Toyo Seikan Kaisha, Ltd.

Tsukishima Kikai Co., Ltd.

Kozaburo Sakano

Jinichi Yazaki

Junichi Matsuo

Yoshitsugu Maruhashi

Sadao Hirata

Muneki Yamada

Takeshi Sugimoto

Shigezo Nohara

Akira Kishimoto

Fumio Kano

Toru Suzuki

Shunsaku Hirata

Yoshimichi Ohkubo

Nobuyuki Funakoshi

Kazuho Tanaka

Isamu Takeda

Isao Tanikawa

Toshiyuki Iwamoto

Yuji Yamaguchi

This invention provides a process a process for recovering terephthalic acid from pulverized products of spent polyethylene terephthalate. This process comprises (1) a decomposition reaction step where the pulverized products of spent polyethylene terephthalate are continuously subjected to decomposition reaction in ethylene glycol in the presence of alkali, which is equimolar or excessmolar relative to the polyethylene terephthalate, so that salt of terephthalic acid and ethylene glycol can be continuously obtained; (2) a solid-liquid separation, dissolution, impurities-removing step where the ethylene glycol is separated from decomposition reaction slurry of salt of terephthalic acid and ethylene glycol, and the solid salt of terephthalic acid is dissolved into water, while insoluble impurities are removed; (3) a neutralization, crystallization step, where solution of said salt of terephthalic acid is neutralized with acid so that terephthalic acid can be crystallized; (4) a solid-liquid separation, washing stop where slurry of terephthalic acid crystals is subjected to solid-liquid separation so that the terephthalic acid crystals can be obtained and washed; and (5) a drying, pulverization step where the washed terephthalic acid crystals are dried and pulverized.

Process for recovering terephthalic acid from pulverized product of spent polyethylene terephthalate and system for use in such process

This invention provides a process a process for recovering terephthalic acid from pulverized products of spent polyethylene terephthalate. This process comprises (1) a decomposition reaction step where the pulverized products of spent polyethylene terephthalate are continuously subjected to decomposition reaction in ethylene glycol in the presence of alkali, which is equimolar or excessmolar relative to the polyethylene terephthalate, so that salt of terephthalic acid and ethylene glycol can be continuously obtained; (2) a solid-liquid separation, dissolution, impurities-removing step where the ethylene glycol is separated from decomposition reaction slurry of salt of terephthalic acid and ethylene glycol, and the solid salt of terephthalic acid is dissolved into water, while insoluble impurities are removed; (3) a neutralization, crystallization step, where solution of said salt of terephthalic acid is neutralized with acid so that terephthalic acid can be crystallized; (4) a solid-liquid separation, washing step where slurry of terephthalic acid crystals is subjected to solid-liquid separation so that the terephthalic acid crystals can be obtained and washed; and (5) a drying, pulverization step where the washed terephthalic acid crystals are dried and pulverized.

At least an outer layer of a plastic container is formed of a blend including an ethylene-propylene block copolymer containing 3 to 10% by weight, particularly 5 to 9% by weight of ethylene and a melt flow rate of 0.8 to 10 g/10 min. and a polyethylene having a given density at a weight ratio of 9:1 to 5:5. A plastic container made of an olefin resin having a frosted or matted appearance can be manufactured with excellent moldability without requiring any special working such as sand blasting the cavity surface of a mold. The container will gives an impression of shade off, depth and high grade.

Frosted container

In a thermoplastic polyester, a compound having at least two ethylenically unsaturated groups and/or oxirane rings in one molecule is coated as a crosslinking agent on the outer surface of the polyester substrate, or a polyester composition containing this crosslinking agent is laminated on the polyester substrate as the inner surface layer, and the crosslinking agent or the crosslinking agent-containing polyester composition is irradiated with ionizing radiant rays or ultraviolet rays. In this processed vessel, the dimension stability and rigidity are highly improved, and deformation under heat and/or pressure can be effectively prevented.

Polyester vessel having improved dimension stability and process for

A process for the production of a multi-layer pipe to be used for formation of a bottle by draw-blow-forming, comprising forming by co-extrusion a pipe having inner and outer layers of a polyester composed mainly of ethylene terephthalate units and an intermediate layer of an oxygen-barrier resin interposed between the inner and outer layers, an adhesive resin layer is preferably interposed between every two adjacent layers. The co-extruded multi-layer pipe in the molten state so that the diameter of the pipe is sized is uniform. The process continues by cooling the outer portion of the molten multi-layer pipe by contact with water and simultaneously introducing an inert gas or an inert gas containing a water mist into the interior of the pipe to thereby cool the inner portion of the pipe and prevent oxidation in the pipe A. Multi-layer pipe prepared according to this process is excellent in the transparency and the draw-formability into a multi-layer drawn bottle.

