Sanyo Electric Co., Ltd.

C/o Intellectual Property H.q., Sanyo Electric Co., Ltd.

Kumiko Kanai

Masahisa Fujimoto

Takao Inoue

Hideyuki Koga

Masaharu Itaya

An object of the invention is to provide an inexpensive non-aqueous electrolyte secondary battery that allows reversible charge and discharge to be carried out and can be used for a long period because of a stable non-aqueous electrolyte used therein. The invention provides a non-aqueous electrolyte secondary battery including a positive electrode including a positive electrode active material and capable of storing and releasing sodium, a negative electrode capable of storing and releasing sodium, and a non-aqueous electrolyte, and the positive electrode active material includes sodium, nickel, manganese, and a transition metal that can exist in a hexavalent state. An example of the transition metal that can exist in a hexavalent state may include tungsten (W). An example of the negative electrode may include a sodium metal capable of storing and releasing sodium ions.

Non-aqueous electrolyte secondary battery

A material (hereinafter referred to as 'positive electrode material') including sodium manganate powder as a positive electrode active material, carbon black powder as a conductive agent, and polytetrafluoroethylene as a binder is prepared. The positive electrode material is mixed in an N-methylpyrrolidone solution to produce slurry as a positive electrode mixture. A working electrode is produced by applying the slurry on a positive electrode collector. A negative electrode containing tin or germanium is produced. The non-aqueous electrolyte is produced by adding sodium hexafluorophosphate as an electrolyte salt in a non-aqueous solvent produced by mixing ethylenecarbonate and diethyl carbonate.

Positive electrode and non-aqueous electrolyte secondary battery

A nonaqueous electrolyte battery whose electrolyte can be selected from a wider range of materials can be obtained. The nonaqueous electrolyte battery comprises a positive electrode, a negative electrode and a nonaqueous electrolytic solution. At least one of the positive and negative electrodes has a collector which includes a compound containing at least one element selected from the group consisting of transition metal elements, group III elements, group IV Elements, and group V elements.

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Osaka, Japan

Kumiko Kanai