Sk Innovation Co., Ltd.

Sk on Co., Ltd.

Kook Hyun Han

Duck Chul Hwang

Kyung Bin Yoo

Jik Soo Kim

Mi Jung Noh

Min Gu Kang

Seong Ho Lee

Ji Hoon Choi

Jung In Yeon

Sang Bok Kim

A cathode active material for a lithium secondary battery according to embodiments of the present invention includes a lithium metal oxide particle which includes a core part and a shell part and contains nickel (Ni), cobalt (Co) and manganese (Mn). A total Ni content of the lithium metal oxide particle is 70 mol % or more based on a total 100 mol % of Ni, Co and Mn. The shell part includes a depth region in a range of 10 to 100 nm from a surface of the lithium metal oxide particle, and a Co content thereof in the depth region is 1.4 to 6 times a Co content of the core part. Stability of the lithium secondary battery may be improved through surface treatment using high content of Co.

Positive electrode active material for lithium secondary battery, method for manufacturing same, and lithium secondary battery including same

A cathode active material precursor according to embodiments of the present invention includes a composite hydroxide particle in which primary precursor particles are aggregated. The primary precursor particles include a particle having a triangular shape in which a minimum interior angle is 30° or more and a ratio of a length of a short side relative to a length of a long side is 0.5 or more. A cathode active material and a lithium secondary having improved high temperature stability is provided using the cathode active material precursor.

Cathode active material precursor, cathode active material, lithium secondary battery and method of manufacturing the same

A cathode active material for a lithium secondary battery includes a lithium-aluminum-titanium oxide formed on a surface of a lithium metal oxide particle having a specific formula. The cathode active material may have an improved structural stability even in a high temperature condition.

Cathode active material for lithium secondary battery and lithium secondary battery including the same

A lithium secondary battery comprises a cathode formed from a cathode active material including a first cathode active material particle and a second cathode active material particle, an anode and a separator interposed between the cathode and the anode. The first cathode active material particle includes a lithium metal oxide including a continuous concentration gradient in at least one region between a central portion and a surface portion. The second cathode active material particle includes a constant concentration composition.

Lithium secondary battery and method of fabricating the same

A lithium secondary battery includes a cathode formed from a cathode active material including a cathode active material particle having a specific concentration ratio, an anode; and a separation layer interposed between the cathode and the anode. The lithium secondary battery has improved formation discharge amount, formation discharge efficiency and power output.

Lithium secondary battery

A lithium secondary battery includes a cathode formed from a cathode active material including a first cathode active material particle and a second cathode active material particle, an anode and a separator interposed between the cathode and the anode. The first cathode active material particle includes a lithium metal oxide including a continuous concentration gradient in at least one region between a central portion and a surface portion. The second cathode active material particle includes a lithium metal oxide including elements the same as those of the first cathode active material particle, and the second cathode active material particle has a uniform composition from a central portion to a surface.

Provided is a lithium secondary battery including a cathode containing a cathode active material in which a central part has a different concentration from a surface part, and a conductive material having a specific composition ratio, and specifically, a lithium secondary battery including a cathode containing a cathode active material in which a central part of one or more kinds of metals configuring the cathode active material has a different concentration from a surface part thereof, and two or more kinds of conductive materials mixed at a specific ratio, thereby having excellent stability and high low-temperature characteristic and high output characteristic as compared to a conventional lithium secondary battery.

Provided is a lithium secondary battery containing a cathode active material capable of preventing decreases in power and cycle life occurring at the time of adding a sulfur based additive used in order to improve high-temperature storage characteristics to an electrolyte.

Provided is a porous lithium composite phosphate-based compound containing lithium and having open pores formed in primary particles. As the open pores are formed in the primary particles themselves, a contact area between an electrolyte and the lithium composite phosphate-based compound is maximized, and low conductivity is compensated for, such that a diffusion rate of lithium ions is remarkably increased, and when the lithium composite phosphate-based compound is used as an active material of a secondary battery, the secondary battery may be charged and discharged at a high speed. Additionally, there are advantages in that an electrode density may be significantly increased in addition to the increase in the diffusion rate of the lithium ions, and charge and discharge cycle characteristics may be significantly stable.

Lithium composite phosphate-based compound and preparation method therefor

In a method of preparing a lithium metal oxide, a preliminary lithium metal oxide is prepared. The preliminary lithium metal oxide is washed using a washing solution to remove lithium salt impurities. The washing solution includes water and an organic ligand multimer compound. The lithium metal oxide having improved structural uniformity and stability is obtained using the washing solution.

Method of preparing lithium metal oxide and method of manufacturing lithium secondary battery

In a method of preparing a lithium metal oxide, a preliminary lithium metal oxide is prepared. The preliminary lithium metal oxide is washed using an organic washing solution to remove lithium salt impurities. The organic washing solution includes an organic solvent and a multivalent carboxylic acid compound. A minimum distance between oxygen atoms included in different carboxylic acid groups neighboring each other in the multivalent carboxylic acid compound is 220 pm or more.

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Daejeon, South Korea

Kook Hyun Han