), a compound represented by 

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Seoul, South Korea

Kwang Sei Oh