Kurita Water Industries Ltd.

Kunihiro Hayakawa

Takahiro Kawakatsu

Tetsuya Aoki

Hideki Kobayashi

Masanobu Osawa

Nobuhiro Orita

Water discharged from a circulating cooling water system is treated by a water recovery system including a clarification equipment and an RO membrane, and treated water is returned to the circulating cooling water system. A dispersant is added to the circulating cooling water system for dispersing scale components. The dispersant includes a polymer having a carboxyl group and having a weight average molecular weight of 5,000 or less, and permeates through the clarification equipment. The polymer having a carboxyl group and having a weight average molecular weight of 5,000 or less permeates through the clarification equipment, and performs as a scale dispersing agent for the RO membrane, preventing precipitation of scale. Since the polymer intrinsically has an anticorrosion effect, it becomes unnecessary to add a phosphoric acid compound to the cooling water system as an anticorrosion agent, or the required amount of the compound to be added can be reduced.

Recovery method for discharged cooling water

The invention provides cleaning agents, cleaning liquids and cleaning methods that effectively remove contaminants which are impossible to remove sufficiently with conventional cleaning liquids at the occurrence of a decrease in performances such as permeation flux and salt rejection rate due to contamination of permeable membranes, in particular aromatic polyamide RO membranes used in water treatment. Permeable membranes are cleaned with a cleaning liquid which is an aqueous solution including a chloramine compound and an alkali agent and having a pH of 10 or above. The chloramine compound is preferably one obtained by mixing a compound having a primary amino group with hypochlorous acid and/or a hypochlorite.

Agent and method for cleaning permeable membranes

Provide is a reverse osmosis membrane device that is capable of treating raw water containing membrane-fouling substance in large quantities, such as MBR-treated water, in a stable manner while preventing decreases in permeate flow rate, and a method for operating thereof. A method for operating a reverse osmosis membrane device that treats raw water containing high-molecular-weight organic matter, wherein the raw water contains high-molecular-weight organic matter having a molecular weight of 10,000 or more at a concentration of 0.01 ppm or more, wherein the reverse osmosis membrane device is equipped with a spiral-type reverse osmosis membrane element that has a membrane surface area satisfying the below formula (1), and wherein the reverse osmosis membrane device is operated at a permeate flux of 0.6 m/d or less:membrane surface area(m)&#x2265;&#xd7;(11/16)&#x2003;&#x2003;(1)wherein n represents a diameter (inches) of the reverse osmosis membrane element.

Method for operating reverse osmosis membrane device, and reverse osmosis membrane device

Provided are reverse-osmosis-membrane device capable of treating raw water including a large amount of membrane foulants, such as MBR-treated water, with stability while preventing a reduction in the amount of permeate, and a method for operating the reverse-osmosis-membrane device. The raw water includes a high-molecular organic substance having a molecular weight of 10,000 or more at a concentration of 0.01 ppm or more. The reverse-osmosis-membrane device includes a reverse-osmosis-membrane element including a membrane unit, the membrane unit including a reverse osmosis membrane having a thickness of 0.1 mm or less, a feed spacer disposed on a surface of the reverse osmosis membrane, and a permeate spacer disposed on the other surface of the reverse osmosis membrane. The reverse-osmosis-membrane device is operated at a permeation flux of 0.6 m/d or less.

Reverse-osmosis-membrane device and method for operating the same

To provide a method for improving a rejection rate of an RO membrane, which further improves the stability of removal performance (rejection rate) and flux stability (sustainability of contamination resistance). In a method for improving a rejection rate of an RO membrane, including a step of allowing an aqueous solution containing a polyphenol to pass through an RO membrane, the method further includes a step of allowing an aqueous solution containing at least one type selected from the group consisting of a modified poly(vinyl alcohol), a high molecular polysaccharide, and a poly(amino acid) to pass through the RO membrane. The method preferably further includes a step of allowing an aqueous solution containing an organic compound having an amino group and having a molecular weight of 1,000 or less to pass through the RO membrane.

Method for improving rejection rate of reverse osmosis membrane

A method capable of effectively improving a rejection of a reverse osmosis membrane without remarkably reducing a permeation flux, even if the membrane is seriously degraded. An aqueous solution containing a first organic compound having a molecular weight of less than 200, a second organic compound having a molecular weight of 200 to less than 500, and a third organic compound having a molecular weight of 500 or more is passed through the reverse osmosis membrane. The first organic compound is preferably an amino acid or an amino acid derivative. The total concentration of the first organic compound and the second organic compound and the concentration of the third organic compound are each preferably 1 to 500 mg/L.

Method for improving rejection of reverse osmosis membrane, treatment agent for improving rejection, and reverse osmosis membrane

Disclosed are a method for further purifying ultrapure water, according to which any impurities in ultrapure water can be stably removed to a high degree within a small space over a prolonged period; and an apparatus therefor. Ultrapure water introduced into an ultrapure-water purifying apparatuspasses through an ion exchange resin layerin a lower chamber. During this process, metal ions, for example, in the ultrapure water are removed by the ion exchange resin. The ultrapure water then passes through a perforated plate, flows into an upper chamber, and permeates an ion exchange filter. During this process, metal ions and other impurities remaining unremoved by the ion exchange resin layerare removed. Specifically, metal ions are removed to a certain extent by the ion exchange resin, so that it is enough for the ion exchange filter provided downstream thereof to remove an extremely small amount of metal ions. Consequently, reaching of the ion exchange filter to breakthrough within a short period can be prevented, thereby attaining further purification of ultrapure water over a prolonged period of time.

Method and apparatus for further purifying ultrapure water

An agent for increasing the rejection with a permeable membrane which comprises an ionic macromolecule having a weight-average molecular weight of 100,000 or greater; a process for increasing the rejection with a permeable membrane which comprises treating a permeable membrane with the agent; a permeable membrane which is treated in accordance with the process; and a process for water treatment which comprises using the permeable membrane are disclosed. By using the above agent, an increased rejection of inorganic electrolytes and organic compounds soluble in water can be maintained for a long time easily and safely at the location of the use of the membrane without extreme decrease in the flux of permeation in the membrane separation using a selective permeable membrane such as a nano filtration membrane and a reverse osmosis membrane.

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Tokyo, Japan

Kunihiro Hayakawa