Afton Chemical Corporation

Kongsheng Yang

William Y Lam

Jeremy P Styer

Kristin Fletcher

Sheng Jiang

Kristi Engelman

Ashutosh Gupta

Joseph W Roos

Joseph Eugene Remias

Kenneth J Garelick

Arturo Carranza

Leah Donham

Ian A Bell

Amy M James

Youhong Wang

Brent Calcut

Alexei Neverov

Jeremy Styer

Ashu Gupta

Joseph Remias

Ian Bell

The present disclosure relates to lubricating compositions and methods of lubricating a spark-ignition engine effective to improve low-speed pre-ignition (LSPI) through selection of lubricant elemental relationships rather than through the addition of supplemental fluid additives with the added benefit that the relationships herein, in some circumstances, improve the low-speed pre-ignition independent of the underlying base oil quality. The lubricating compositions herein include one or more base oils of lubricating viscosity, one or more phosphorus-containing additives providing low levels of phosphorus, a detergent system providing calcium and/or magnesium with certain relationships of the calcium sulfated ash content to the low phosphorus content.

Lubricating oil compositions for improving low-speed pre-ignition

The present disclosure relates to passenger car motor oil lubricating oil compositions having select dispersant and detergent systems to improve at least one of deposits, sludge, oxidization, and wear when using a blend of API Group II base oils with one or more API Group III and/or API Group IV base oils. The dispersant systems herein includes select amounts of boron, nitrogen, and total base number contributions that surprisingly achieve performance even when including higher amounts of the API Group II base oils in the lubricants.

Dispersant and detergent systems for improved motor oil performance

A lubricating composition including a polymer blend of a modified styrene-maleic anhydride copolymer and poly(meth)acrylate copolymer effective to maintain a pumpable fluid at low temperatures.

Engine oils with low temperature pumpability

A lubricating oil composition including a major amount of a base oil, one or more calcium-containing detergents to provide at least 1000 ppmw of calcium, and one or more silicon-containing compound(s) to provide at least 50 ppmw of silicon to the lubricating oil composition, all based on the total weight of the lubricating oil composition, wherein a ratio of ppmw of silicon provided by the one or more silicon-containing compound(s) to the lubricating oil composition to the ppmw of calcium provided by the one or more calcium-containing detergent(s) to the lubricating oil composition is from 0.02 to 1. Methods of using these compositions and silicon-containing detergents are also described.

Lubricant formulations with silicon-containing compounds

A multi-functional olefin copolymer viscosity index improver and a lubricating oil composition including such lubricant additive that provides improved viscometric properties and helps reduce low speed pre-ignition events at the same time. In one approach, the multi-functional olefin copolymer viscosity index improver is silicone functionalized and includes an acylated olefin copolymer with aminosilane or aminosiloxone pendant or side groups.

Silicone functionalized viscosity index improver

A lubricating oil composition and method of operating a boosted internal combustion engine. The lubricating oil composition includes greater than 50 wt. % of a base oil of lubricating viscosity, calcium, nitrogen, molybdenum and boron. The weight ratio of Ca:N (ppm/ppm) in the lubricating oil composition is greater than 1.3 to less than 3.0, the weight ratio of Ca:Mo (ppm/ppm) in the lubricating oil composition is greater than 6.7 to less than 56.3, and the weight ratio of Ca:B (ppm/ppm) in the lubricating oil composition is greater than 5.0 to less than 9.8. The lubricating oil composition does not contain added magnesium from a magnesium-containing detergent. The lubricating oil composition is resistant to deposit formation in the boosted internal combustion engine, as shown by its ability to ensure a TCO Temperature Increase of less than 9.0% as measured using the 2015 version of the General Motors dexos1&#xae; Turbocharger Coking Test.

Lubricants for use in boosted engines

A lubricating oil composition and method of operating a boosted internal combustion engine. The lubricating oil composition includes a major amount of a base oil, one or more overbased calcium-containing detergents having a total base number of greater than 225 mg KOH/gram, to provide greater than 900 ppm by weight to less than 2400 ppm by weight of calcium to the lubricating oil composition, and a low speed pre-ignition reducing amount of one or more titanium-containing compounds to provide from 10 ppm to 3000 ppm titanium and/or one or more tungsten-containing compounds to provide from 125 ppm to 3000 ppm tungsten, all based on the total weight of the lubricating composition. The low speed pre-ignition events in the boosted internal combustion engine may be reduced relative to a number of low speed pre-ignition events in the same engine lubricated with the same lubricating oil without the titanium- and/or tungsten-containing additive.

