Mitsui Chemicals, Inc.

Tohcello Co., Ltd.

Prime Polymer Co., Ltd.

Kou Tsurugi

Isao Hara

Atsushi Shibahara

Kazumori Kawamura

Tatsuya Nakamura

Akiko Matsumoto

Shiori Hanada

Fumiaki Nishino

Yasuyuki Harada

Wataru Yamada

Toshihiro Muroto

Yoshihisa Inoue

Akira Nomoto

Tomoyoshi Hakamata

Osamu Nakamura

Yoshihiro Yamamoto

Naoto Matsukawa

Keita Itakura

Tetsuya Hamada

Seiichi Ishii

Yasushi Nakayama

Yasuhiko Suzuki

Hiroyoshi Watanabe

Naritoshi Yoshimura

Shinsuke Kinoshita

Susumu Murata

Yasunori Saito

Nobuhiro Tanabe

Ryoko Hiroi

Shino Naito

Takanori Furuta

Siori Hanada

A propylene polymer composition includes a propylene homopolymer (A) having an intrinsic viscosity [η] measured in a tetralin solvent at 135° C. in the range of 7 to 12 dl/g, a propylene polymer (B) having an intrinsic viscosity [η] in the range of not less than 0.21 dl/g and less than 0.54 dl/g, and having a proportion of a component eluted at a temperature of not more than −20° C. in TREF in the range of not more than 3.5 mass %, and a propylene polymer (C) having an intrinsic viscosity [η] in the range of not less than 0.54 dl/g and less than 2.6 dl/g, wherein the content of (A) is 0.5 to 47.5 mass %, the content of (B) is 5 to 95 mass % and the content of (C) is 2.5 to 85.5 mass %, based on the total of (A), (B) and (C).

Propylene polymer composition and shaped article

An object of the invention is to provide a solid polyaluminoxane composition suitably used as a cocatalyst and a catalyst carrier in combination with an olefin oligomerization or polymerization catalyst, without the use of solid inorganic carriers such as silica. The solid polyaluminoxane composition of the invention includes a polyalkylaluminoxane and a trialkylaluminum, and has a solubility in n-hexane at 25&#xb0; C. of less than 0.50 mol % as measured by a specific method (i), a solubility in toluene at 25&#xb0; C. of less than 1.0 mol % as measured by a specific method (ii), and a 13 mol % or more molar fraction of alkyl groups derived from the trialkylaluminum moieties relative to the total number of moles of alkyl groups derived from the polyalkylaluminoxane moieties and the alkyl groups derived from the trialkylaluminum moieties as measured with respect to tetrahydrofuran-dsoluble components by a specific method (iii).

Solid polyaluminoxane composition, olefin polymerization catalyst, olefin polymer production method and solid polyaluminoxane composition production method

A method for producing a solution containing at least an unsaturated carboxylic acid-modified vinyl alcohol polymer is characterized by reacting a vinyl alcohol polymer and an unsaturated carboxylic acid compound in the presence of an acid catalyst soluble in the reaction system or a solid acid catalyst, and a gas barrier film is obtained by using the same. An example thereof is a method for producing a solution (A) containing an unsaturated carboxylic acid-modified vinyl alcohol polymer (b), the method comprising following two steps of: (1) a reaction step in which the unsaturated carboxylic acid-modified vinyl alcohol polymer (b) is formed by reacting a vinyl alcohol polymer and an unsaturated carboxylic acid compound (a) in the presence of an acid catalyst soluble in the reaction system; and (2) an ion exchange step in which at least the acid catalyst of acidic compounds is removed by an anion exchange resin.

Method for producing unsaturated carboxylic acid-modified vinyl alcohol polymer, and gas barrier film or gas barrier laminate using the same

The invention provides transition metal complex compounds, high-activity olefin oligomerization catalysts containing the compounds, and olefin oligomerization processes using the catalysts. A transition metal complex compound [A] according to the invention is represented by Formula (I) or Formula (I') below. An olefin oligomerization catalyst includes the transition metal complex compound [A]. In an olefin oligomerization process of the invention, an olefin is oligomerized in the presence of the catalyst. 

Transition metal complex compounds, olefin oligomerization catalysts including the compounds, and processes for producing olefin oligomers using the catalysts

Disclosed is an excellent gas barrier laminate whose gas-barrier property has little dependency on temperature and which hardly causes fracture even when the laminate is stretched. A gas barrier film comprising a polymer (A) of an unsaturated carboxylic acid compound monovalent metal salt (a), wherein the polymer (A) contains a modified vinyl alcohol polymer (B); a gas barrier laminate comprising a base layer and the gas barrier film formed on at least one surface of the base layer; and a method for production of a gas barrier laminate comprising the steps of: coating a solution of an unsaturated carboxylic acid compound monovalent metal salt (a) having a polymerization degree less than 20 on at least one surface of a base layer, wherein the solution contains a modified vinyl alcohol polymer (B); performing the polymerization to form a layer of the polymer (A) of the unsaturated carboxylic acid compound monovalent metal salt (a) containing the modified vinyl alcohol polymer (B).

Gas barrier film, gas barrier laminate and method for manufacturing film or laminate

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Sodegaura, Japan

Kou Tsurugi