Nissin Electric Co., Ltd.

Honda Motor Co., Ltd.

Nippon Itf, Inc

Idemitsu Kosan Company, Limited

Koji Miyake

Takehiko Ooshiro

Masanori Tsujioka

Hajime Kuwahara

Kiyoshi Ogata

Takahiro Nakahigashi

Hiroaki Koshima

Satoshi Yoshida

Moritsugu Kasai

Tsukasa Hayashi

Yoko Ogahara

Kentaro Komori

Yasuo Murakami

Nobuaki Watanabe

Jo Takeuchi

Eishi Fujimagari

Yukako Fukutani

Ryohei Nishiumi

Takeyuki Yamasaki

Hidetoshi Chiba

Masashi Kaji

A hard carbon film that forms a sliding surface of a sliding member, wherein the hard carbon film includes terminal atoms that bond to carbon atoms and has a plurality of protruding shaped parts, part of which protrude from the surface thereof, with the periphery of each of the plurality of protruding shaped parts being terminated by a terminal atom. A manufacturing method for the hard carbon film for producing the hard carbon film on a sliding surface of the sliding member using arc vapor deposition having graphite as the vaporization source, wherein a gas containing the terminal atoms that bond to carbon atoms is introduced, and the plurality of protruding shaped parts is grown on the surface of the hard carbon film while terminating the periphery of the plurality of protruding shaped parts by bonding of the terminal atoms to carbon atoms.

Hard carbon film, manufacturing method for same, and sliding member

A piston ring in which carbon films with film qualities optimized to be adapted to required performance are formed on an outer circumferential sliding surface and top and bottom surfaces thereof with good productivity is provided, and a high-performance engine which employs the piston ring is also provided. In the piston ring, a carbon film is formed on an outer circumferential sliding surface and top and bottom surfaces. The carbon film contains a stacking of at least two types of carbon film layers with different film qualities, and a thickness ratio of the two types of carbon film layers is different between the outer circumferential sliding surface and the top and bottom surfaces.

Piston ring and engine

Provided is a piston ring having excellent low-friction properties and abrasion resistance manufactured without the need for precision control using an ordinary film formation device that does not have a special function. A piston ring obtained by coating an amorphous carbon film on the surface of a ring-shaped substrate, the piston ring being configured so that the amorphous carbon film is formed by CVD, an increase region, in which the ratio sp/spof the spbond to the spbond continuously increases from the substrate surface toward the film surface, and a decrease region, in which the ratio sp/spcontinuously decreases, are formed in alternating fashion, a soft film in which the ratio sp/spis low and a hard film in which the ratio sp/spis high are formed so as to be layered in alternating fashion by continuous variation of the ratio sp/spin the boundary between the increase region and the decrease region, and the decrease regions are formed in equal number to or with one region less than the number of increase regions.

Piston ring and method for manufacturing same

Provided are a piston ring which, even when a sleeve constituted of an aluminum alloy is used, can sufficiently show the required low frictional properties, wear resistance, and low counterpart-material attacking properties, and a process for producing the piston ring. The piston ring has a rigid carbon film formed as the outermost layer thereof and serving as a sliding surface with a sleeve constituted of an aluminum alloy, wherein the rigid carbon film gives an X-ray diffraction pattern that has peaks assigned to graphite crystals. The rigid carbon film of the piston ring is formed using a chemical vapor deposition method. The rigid carbon film of the piston ring has a hydrogen content which is at least 20 atm % but lower than 30 atm %, and gives a Raman spectrum in which the ratio of the area (ID) of D-band peaks to the area (IG) of G-band peaks, ID/IG, is 0.5-2.0.

Piston ring and process for producing same

Disclosed is a lubricating oil composition for low-friction sliding materials, which is used in a sliding mechanism where a DLC film containing hydrogen in an amount of from 5 atom % to 50 atom % is formed on at least one sliding surface. The lubricating oil composition contains, in the lubricant base oil therein and based on the total amount of the composition, (A) an organic zinc dithiophosphate in an amount of from 0.005% by mass to 0.12% by mass in terms of the phosphorus concentration therein, (B) an amine-based friction-reducing agent in an amount of from 0.05% by mass to 5.0% by mass, and (C) an alkaline earth metal salicylate-based detergent and/or an alkaline earth metal sulfonate-based detergent in an amount of from 0.05% by mass to 0.5% by mass in terms of the alkaline earth metal concentration therein, wherein the component (A) contains, based on the total amount of the composition, a zinc primary dialkyldithiophosphate in an amount of from 0.005% by mass to 0.05% by mass in terms of the phosphorus concentration therein.