Lubricants with titanium and/or tungsten and their use for improving low speed pre-ignition

A lubricating oil composition and method of operating a boosted internal combustion engine. The lubricating oil composition includes greater than 50 wt. % of a base oil, one or more overbased calcium-containing detergents having a TBN greater than 225 mg KOH/g and one or more magnesium-containing detergents. A total amount of calcium from the one or more overbased calcium-containing detergents is from 900 ppm to less than 2400 ppm by weight, and a total amount of magnesium from the one or more magnesium-containing detergents is from 50 ppm to 500 ppm by weight, both based on a total weight of the lubricating oil composition. The lubricating oil composition and the method of using it are effective to reduce low speed pre-ignition events in a boosted internal combustion engine lubricated with the lubricating oil composition.

Lubricants with magnesium and their use for improving low speed pre-ignition

A lubricating oil composition and method of operating a boosted internal combustion engine. The lubricating oil composition is formulated to be resistant to turbocharger deposit formation in the boosted internal combustion engine, as shown by its ability to ensure a TCO Temperature Increase of less than 9.0% as measured using the 2015 version of the General Motors Dexos1&#xae; Turbocharger Coking Test. The lubricating oil composition may also have a low NOACK volatility, as measured by the method of ASTM D-5800 at 250&#xb0; C.

A lubricating oil composition and method of operating a boosted internal combustion engine. The lubricating oil composition includes greater than 50 wt. % of a base oil, an overbased detergent having a TBN greater than 225 mg KOH/g and a low-based/neutral detergent having a TBN up to 175 mg KOH/g. A total amount of calcium from the overbased and low-based/neutral detergent is greater than 1100 ppm to less than 2400 ppm by weight based on a total weight of the lubricating oil composition. The lubricating oil composition and method may be effective to reduce low-speed pre-ignition events in a boosted internal combustion engine lubricated with the lubricating oil composition relative to commercially available lubricating oil compositions.

Lubricants with calcium-containing detergent and their use for improving low speed pre-ignition

A lubricating oil composition and method of operating a boosted internal combustion engine. The lubricating oil composition has not more than 150 ppm sodium and includes a major amount of a base oil and an additive composition that includes one or more overbased calcium-containing detergents having a total base number of greater than 225 mg KOH/gram, in an amount sufficient to provide greater than 1100 ppm by weight to less than 2400 ppm by weight of calcium to the lubricating oil composition, and one or more molybdenum-containing compounds in an amount sufficient to provide at least about 80 ppm by weight molybdenum to the lubricating oil composition, all based on the total weight of the lubricating composition. The oil and method may reduce low-speed pre-ignition events in the boosted internal combustion engine relative to a number of low-speed pre-ignition events in the same engine lubricated with a reference lubricating oil.

Lubricants with molybdenum and their use for improving low speed pre-ignition

A lubricating oil composition and method of for providing an acceptable number of low-speed pre-ignition events in a boosted internal combustion engine using the lubricating oil composition. The lubricating oil composition includes greater than 50 wt. % of a base oil of lubricating viscosity, and an additive composition that includes an overbased calcium-containing detergent having a TBN greater than 225 mg KOH/g, and one or more zinc dialkyl dithiophosphate compounds are derived from a molar ratio of secondary alcohol to primary alcohol of 20:100 to about 100:0 and have an average total carbon content of greater than 10 carbon atoms per mole of phosphorous. The lubricating oil compositions contains the overbased calcium-containing detergent in an amount to provide greater than 900 ppm to less than 2400 ppm by weight calcium, and at least 0.01 wt. % of the zinc dialkyl dithiophosphate, both amounts based on the total weight of the lubricating oil composition.

Lubricants with zinc dialkyl dithiophosphate and their use in boosted internal combustion engines

A lubricant additive composition, a method for reducing engine deposit formation and a method for improving emulsion stability of a lubricant composition. The lubricant additive composition includes (a) an organomolybdenum compound contributing from about 20 to no greater than 300 ppm by weight molybdenum to the lubricant composition based on a total weight of the lubricant composition containing the additive composition; (b) a boronated hydrocarbyl substituted succinimide dispersant; and (c) a reaction product of (i) a hydrocarbyl-dicarboxylic acid or anhydride, (ii) a polyamine, (iii) a dicarboxyl-containing fused aromatic compound, and (iv) a non-aromatic dicarboxylic acid or anhydride. The hydocarbyl group of the hydrocarbyl-dicarboxylic acid or anhydride has a number average molecular weight of greater than 1800 Daltons as determined by gel permeation chromatography. A weight ratio of (b) to (c) ranges from about 1:1 to about 4:1.

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Glen Allen, VA, United States of America

Kongsheng Yang