Laminate preform for a multi-layer polyester bottle

An improved liquid transfusing bottle made of flexible material of the type using no air venting needle. It includes a barrel portion, a shoulder portion and a bottom portion and parting lines extend on both the side faces in the vertical direction. The barrel portion is formed with ribs or recessed area of which contour line is so designed that a distance as measured from the parting line decreases toward the center part of the bottle from the shoulder portion or the bottom portion. As a residual volume of liquid in the bottle decreases, the barrel portion is deformed in the flattened configuration along the contour lines of the ribs or the recessed parts in such a manner that the shorter diameter thereof is reduced. Deformation of the barrel portion is achieved without any occurrence of twisting, breaking or the like of the bottle and liquid in the bottle is smoothly discharged therefrom at a constant speed during operation of transfusion.

Liquid transfusing bottle

A process for the production of a multi-layer pipe to be used for formation of a bottle by drawblow-forming, comprising forming by co-extrusion a pipe having inner and outer layers of a polyester composed mainly of ethylene terephthalate units and an intermediate layer of an oxygen-barrier resin interposed between the inner and outer layers. An adhesive resin layer is preferable interposed between every two adjacent layers. The co-extruded multi-layer pipe is sized in the molten state so that the diameter of the pipe is uniform. The process continues by cooling the outer portion of the molten multi-layer pipe by contact with water and simultaneously introducing an inert gas or an inert gas containing a water mist into the interior of the pipe to thereby cool the inner portion of the pipe and prevent oxidation in the pipe. A multi-layer pipe prepared according to this process is excellent in the transparency and the draw-formability into a multi-layer drawn bottle.

Process for production of multi-layer pipes for draw-forming

Disclosed is a hot-melt adhesive composed of a composition comprising an acid-modified olefin resin formed by graft modification of an ethylenically unsaturated carboxylic acid or its anhydride or a resin composition containing said modified olefin resin and an oxirane ring-containing compound, wherein said composition has a carbonyl group concentration of 1 to 600 millimoles per 100 g of the composition and an oxirane oxygen concentration of 0.01 to 50 millimoles per 100 g of the composition.

Hot-melt adhesive as intermediate layer of a laminate structure

Hot-melt adhesive

Disclosed is a multi-layer drawn plastic vessel comprising at least one layer composed mainly of at least one crystalline olefin resin selected from crystalline polypropylene and crystalline propylene/ethylene copolymers having an ethylene content of 1 to 20 mole %, at least one oxygen-barrier layer composed mainly of an ethylene/vinyl alcohol copolymer having an ethylene content of 25 to 60 mole %, and an adhesive resin layer interposed between said two resin layers, said adhesive resin layer containing an acid- or acid anhydride-modified, linear, low-density polyethylene or a mixture of said polyethylene with an acid- or acid anhydride-modified propylene resin and said crystalline olefin resin layer being molecularly oriented in at least one direction.

Multi-layer drawn plastic vessel

Disclosed is a multi-layer plastic vessel comprising a laminate including at least one layer composed mainly of a moisture-resistant thermoplastic resin, at least one layer composed mainly of an ethylene-vinyl alcohol copolymer and a thermoplastic resin adhesive layer interposed between both the resin layers, wherein said adhesive layer is composed of a composition comprising an acid- or acid anhydride-modified olefin resin and an epoxidized unsaturated carboxylic acid ester.

Multi-layer plastic vessel

Disclosed is a laminated plastic container in the form of a bottle, the wall of which comprises a substrate formed of a melt-moldable plastic material, a coating layer formed on at least one surface of the substrate, said coating layer being composed of a copolymer consisting essentially of 99 to 70% by weight of vinylidene chloride and 1 to 30% by weight of at least one acrylic or methacrylic monomer and further including up to 100 parts by weight of at least one member selected from other ethylenically unsaturated monomers per 100 parts by weight of the total amount of said two monomers, said copolymer having an oxygen permeation coefficient of less than 9.times.10.sup.-14 cc.multidot.cm/cm.sup.2 .multidot.sec.multidot.cmHg as measured at a temperature of 20.degree. C. and a relative humidity of 100% and a water vapor permeability coefficient of less than 3.times.10.sup.-3 g.multidot.cm/m.sup.2 .multidot.day as determined according to the method of JIS Z-0208, and a protecting surface layer of a film-forming synthetic resin other than a vinylidene chloride resin, which is formed contiguously to said coating layer. This laminated plastic container is excellent in the barrier property to various gases such as oxygen, water vapor, nitrogen and carbon dioxide gas and other properties required for plastic containers. The humidity dependency of the oxygen barrier property is highly improved in this laminated plastic container.

Laminated plastic container and process for preparation thereof

A transparent multi-layer container comprising a co-extrudate of an oxygen-barrier resin layer and an orienting resin layer which is monoaxially or biaxially oriented is disclosed. An adhesive resin layer is preferably interposed between the oxygen-barrier layer and the orienting resin layer, and this co-extrudate is drawn and molded at a specific temperature determined relatively to the melting points and softening points of the respective resins. This container is excellent in the combination of transparency, rigidity, mechanical strength, gas-barrier property and interlaminar peel strength.

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Kawasaki, Japan

Kozaburo Sakano