Lubricating oil composition, and sliding mechanism using lubricating oil composition

Provided is a technique whereby a DLC film having a desired surface roughness and a desired film hardness can be easily formed within a short period of time while preventing cost increase so that a large quantity of boll joints, which are less expensive and yet have stable sliding characteristics, can be supplied. A method for manufacturing a ball joint provided with a ball stud that has a spherical surface section and a holder section that pivotally holds the spherical surface section, said method comprising: an intermediate underlayer-forming step for forming an intermediate underlayer, that has a fine irregular surface structure, on the surface of the spherical surface section using a sputtering method; and an amorphous hard carbon film-forming step for forming an amorphous hard carbon film, that has a root mean square roughness on the surface of 6.5-35 nm, on the intermediate underlayer using a PIG plasma film formation method.

Ball joint and method for manufacturing same

Disclosed is a lubricating oil composition for low-friction sliding materials, which is used in a sliding mechanism where a DLC film containing hydrogen in an amount of from 5 atom % to 50 atom % is formed on at least one sliding surface. The lubricating oil composition contains, in the lubricant base oil therein and based on the total amount of the composition, (A) an organic zinc dithiophosphate in an amount of from 0.005% by mass to 0.12% by mass in terms of the phosphorus concentration therein, (B) an amide-based friction-reducing agent in an amount of from 0.05% by mass to 5.0% by mass, and (C) an alkaline earth metal salicylate-based detergent and/or an alkaline earth metal sulfonate-based detergent in an amount of from 0.05% by mass to 0.5% by mass in terms of the alkaline earth metal concentration therein.

A vacuum arc vapor deposition apparatus includes a plurality of magnetic coils for guiding a plasma produced by a vacuum arc evaporating source to the vicinity of a substrate in a film forming chamber by use of a deflection magnetic field. The vacuum arc vapor deposition apparatus further includes a coil power source for reversing a coil current to be fed to the magnetic coils, and a control unit for controlling the coil power source to reverse the flowing direction of the coil current.

Vacuum arc vapor deposition apparatus and vacuum arc vapor deposition method

A carbon film C containing carbon as a main component, formed on the surface of a soft base material , characterized in that the film C is cracked A and divided into a plurality of regions B, and an average area of respective regions (blocks) surrounded by cracks A is 0.15&times;10 mm to 20&times;10 mm .

Carbon film and method of forming the same

A method of forming a silicon-contained crystal thin film can efficiently form the crystal thin film of a relatively large thickness. In the method, hydrogen ions are implanted into a silicon-contained crystal substrate. Voids are formed by immersing the ion-implanted crystal substrate in a melted metal liquid containing, e.g., silicon and indium for heating the substrate. While pressing an ion-injected surface of the substrate, the substrate is heated by the melted metal liquid to form the voids. By cooling the liquid, the silicon in the supersaturated liquid is deposited on the surface of the substrate so that the silicon-contained crystal film is formed on the surface of the substrate. The substrate is divided in the void-formed position. Thereby, a thin film including the silicon-contained crystal film layered on a portion of the substrate is obtained. The silicon-contained crystal thin film thus obtained can be adhered to a support substrate, if necessary.

Method of forming silicon-contained crystal thin film

A method for implanting negative hydrogen ions includes the following steps. Plasma containing hydrogen is generated. Negative hydrogen ions are generated in the plasma. An electric field is formed between the plasma and a substrate. Negative hydrogen ions from the plasma is accelerated by using the electric field so as to implant negative hydrogen ions into a predetermined depth of a substrate.

Method for implanting negative hydrogen ion and implanting apparatus

A vaporizing apparatus has a vaporizing container into which a liquid raw material is introduced and which is made of metal, a heater for heating the vaporizing container to vaporize liquid introduced into the vaporizing container and a metal nozzle (an electrode) disposed in the vaporizing container in such a manner that the nozzle is electrically insulated from the vaporizing container. Moreover, the vaporizing apparatus has a cleaning-solution supply apparatus for supplying, to the inside portion of the vaporizing container, a cleaning solution for solving residues generated in the vaporizing container and a plasma generating power source for supplying high-frequency electric power to a position between the nozzle and the vaporizing container to generate plasma in the vaporizing container by using the vaporized cleaning solution.

Apparatus for vaporizing liquid raw material and method of cleaning CVD apparatus

A work is supported by a work support electrode arranged in a vacuum container, a treatment gas corresponding to intended treatment of the work is supplied into the container, and a vacuum is produced in the container. Plasma is formed from the gas by applying an amplitude-modulated high-frequency power to an electrode electrically insulated from the work support electrode, said amplitude-modulated high-frequency power being prepared by effecting amplitude modulation on a basic high-frequency power having a predetermined frequency in a range from 10 MHz to 200 MHz with a modulation frequency in a range from 1/1000 to 1/10 of said predetermined frequency. A positive pulse voltage is applied to the work support electrode to effect the treatment on the surface of the work supported by the work support electrode.

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Kyoto, Japan

Koji Miyake