Uop Lcc

Honeywell International Inc.

Krishna Mani

Gautam Pandey

Stanley Joseph Frey

Priyesh Jayendrakumar Jani

Deepak Bisht

Krishan Pratap Jadaun

Andrea G Bozzano

Ram Ganesh Rokkam

Avnish Kumar

Vikrant Vilasrao Dalal

Anjan Ray

Kanchan Dutta

Soumendra Mohan Banerjee

Haiyan Wang

Christopher D DiGiulio

Hari S Bajpai

Steven F Zink

Gaurav Srivastava

Shubhra J Bhadra

Mousumi Chanda

The apparatus produces a diesel stream from a biorenewable feedstock by hydrotreating to remove heteroatoms and hydroisomerization to improve cold flow properties. Heavy diesel can be hydrocracked to jet fuel range material or further hydroisomerized to increase its value lower its freeze point while light diesel may be taken as a motor fuel.

Process for producing jet fuel from a biorenewable feed

A process for hydrotreating a renewable feedstock with improved carbon monoxide management is disclosed. A mixture of renewable feedstock and hydrocarbon feedstock is treated in a hydrotreating reactor to produce a hydrotreated effluent stream and contacting the hydrotreated effluent stream with a water gas shift catalyst bed to produce a shift reactor effluent stream. The shift reactor effluent stream is passed to a cold separator to recover a cold vapor stream and recycling the cold vapor stream having reduced concentration of carbon monoxide to the hydrotreating zone. The subject matter disclosed provides an improved process and apparatus to reduce the accumulation of CO by converting CO present in the hydrotreated effluent stream to COusing the water shift gas reaction.

Integrated process for hydrotreating a renewable feedstock with improved carbon monoxide management

A process is provided for purification of biogas to produce biomethane. The biogas is treated in a pressure swing adsorption unit to remove carbon dioxide and water. Other impurities including oxygen, hydrogen and carbon monoxide may be removed by an additional adsorption bed. The adsorption beds may be single stage or two-stage VPSA or PSA adsorption beds.

Treatment of biogas by pressure swing adsorption

Hydrodeoxygenating a biorenewable feed that is concentrated in free fatty acids with 10-13 carbon atoms at a moderate hydrodeoxygenation ratio that is less than the ratio of hydrodeoxygenation utilized for traditional biorenewable feeds such as vegetable oil or even mineral feedstocks, normal paraffins in the range desired by the detergents industry can be produced. Either hydroisomerization or an iso-normal separation can be performed to provide green fuel streams. Two reactors are proposed, one for hydrodeoxygenation of the biorenewable feed that is concentrated in free fatty acids with 10-13 carbon atoms and the other for a traditional biorenewable feed or even a mineral feed operated at a higher deoxygenation ratio.

Process for producing renewable product streams

This disclosure provides an apparatus and method for harnessing machine learning and data analytics for a real-time predictive model for a FCC pre-treatment unit. The method includes collecting operating parameters of a pre-treatment unit and fluid catalytic cracking (FCC) unit; evaluating an independent variable of the operating parameters; and adjusting an input to the pre-treatment unit to control the independent variable within specifications in an output of the FCC unit.

Harnessing machine learning and data analytics for a real time predictive model for a FCC pre-treatment unit

The process produces a diesel stream from a biorenewable feedstock by hydrotreating to remove heteroatoms and hydroisomerization to improve cold flow properties. Heavy diesel can be hydrocracked to jet fuel range material or further hydroisomerized to increase its value lower its freeze point while light diesel may be taken as a motor fuel.

Processes for co-processing a naphtha stream with a light cycle oil stream are disclosed. The processes include hydrocracking the light cycle oil stream under hydrocracking conditions to provide a hydrocracked effluent stream. A naphtha stream is hydrotreated under hydrotreating conditions to provide a hydrotreated effluent stream. The hydrocracked effluent stream and the hydrotreated effluent stream may be passed to a stripping column to recover a stripping bottom stream. The stripping bottom stream may be passed to a main fractionation column to recover an intermediate naphtha stream.

