3m Innovative Properties Company

Ineos Styrolution Group Gmbh

Konstantin Mierdel

Achim Schmidt-Rodenkirchen

Klaus Hintzer

Norbert Niessner

Thorsten Gerdes

Arne Thaler

Bianca Wilhelmus

Frank Neuner

Gregg D Dahlke

Denis Duchesne

Mark W Muggli

Markus E Hirschberg

Thomas W Schoettle

The process produces a fluorinated olefin from a fluorinated copolymer having at least one of sulfonic acid groups, carboxylic acid groups, or salts thereof. The process includes heating the fluorinated copolymer at a first temperature not more than 450° C. to decompose at least one of the sulfonic acid groups, carboxylic acid groups, or salts thereof to form a partially pyrolyzed intermediate and subsequently heating the partially pyrolyzed intermediate at a second temperature of at least 550° C. to produce the fluorinated olefin.

Process of making fluoroolefins by thermal decomposition of fluorinated ionomers

The invention relates to a method for producing styrene monomers by the depolymerisation of polystyrene in the presence of foreign polymers, such as polyolefins. Said method comprises the following steps: a) introducing a polymer composition (A) containing: I) 10 to 99.5% by weight, based on the polymer composition (A), of polystyrene (I); and II) 0.1 to 89.9% by weight of polyolefin (II); and/or III) 0.1 to 4.9% by weight of acrylonitrile-based polymer (III); and/or IV) 0.1 to 4.9% by weight of polyester (IV), into the reaction zone (R) of a pyrolysis reactor (P); b) thermal cracking the polystyrene contained in the polymer composition (A) in the reaction zone (R) of the pyrolysis reactor (P) at a temperature of between 400-1000° C., c) removing the product mixture (G) obtained from the reaction zone (R), d) cooling of the product mixture (G), and e) separating the styrene monomers from the further components.

Method for the depolymerisation of polystyrene in the presence of foreign polymers

The invention relates to a process for the preparation of styrene monomers by depolymerising polystyrene, to a device for carrying out the process and to the use of a fluidised bed reactor for the depolymerisation of polystyrene. Said process comprising the following steps: a) feeding a polymer composition (A) containing 60 to 99.9 wt. polystyrene, based on the total weight of the polymer composition (A), into the reaction zone (R) of a pyrolysis reactor (P); b) thermally cracking the polystyrene contained in the polymer composition (A) in the reaction zone (R) of the pyrolysis reactor (P) at a temperature of between 400° C. to 1000° C. to obtain a product mixture (G) containing styrene monomers and other components; c) removing the product mixture (G) obtained in step b) from the reaction zone (R) of the pyrolysis reactor (P); d) cooling the product mixture (G) removed in step c) to obtain a condensed product mixture (K) containing styrene monomers and further components; and e) separating the styrene monomers from the further components of the condensed product mixture (K) obtained in step d), wherein the average residence time (Z) of the polymer composition (A) in the reaction zone (R) of the pyrolysis reactor (P) is from 0.01 sec to 10 sec.

Process for the depolymerization of polystyrene

Methods of converting a variety of fluorinated materials into anhydrous hydrogen fluoride are described. The methods include thermally decomposing the fluorinated materials into a gaseous effluent comprising hydrogen fluoride and carbon dioxide. This gaseous effluent is then treated with carbon at a temperature of at least 830° C., converting the carbon dioxide to carbon monoxide (CO) and producing a gaseous product comprising the hydrogen fluoride, which can be condensed to generate anhydrous hydrogen fluoride. These methods can also be used to convert water contained in the gaseous effluent into hydrogen.

Converting fluorinated materials into anhydrous hydrogen fluoride

Growing community of inventors

Bayreuth, Germany

Konstantin Mierdel