Daicel Chemical Industries, Ltd.

Kozo Kawahashi

Kiyokazu Murata

Mamoru Watabiki

A process for continuously producing aromatic carbonates comprising continuously feeding a dialkyl carbonate, an aromatic hydroxy compound, and a catalyst to a reactor equipped with a distillation tower, continuously distilling off a by-produced aliphatic alcohol from the distillation tower so as to keep the aliphatic alcohol concentration in the reactor at 2% by weight or less, and continuously withdrawing produced alkylaryl carbonate and/or diaryl carbonate and the catalyst from the reactor; and a process for continuously producing a diaryl carbonate comprising continuously feeding an alkylaryl carbonate and a catalyst to a reactor equipped with a distillation tower, continuously distilling off a by-produced dialkyl carbonate from the distillation tower so as to keep the dialkylcarbonate concentration in the reactor at 2% by weight or less, and continuously withdrawing the produced diaryl carbonate and the catalyst from the reactor are disclosed. Continuous production of aromatic carbonates can be performed in a stable manner without being accompanied by clogging of a distillation tower.

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Hyogo, Japan

Kozo Kawahashi