Kansai Paint Company, Ltd.

Toyota Jidosha Kabushiki Kaisha

Koji Kamikado

Shigeo Nishiguchi

Akira Tominaga

Hideki Iijima

Susumu Midogochi

Tadayoshi Hiraki

Haruo Nagaoka

Akihiko Shimasaki

Hidenori Sawada

Reiziro Nishida

Hidehiko Haneishi

Masaharu Shimoda

Masanobu Kudoh

Naozumi Iwasawa

Akimasa Nakahata

Masafumi Kume

Masaru Mitsuji

Tetsuo Aihara

Tadayoshi Tatsuno

Eisaku Nakatani

Toshio Ohkoshi

Yasuyuki Hirata

Katsuhisa Sugisaki

Takahisa Kasukawa

Kyoichi Horibe

Hirokazu Hayashi

Minoru Hanatani

Yutaka Iino

Souichi Ikejiri

Susumu Kansai-Paint-Hiratsuka-Cluba204 Midogochi

The invention provides electrodeposition paint of reduced volatile organic compound content, in which specific polyether compound(s) having a molecular weight not more than 1,000 is(are) incorporated and which excel in corrosion resistance, electrocoating ability of rustproof steel sheet, film-forming ability, pin holing resistance and stability.

Electrodeposition paint

A coated article is obtained by electrodeposition coating using an electrodeposition coating composition, which comprises: (A) a resin component obtained by reacting an epoxy resin, an amino compound and/or a phenolic compound; (B) a resin component having a specific structural unit; (C) a blocked polyisocyanate compound; and (D) at least one rust inhibiting component selected from the group consisting of metal ions selected from zirconium, titanium, cobalt, vanadium, tungsten and molybdenum, oxymetal ions of the metal, and fluorometal ions of the metal.

Electrodeposition coating composition, coating method and coated article

A coating film-forming method, which method comprises coating a cationic electrodeposition coating composition onto a substrate, followed by heat curing to form a cured electrodeposition coating film, said cationic electrodeposition coating composition containing a base resin consisting of an amine-added epoxy resin (A) obtained by reacting an epoxy resin (a) with at least one modifying agent selected from the group consisting of a polyhydric polyol (a), an epoxy compound (a) of the polyhydric polyol and a cyclic ester compound (a), a polyphenol compound (a) and an amino group-containing compound (a), and a curing agent consisting of a blocked polyisocyanate curing agent (B) obtained by reacting at least one polyisocyanate compound (b) selected from the group consisting of an aromatic polyisocyanate compound and an alicyclic polyisocyanate compound with at least one blocking agent (b) selected from the group consisting of an oxime compound, aliphatic alcohols, aromatic alkyl alcohols and ether alcohols.

Coating film-forming method

A method for forming an electrodeposition coating film, comprises a step of subjecting a steric metal article to be coated to electrodeposition coating, and a step of selectively heating/drying the resultant coating film by a plurality of induction heating devices.

Method for forming electrodeposition coating film

A cationic electro-deposition coating composition, comprises: Component (A): an amino-containing epoxy resin (A) obtained by adding an amino-containing compound (a-2) to an epoxy resin (a-1) having an epoxy equivalent of from 400 to 3000, Component (B): an amino-containing acrylic resin (B) obtained by adding an amino-containing compound (b-4) to a copolymer resin obtained by radical copolymerization of, as essential components, a polylactone-modified hydroxyl-containing radical copolymerizable monomer (b-1), which is obtained by adding a lactone to a hydroxyl-containing acrylic monomer (b), and glycidyl (meth)acrylate (b-2), and another radical copolymerizable monomer (b-3); and Component (C): a blocked polyisocyanate curing agent (C) as a curing component, the component (A), component (B) and component (C) being added in amounts of 5 to 80 wt %, 5 to 80 wt % and 10 to 40 wt %, respectively, based on the total solid content of the components (A), (B) and (C).

Cationic electro-deposition coating compositions

It is an object of the present invention to provide an electrodeposition coating composition excellent in corrosion resistance and stability of the coating. The electrodeposition coating composition comprises, based on 100 parts by weight (solid basis) of a core resin and a hardener constituting an electrodeposition coating, 1 to 100 parts by weight of (a) a zinc powder dispersed by a phosphoric-acid-group-containing dispersing resin.

Electrodeposition coating compositions and articles coated therewith

The present invention provides a cationic paint composition containing, as a vehicle component, a xylene-formaldehyde resin-modified amino group-containing epoxy resin obtained by reacting an epoxy resin having an epoxy equivalent of 180 to 2,500 with an alkyl phenol and/or a carboxylic acid, a xylene-formaldehyde resin, and an amino group-containing compound.

Cationic paint composition

The present invention provides a resin composition for coating, capable of forming a coating film excellent in electrodeposition property, coating surface smoothness and anticorrosivity in spite of small content of organic solvent and without containing a lead compound, and comprising a modified epoxy-polyamine resin (f), obtained by first reacting a diepoxide compound (a), wherein a specified amount of alkylene oxide has been introduced, and a bisphenol A type epoxy resin of an epoxy equivalent 170-500 with a bisphenol (b), reacting the epoxy resin (c) thus obtained with a cyclic ester (d), and further reacting the modified epoxy resin (e) thus obtained with an amine compound having active hydrogen.

Advanced bisphenol and oxyalkylene diepoxides reacted with cyclic ester, amine and blocked isocyanate

Bisphenol and oxyalkylene diepoxide-advanced epoxy resin with cyclic ester and amine

The present invention provides a cationic resin composition comprising a cationic resin (A) and a blocked polyisocyanate (B) obtained by reacting an active hydrogen-containing component comprising a diol (a) which has two hydroxyl groups having different reactivities from each other and which has a molecular weight of 76 to 150 and a carboxyl group-containing diol (b) having a molecular weight of 106 to 500 with a polyisocyanate compound (c).

Cationic resin composition

The present invention provides a cationic coating composition capable of forming a coating film which is excellent in an electrodepositablly coating property and an adhesive property toward a rust preventive steel plate, a corrosion resistance and a low temperature curability. The cationic coating composition described above comprises as a vehicle component, a xylene-formaldehyde resin-modified, amino group-containing epoxy resin obtained by reacting an epoxy resin (A) having an epoxy equivalent of 180 to 2500 with a xylene-formaldehyde resin (B) and an amino group-containing compound (C).

Cationic coating composition

The present invention provides a cationic paint composition containing as resin component a polyol-modified amino group-containing epoxy resin obtained by reacting an epoxy resin with epoxy equivalent 180-2500 with a alkyl phenol and/or a carboxylic acid; a polyol obtained by adding a caprolactone to a compound containing a plurality of active hydrogen groups and an amino group-containing compound.

The present invention provides a cationic coating composition capable of forming a coating film which is excellent in a corrosion resistance and an adhesive property and an electrodepositably coating property toward a rust preventive steel plate (zinc-plated steel plate). The cationic coating composition described above comprises as a vehicle component, a polyol-modified, amino group-containing epoxy resin prepared by reacting an epoxy resin (A) having an epoxy equivalent of 180 to 2500 with a polyol compound (B) obtained by adding caprolactone to a compound having plural active hydrogen groups and an amino group-containing compound (C).

Growing community of inventors

Yokohama, Japan

Koji Kamikado