Zimmer Aktiengesellschaft

Davy Mckee Corporation

Davy Mckee Aktiengesellschaft, Borsigalle

Konrad Wolff

Hans-Jochen Rothe

Georg Skupin

Hansdieter Hofmann

Heinrich Koch

Karlheinz Raab

Paul Hagel

Production of spinnable polyhexamethylene adipamide of high molecular weight from adiponitrile, hexamethylene diamine, water and additives, preferably continuously in a reaction cascade and in a finisher as the final stage, catalytically accelerated by catalysts as disclosed. The polyamides can be produced from dinitriles, diamines and excess water in the presence of catalysts selected from the group consisting of: alkyl, aryl and alkyl/aryl esters of phosphoric, phosphorous, phosphonic and phosphinic acids. The catalyst is present in the amount of 0.001 to 1.0% based upon the total weight of the reactants.

Method for producing spinnable polyamide from dinitrile with phosphorus

Production of spinnable polyhexamethylene adipamide of high molecular weight from adiponitrile, hexamethylene diamine, water and additives, preferably continuously in a reaction cascade and in a finisher as the final stage, catalytically accelerated by catalysts as disclosed. It has now been discovered that polyamides can be produced from dinitriles, diamines and excess water in the presence of catalysts selected from the group consisting of: (1) oxygen-containing phosphorous compounds; (2) oxygen-containing boron compounds; (3) acidic oxygen-containing sulfur compounds; and (4) hydrogen halide and ammonium or ammonium alkyl salt thereof.

Preparation of spinnable polyamide from dinitrile, diamine, H.sub.2 O

A continuous process and apparatus for remelting fluffy, high bulk tangled polymer waste, such as nylon or polyethylene terephthalate fibers, which comprises chopping the waste into pieces 15 to 40 mm. mesh size, passing the chopped waste through a charging zone, a compressing screw, and finally an extruder. The charging zone is formed by a vertically-disposed hopper, having two opposed parallel walls and two opposed converging walls. Inside the hopper is a plurality of agitating shafts having tapered fingers that loosen and disentangle the chopped waste. The waste then is compressed to one-fourth to one-fifth its volume and transferred to an extruder where it is melted, degassed and extruded to a predetermined shape.

Apparatus and method for reclaiming polymer waste

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Frankfurt am Main, Germany

Konrad Wolff