Co-processing of light cycle oil and heavy naphtha

An integrated process for maximizing recovery of aromatics is provided. The process comprises passing at least a portion of a xylene column bottoms stream to a heavy aromatics column to provide a heavy aromatics column bottoms stream comprising Caromatics and a heavy aromatics column overhead stream. The heavy aromatics column bottoms stream is passed to a second stage hydrocracking reactor of a two-stage hydrocracking reactor. In the second stage hydrocracking reactor, the heavy aromatics column bottoms stream is hydrocracked in the presence of a hydrocracking catalyst and hydrogen to provide a hydrocracked effluent stream.

Integrated process for maximizing recovery of aromatics

An integrated process for maximizing recovery of hydrogen is provided. The process comprises: providing a hydrocarbonaceous feed comprising naphtha, and a hydrogen stream to a reforming zone, wherein the hydrogen stream is obtained from at least one of a hydrocracking zone, a transalkylation zone, and an isomerization zone. The hydrocarbonaceous feed is reformed in the reforming zone in the presence of the hydrogen stream and a reforming catalyst to provide a reformate effluent stream. At least a portion of the reformate effluent stream is passed to a debutanizer column of the reforming zone to provide a net hydrogen stream and a fraction comprising liquid petroleum gas (LPG). At least a portion of the net hydrogen stream is recycled to the reforming zone as the hydrogen stream.

Integrated process for maximizing recovery of hydrogen

An integrated process for maximizing recovery of LPG is provided. The process comprises providing a hydrocarbonaceous feed comprising naphtha, and a hydrogen stream to a reforming zone. The hydrocarbonaceous feed is reformed in the reforming zone in the presence of the hydrogen stream and a reforming catalyst to provide a reformate effluent stream. At least a portion of the reformate effluent stream and at least one stream comprising Chydrocarbons from one or more of a hydrocracking zone, an isomerization zone, and a transalkylation zone is passed to a debutanizer column of the reforming zone to provide a fraction comprising liquid petroleum gas (LPG) and a debutanizer column bottoms stream.

Integrated process for maximizing recovery of liquid petroleum gas

The present invention discloses a process and apparatus for selectively hydrogenating diolefins in a cracked stream. The method combines a conversion unit and a recovery section. The recovery section includes the diolefin hydrogenation reactor that is used to selectively hydrogenate the diolefins in the cracked naphtha. The diolefin depleted naphtha may be debutanized to separate the stabilized naphtha and liquefied petroleum gas streams.

Process and apparatus for selectively hydrogenating diolefins

Processes for the production of transportation fuel from a renewable feedstock. A catalyst is used which is more selective to hydrodeoxygenate the fatty acid side chains compared to decarboxylation and decarbonylation reactions. A gaseous mixture of carbon monoxide and hydrogen can be supplied to the conversion zone. Water may also be introduced into the conversion zone to increase the amount of hydrogen.

Processes for producing a fuel from a renewable feedstock

Processes for pyrolyzing biomass. A catalyst is used to both pyrolyze and deoxygenate the biomass within the pyrolysis zone. A source of carbon monoxide is also passed to the pyrolysis reactor. The source of carbon monoxide may comprise a stream of gas that includes carbon monoxide, or a material capable of generating or being converted in carbon monoxide within the pyrolysis zone. The carbon monoxide may be used as a reactant for a water gas shift reaction or as a reducing agent to remove oxygen from oxygenated hydrocarbons. The catalyst preferably comprises iron (III) oxide.

Processes for producing biomass-derived pyrolysis oils

Processes for the production of transportation fuel from a renewable feedstock. A gaseous mixture of carbon monoxide and hydrogen is used to deoxygenate and hydrogenate the glycerides to produce long chain hydrocarbons. The hydrocarbons may be isomerized to improve cold flow properties to provide a diesel fuel. Prior to isomerization, the long chain hydrocarbons can be separated or the separation can be after isomerization. Recycle gas streams from the isomerization and the deoxygenation and hydrogenation reactions may be used to supply at least a portion of the gaseous mixture of carbon monoxide and hydrogen. Synthesis gas may also be used to supply at least a portion of the gaseous mixture of carbon monoxide and hydrogen.

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Gurgaon, India

Krishna Mani