Exxon Research and Engineering Company

The Foundation at New Jersey Institute of Technology

National Starch and Chemical Corporation

Givaudan Corporation

Krishna K Rao

I-Der Huang

Tai-Cheng Yang

Leonard Dauerman

Joseph C Dabbs

Brian Delaney

Ji-Yong Ryu

Ralph J Spohn

Leon M Polinski

Robert Drogin

A process for preparing a vanadium, phosphorus oxygen containing catalyst composition capable of partially oxidizing hydrocarbons (e.g., n-butane) to form a carboxylic anhydride (e.g., maleic anhydride), and a process for using this catalyst to form such anhydrides is disclosed. The catalyst composition is prepared by an organic solution technique followed by activation in an air-hydrocarbon atmosphere.

Process for preparing a vanadium phosphorus oxygen catalyst composition

A vanadium, phosphorus oxygen containing catalyst composition capable of partially oxidizing hydrocarbons (e.g., n-butane) to form a carboxylic anhydride (e.g., maleic anhydride), a process for preparing this catalyst, and a process for using this catalyst to form such anhydrides is disclosed. The catalyst composition is prepared by an organic heterogenous technique followed by a water treatment step and activation.

Process for the synthesis of carboxylic anhydrides using a vanadium,

A heterogeneous process for preparing a vanadium-phosphorus-oxygen containing catalyst for use in the preparation of carboxylic anhydrides is disclosed. This process employs an activation procedure in an air-hydrocarbon atmosphere.

Process for oxidizing a carboxylic anhydride with heterogeneously

Heterogeneous process for preparing vanadium phosphorus oxygen

A vanadium, phosphorus oxygen containing catalyst compositions capable of partially oxidizing hydrocarbons (e.g., n-butane) to form a carboxylic anhydride (e.g., maleic anhydride), a process for preparing this catalyst, and a process for using this catalyst to form such anhydrides is disclosed. The catalyst composition is prepared by an organic heterogeneous technique followed by a water treatment step and activation.

Catalyst for carboxylic anhydride production

In the process of producing an aromatic polyisocyanate from a methylated benzene compound having the sequential steps of ammoxidation, hydrolysis, conversion of amide to carbamate, condensation and conversion of polycarbamate ester to polyisocyanate, the improvement of converting said amide to said carbamate in a one-step reaction wherein said amide is reacted with an N-halogenating agent in the presence of alcohol and in a reaction medium having a pH of from neutral to basic and a temperature greater than 40.degree. C.

Carbamate process

In an improved process for preparing discrete particles from solution polymers in which water and neutralizing agent are added to the polymer to form a suspension, the organic solvent is removed therefrom, and the particles are collected by filtration, washing and drying, the suspension is formed by co-feeding the flowable polymer and the aqueous phase containing neutralizing agent into a reactor vessel under specified conditions; stirring the reactants; and discharging the resultant suspension from the reactor vessel, with all steps being carried out in a continuous manner. In one embodiment of the process, additional neutralizing agent, which is preferably sodium hydroxide, is added to the suspension during removal of the solvent therefrom.

Continuous process for increasing discrete particle size of solution

In the process of desulfurizing flue gases in which an alkaline solution of sodium, such as sodium sulfite or sodium hydroxide, is contacted with gases in a scrubber to produce a sodium bisulfite solution, an improved method is provided for substantially reducing the time and equipment required to regenerate the sodium solution. In the method, a lime slurry stream and a sodium bisulfite stream are conflowed into a bifurcated mixing nozzle having a pair of converging inlets and a common outlet. The confluence of the streams in the nozzle creates turbulence which causes the lime slurry to react substantially instantaneously with the sodium bisulfite solution to regenerate the sodium solution which is recycled to the scrubber and a calcium sulfite precipitate which is filtered from the sodium solution and discarded.

Method using lime slurry for regenerating sodium sulfite in double

In the Double Alkali flue gas desulfurization process wherein sodium bisulfite is produced in a scrubber from the reaction of sulfur dioxide laden flue gases with an aqueous solution of sodium sulfite, the sodium sulfite is regenerated from the sodium bisulfite by reacting the same with a limestone slurry in a bifurcated mixing nozzle having a pair of converging inlets communicating with a common outlet. The reactants are flowed into the inlets at flow rates sufficient to produce turbulence in their zone of confluence in the nozzle to initiate a reaction which, although incomplete in the nozzle, proceeds at a rapid rate to completion after the mixed reactants leave the nozzle.

Sodium sulfite regeneration method using limestone slurry

Monohydric primary or secondary saturated and unsaturated alcohols are oxidatively dehydrogenated to the corresponding aldehyde or ketone over a gold catalyst at temperatures between 280.degree.-600.degree. C. in the presence of oxygen.

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Paterson, NJ, United States of America

Krishna K Rao