Mitsubishi Gas Chemical Company, Inc.

Kosuke Otsuka

Takafumi Oda

Masayuki Daito

Takumi Yamada

Jun Mitadera

Tomonori Kato

Nobuhiko Matsumoto

Shinichi Ayuba

Kaname Sato

Yuya Okajima

Provided are a resin composition having excellent oxygen barrier property under high humidity as a novel resin material, a molded body, a method for producing a molded body, and a method for producing a pellet using the resin composition. The resin composition includes a resin component and a plate-shaped talc having an aspect ratio of more than 18, 80 mass % of the resin component comprising a barrier resin having an oxygen transmission coefficient of 5.0 cc·mm/(m·day·atm) or less as measured according to ASTM D3985 at a relative humidity of 60% and a temperature of 23° C., and a content of the plate-shaped talc being from 3.0 to 55.0 mass % when a total of the barrier resin and the plate-shaped talc is 100 mass %.

Resin composition, molded body, and their application

Provided is a multilayer container having a polyester layer containing a polyester resin (X), and a polyamide layer containing a polyamide resin (Y) and a yellowing inhibitor (A). The content of the polyamide resin (Y) is from 0.05 to 7.0 mass % relative to the total amount of all polyamide layers and all polyester layers. The yellowing inhibitor (A) is a dye. The content of the yellowing inhibitor (A) is from 400 to 800 ppm relative to the polyamide layer. An L* of the multilayer container is 87.5 or greater.

Multi-layer container, method for producing same, and method for producing reclaimed polyester

Provided is a polyamide resin having a low mass loss at a temperature slightly higher than the melting point. The polyamide resin includes diamine-derived structural units and dicarboxylic acid-derived structural units, and of the diamine-derived structural units, from 70 to 97 mol % are derived from p-benzenediethanamine and from 3 to 30 mol % are derived from a diamine represented by formula (1). 50 mol % or more of the dicarboxylic acid-derived structural units are derived from an aromatic dicarboxylic acid.

Polyamide resin

Provided is a stretched body having a high barrier property under high humidity, a PET bottle, and a method for producing a container. The stretched body of a composition containing a semi-aromatic polyamide resin and plate-shaped talc having an aspect ratio of more than 18, a content of the plate-shaped talc having an aspect ratio of more than 18 in the composition is from 3.0 to 55.0 mass % when a total content of the semi-aromatic polyamide resin and the plate-shaped talc having an aspect ratio of more than 18 is 100 mass %.

Stretched body, PET bottle, and method for producing container

An easily tearable film with excellent linear cuttability, as well as a multilayer film, a packaging material, and a container are provided. The easily tearable film is a polyamide resin film including polyamide resin components including more than 20 parts by mass and 70 parts by mass or less of a semi-aromatic polyamide resin A and less than 80 parts by mass and 30 parts by mass or more of an aliphatic polyamide resin B; wherein the semi-aromatic polyamide resin A is constituted of a diamine-derived constituent unit and a dicarboxylic acid-derived constituent unit; 60 mol % or more of the diamine-derived constituent units are derived from metaxylylenediamine; 60 mol % or more of the dicarboxylic acid-derived constituent units are derived from an α,ω-linear aliphatic dicarboxylic acid having from 4 to 10 carbons; and the polyamide resin film is stretched, the polyamide resin film having an area fraction corresponding to the semi-aromatic polyamide resin A, as observed in secondary electron image observation, of 9.8% or more after plane ion milling of a cross section of the polyamide resin film in the TD direction.

Easily tearable film, multilayer film, packaging material, and container

Provided is a multilayer container including a polyester layer containing a polyester resin (X), and a polyamide layer containing a polyamide resin (Y), a yellowing inhibitor (A), and an oxidation accelerator (B). The content of the polyamide resin (Y) is from 0.05 to 7.0 mass % relative to the total amount of all polyamide layers and all polyester layers. The yellowing inhibitor (A) is a dye, and the content of the yellowing inhibitor (A) is from 1 to 30 ppm relative to the total amount of all polyamide layers and all polyester layers.

Multilayer container, method for manufacturing same, and method for manufacturing reclaimed polyester

Provided is a multilayer container including: a polyester layer containing a polyester resin (X); and a polyamide layer containing a polyamide resin (Y) and a yellowing inhibitor (A). The content of the polyamide resin (Y) is from 0.05 to 7.0 mass % relative to a total amount of all polyamide layers and all polyester layers, and the content of the yellowing inhibitor (A) is from 1 to 30 ppm relative to the total amount of all polyamide layers and all polyester layers. Also provided are a method for manufacturing the multilayer container, and a method for manufacturing a recycled polyester, the method thereof including a step of recovering polyester from the multilayer container.

An easily tearable film includes polyamide resin components including more than 20 parts by mass and 70 parts by mass or less of a semi-aromatic polyamide resin A and less than 80 parts by mass and 30 parts by mass or more of an aliphatic polyamide resin B; wherein the semi-aromatic polyamide resin A is constituted of a diamine-derived constituent unit and a dicarboxylic acid-derived constituent unit; 60 mol % or more of the diamine-derived constituent units are derived from metaxylylenediamine; 60 mol % or more of the dicarboxylic acid-derived constituent units are derived from an &#x3b1;,&#x3c9;-linear aliphatic dicarboxylic acid having from 4 to 10 carbons; and the molar concentration of phosphorus atoms, the total molar concentration of alkali metal atoms and the total molar concentration of alkaline earth metal atoms, and Mn of the semi-aromatic polyamide resin satisfy predetermined relationships.

Provided is a stretched film stretched stretchable to a high draw ratio a method for manufacturing the stretched film, and, a polyamide resin composition used for manufacturing the stretched film. The stretched film containing 0.5 to 15 parts by weight of a compound represented by Formula (1) per 100 parts by weight of a polyamide resin, wherein the polyamide resin is composed of a structural unit derived from diamine and a structural unit derived from dicarboxylic acid; 50% by mole or more of the structural unit derived from diamine is derived from xylylenediamine, and 50% by mole or more of the structural unit derived from dicarboxylic acid is derived from a straight-chain aliphatic am-dicarboxylic acid having 4 to 20 carbon atoms: wherein Rrepresents an alkyl group having 1 to 10 carbon atoms, Rrepresents an alkyl group having 2 to 12 carbon atoms, and n represents an integer of 1 to 3. 

Stretched film, method for manufacturing stretched film, and, polyamide resin composition

Provided is a polyamide resin composition comprising an elastomer etc, and a reactive polyamide resin excellent in reactivity. The polyamide resin composition comprises 0.5 to 100 parts by mass of an elastomer per 100 parts by mass of a reactive polyamide resin, wherein the reactive polyamide resin obtained by polycondensing a diamine (A) containing 70 mol % or more of a diamine structural unit derived from xylylenediamine and a dicarboxylic acid (B) containing 50 mol % or more of a dicarboxylic acid structural unit derived from sebacic acid, and has a concentration of reactive functional groups of 100 &#x3bc;eq/g or more and a molar ratio of reacted diamine to reacted dicarboxylic acid (the number of moles of reacted diamine/the number of moles of reacted dicarboxylic acid) of 1.0 or more.

Growing community of inventors

Hiratsuka, Japan

Kosuke Otsuka